Summary
Hardwood sawdust was derivatized either by carboxymethylation, glutaration, maleiation, phthallation, or succination in order to produce anionic materials suitable for complexation with soy protein isolate. Blending each derivative with soy protein isolate resulted in instant precipitation of gels. Infrared spectroscopy and differential scanning calorimetry suggested that each derivative formed a complex with protein. Reaction products could be dried into pellets exhibiting tensile strengths between 0.9–2.4 MPa, suggested that these materials could be promising candidates for biodegradable structural materials.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
C. H. Schilling P. Tomasik D. S. Karpovich B. Hart S. Shepardson J. Garcha P. T. Boettcher (2004) J. Polym. Environ. 12 257–264 Occurrence Handle10.1007/s10924-004-8317-z Occurrence Handle1:CAS:528:DC%2BD2cXhtVGitrvJ
C. H. Schilling P. Tomasik D.S. Karpovich B. Hart J. Garcha P. T. Boettcher (2005) J. Polym. Environ. 13 57–63 Occurrence Handle10.1007/s10924-004-1216-5 Occurrence Handle1:CAS:528:DC%2BD2MXht1ymt74%3D
C. H. Schilling, P. Tomasika, D. S. Karpovich, B. Hart, J. Garcha, and P. T. Boettcher, J. Polym. Environ., in press
E. S. Stevens (2002) Green Plastics: An Introduction to the New Science of Biodegradable Plastics Princeton University Press Princeton, NJ
G. Scott (1995) Degradable Polymers Chapman & Hall Newyork 44–50
R. A. Gross B. Kalra (2002) Science 297 803–807 Occurrence Handle10.1126/science.297.5582.803 Occurrence Handle1:CAS:528:DC%2BD38XlvVyku7Y%3D Occurrence Handle12161646
Y. Poirier D. E. Dennis K. Klomparins C. Somerville (1992) Science 256 520–622 Occurrence Handle1:CAS:528:DyaK38XisFaitL8%3D
C. Okkerse and H. van Bekkum (1996). Starch 96 (H. van Doren and N. van Swaaj, Eds.), Zestec bv/Carbohydrate Research Foundation, Ch.1
H. Ruck (1996) ywn. Technol. Jakoœæ, Suppl 2 IssueID7 138–157
P. Tomasik M. Pałasiñski S. Wiejak (1989) Adv. Carbohydr. Chem. Biochem. 47 203–278 Occurrence Handle1:CAS:528:DyaK3cXlslansbc%3D
P. Tomasik S. Wiejak M. Pałasinski (1989) Adv. Carbohydr. Chem. Biochem. 47 279–344 Occurrence Handle1:CAS:528:DyaK3cXht1SqtLg%3D
P. Tomasik C. H. Schilling (1998) Adv. Carbohydr. Chem. Biochem., 53 263–343
P. Tomasik C. H. Schilling (1998) Adv. Carbohydr. Chem. Biochem. 53 345–426 Occurrence Handle1:CAS:528:DyaK1MXkvFCg
P. Tomasik C. H. Schilling (2004) Adv. Carbohydr. Chem. Biochem. 59 175–403 Occurrence Handlefull_text||10.1016/S0065-2318(04)59005-4 Occurrence Handle1:CAS:528:DC%2BD2MXjtFant7s%3D Occurrence Handle15607766
P. Tomasik M. F. Zaranyika (1995) Adv. Carbohydr. Chem. Biochem. 51 243–318 Occurrence Handle1:CAS:528:DyaK28XpvFyrsQ%3D%3D Occurrence Handle7484364
A. C. Albertson B. Ranby (1979) J .Appl. Polym. Sci. 35 413–430
J. G. Batelaan and P. M. Van der Horst (2000) U.S. Patent 6,103,885
J. A. Youngquist, A. M. Krzysik, B. W. English, H. N. Spelter, and P. Chow (1996) Proc. Symp. The Use of Recycled, Wood, and Paper in Building Applications, Madison,WI. pp. 123–134
R. M. Rowell A. R. Sanadi D. T. Caufield R. E. Jacobson (1997) NoChapterTitle A. L. Leao F. X. Carvalho E. Frollini (Eds) Lignocellulosic Plastic Composites Uniiversidad de Sao Paulo Sao Paulo 23–51
P. J. Andersen and S. K. Hodson (2001) US Patent 6,231,970
J. A. Youngquist, B. E. English, ZR. C. Schramer, Poo Chow, and R. S. Shooh (1998) US Department of Agriculture, General Technical Report FPL-GTR-80
J. L.Wilett and W. M. Doane (2001) US Patent 6,362,256
L. A. Johnson D. J. Myers D. J. Burden (1992) Inform 3 IssueID3 282–290
A. Satkofsky (2002) J. Comp. Org. Recycl. 43 IssueID3 60
J. Jane S. T. Tim (1995) NoChapterTitle F. Meuser D. J. Munnes W. Seibel (Eds) Progresss in Plant Polymeric Carbohydrate Research Behr’s Verlag Hamburg 165–168
C. H. Schilling T. Babcock S. Wang J. Jane (1995) J. Mater. Res. 10 2197–2202 Occurrence Handle1:CAS:528:DyaK2MXns12jsL4%3D
J. Zhang P. Mungara J. Jane (2000) Polymer 42 2569–2578 Occurrence Handle10.1016/S0032-3861(00)00624-8
I. Pateau C. A. Chen J. Jane (1994) Ind. Eng. Chem. Res. 33 1821–1827 Occurrence Handle10.1021/ie00031a023
J. Jane and S. Zhang (1995) U.S. Patent 5,710,190
J. Jane and K. Spence (1995) U.S. Patent 5,397,834
S. K. Samant R. S. Singhal P. R. Kulkarni D. V. Rege (1993) Int. J. Food Sci. Technol. 28 547–562 Occurrence Handle1:CAS:528:DyaK2cXisVaksLw%3D
C. Schmitt C. Sanchez S. Desobry-Banon J. Hardy (1998) Crit. Rev. Food Sci. Nutr. 38 689–733 Occurrence Handle1:CAS:528:DyaK1cXotV2ksrc%3D Occurrence Handle9850463
H. Zaleska P. Tomasik S. G. Ring (2001) Carbohydr. Polym. 45 89–94 Occurrence Handle10.1016/S0144-8617(00)00239-3 Occurrence Handle1:CAS:528:DC%2BD3MXhslGqsbo%3D
H. Zaleska S. G. Ring P. Tomasik (2001) Int. J. Food Sci. Technol., 36 509–515
T. Grega D. Najgebauer M. Sady P. Tomasik M. Faryna (2003) J. Polym. Environ. 11 75–83 Occurrence Handle10.1023/A:1024275906612 Occurrence Handle1:CAS:528:DC%2BD3sXks12rtro%3D
A. Dejewska J. Mazurkiewicz P. Tomasik H. Zaleska (1995) Starch/Staerke 47 219–223 Occurrence Handle1:CAS:528:DyaK2MXmt1Slsrw%3D
H. Zaleska J. Mazurkiewicz P. Tomasik M. Baczkowicz (1999) Nahrung 43 278–283 Occurrence Handle10.1002/(SICI)1521-3803(19990801)43:4<278::AID-FOOD278>3.0.CO;2-C Occurrence Handle1:CAS:528:DyaK1MXmvVGnsL8%3D
H. Zaleska S. G. Ring P. Tomasik (2000) Food Hydrocoll. 14 371–382
C. Y. Lii H. H. Chan P. Tomasik (2003) J. Polym. Environ. 11 115–121 Occurrence Handle10.1023/A:1024687115062 Occurrence Handle1:CAS:528:DC%2BD3sXltlWgsbg%3D
C. Y. Lii H. H. Chan S. Lu P. Tomasik (2003) Int. J. Food Sci. Technol. 38 787–793 Occurrence Handle10.1046/j.1365-2621.2003.00733.x Occurrence Handle1:CAS:528:DC%2BD3sXnvFOntbg%3D
C. Y. Lii S. C. Liaw V. M.-F. Lai P. Tomasik (2002) Eur. Polym. J. 38 1377–1381 Occurrence Handle10.1016/S0014-3057(02)00008-3 Occurrence Handle1:CAS:528:DC%2BD38Xjt1ClsLc%3D
C. Y. Lii S. C. Liaw P. Tomasik (2003) Pol. Food J. Nutr. Sci. 12 IssueID3 25–29 Occurrence Handle1:CAS:528:DC%2BD3sXptFWitLY%3D
C. Y. Lii P. Tomasik H. Zaleska S. C. Liaw (2002) Carbohydr. Polym. 50 19–26 Occurrence Handle10.1016/S0144-8617(01)00372-1 Occurrence Handle1:CAS:528:DC%2BD38XjvF2qtb4%3D
H. Zaleska P. Tomasik S. C. Lii (2002) J. Food Eng. 14 215–224
H. Zaleska P. Tomasik C. Y. Lii (2002) Carbohydr. Polym. 53 249–257
T. Grega D. Najgebauer M. Sady P. Tomasik (2003) J. Polym. Environ. 12 17–25 Occurrence Handle10.1023/B:JOOE.0000003124.39173.8f
T. Kitamura and H. Katayama (1999) Proc. REWAS 99 Symp. San Sebastian Sept. 5–9 1999. vol. 3, (I. Gabellah, J. Hager, and R. Solozabal, Eds.), Metals & Materials Soc, Warrendale, PA, pp. 2021–2028
G. Lu Q. Wang K. Sakamoto H. Kim J. Naruse J. Yuan T. Maruyama M. Kanude M. Sadakata (2000) Energy, Fuel 14 1133–1138
T. Ohtsuka (1999) Jpn. Kokai Tokkyo Koho, 113 33420; Chem. Abstr.132, 24041
W. S. Andrew, Jr. (1998) US Patent 5 728, 192
H. Tanaka (2001) Jpn. Kokai Tokkyo Koho, 2002145686; Chem. Abstr.136, 406170
J. Xu, T. Li, Y. Yan, and Z. Ren (1999) Ranliao Huaxue Xuebao27, 328–334; Chem.Abstr.131, 301308
G. Hartel S. Roatz M. Schrey (1999) Freib. Forschungshef A852 243–257 Occurrence Handle1:CAS:528:DC%2BD3cXjvFSr
A. Nag (1995) Proc. Saf. Environ. Protect 73 IssueID(B4 299–304 Occurrence Handle1:CAS:528:DyaK28XlsFGisA%3D%3D
D. N. Thompson R. L. Sayer K. S. Noah (2000) Minerals, Metalurg. Proc. 17 96–104
N. Marcovich, M. M. Reboredo, and M. T. Aranguren (1997) Proc. Int. Symp. Lignocellulosic Plastic Composites, Sao Paulo, Mar. 13–115, 1996(A. L. Leao, F. X. Carvalho, and E. Frollini, Eds.), Universidade de Sao Paulo, Sao Paulo, pp. 223–240
G. R. Rech, S. L. Vieira, G. A. Carvalho, M. Zeni, and J. A. Zattera (1998) Proc. Int. l Symp. Natural Polymer and Composites, Atibaia, May 10–13, 1998,(H. C. Mattosol, E. Frollini, and A. L. Leao, Eds), Embraya Agricultural Instrumentation, Sao Carlos, pp. 111–114
A. S. Cherbakov, L. V. Golzeva, S. V. Podtyufarov, V. I. Kucherzoi, and V. S. Podtyufarov (1997) Jpn. Kokai Tokkyo Koho 09086999; Chem. Abstr.127, 180110
Z. Kin (1971) Lignin, Chemistry and Uses(in Polish), WNT, Warsaw, Ch. 1 and 2
D. Bortzmeyer (1992) J. Mater. Sci. 27 3305–3308 Occurrence Handle10.1007/BF01116029 Occurrence Handle1:CAS:528:DyaK38XkslCku7c%3D
R. M. Silverstein G. C. Basler T. C. Morrill (1991) Spectrometric Identification of Organic Compounds, 5th Edn John Wiley & Sons New York
W. D. Callister (2000) Materials Science and Engineering, An Introduction, 5th Edn Wiley New York 800–801
R. W. Hertzberg (1996) Deformation and Fracture Mechanics of Engineering Materials, 4th Edn Wiley New York 315–321
L. J. Gibson M. F. Ashby (1988) Cellular Solids, Structure and Properties – 2nd Edn Cambridge University Press Cambridge, UK 219–222
J. S. Reed (1991) ‘Drying” S. J. Schneider (Eds) Engineered Materials Handbook, Volume 4, Ceramics and Glasses ASM International Metals Park, Ohio 130–134
G. Y. Onoda (1976) J. Am. Ceram. Soc. 58 236–39
C. H. Schilling V. J. Garcia R. M. Smith R. A. Roberts (1998) J. Am. Ceram. Soc. 81 2629–269 Occurrence Handle1:CAS:528:DyaK1cXms12ht78%3D
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Schilling, C.H., Tomasik, P., Karpovich, D.S. et al. Preliminary Studies on Converting Agricultural Waste into Biodegradable Plastics – Part III: Sawdust. J Polym Environ 13, 177–183 (2005). https://doi.org/10.1007/s10924-005-2948-6
Issue Date:
DOI: https://doi.org/10.1007/s10924-005-2948-6