Abstract
A new binary complex salt — chloropentaamminechromium(III) tetrabromopalladate(II) [Cr(NH3)5Cl][PdBr4] — has been synthesized. The compound was characterized by elemental, X-ray diffraction, and X-ray phase analysis. The salt is isostructural with the previously investigated compounds [M(NH3)5Cl][PtCl4] (M = Ir, Rh, Ru, Co, Cr) and [CM(NH3)5Cl][PdBr4] (M = Ir, Rh, Co). Crystallographic data: space group Pnma, a = 17.068(2) Å, b = 8.315(12) Å, c = 9.653(14) Å; V = 1370.0(3) Å3, Z = 4, d calc = 2.903 g/cm3.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 6, pp. 1133–1136, November–December, 2005.
Original Russian Text Copyright © 2005 by A. V. Zadesenets, A. B. Venediktov, S. V. Korenev, I. A. Baidina, and S. A. Gromilov
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Zadesenets, A.V., Venediktov, A.B., Korenev, S.V. et al. Synthesis and crystal structure of [Cr(NH3)5Cl][PdBr4]. J Struct Chem 46, 1091–1094 (2005). https://doi.org/10.1007/s10947-006-0248-1
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DOI: https://doi.org/10.1007/s10947-006-0248-1