The biobased epoxy containing epoxidized linseed oil (ELO) and its clay nanocomposites were processed with an anhydride curing agent. The certain amount of diglycidyl ether of bisphenol F (DGEBF) was replaced by ELO. The selection of the DGEBF, ELO, an anhydride curing agent, and organo-montmorillonite clay resulted in an excellent combination, to provide new biobased epoxy/clay nanocomposites showing high elastic modulus, high glass transition temperature, and high fracture toughness with larger amount of ELO. Izod impact strength was almost constant while changing the amount of ELO. This is a promising result for future applications in different engineering industries.
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References
S. Dirlikov I. Frischinger Z. Chen (1996) Adv. Chem. Ser. 252 95–109 Occurrence Handle1:CAS:528:DyaK28XntFWjtr0%3D
D. Ratna A. K. Banthia (2000) J. Adhesion. Sci. Eng. 14 IssueID1 15–25 Occurrence Handle10.1163/156856100742087 Occurrence Handle1:CAS:528:DC%2BD3cXhs1CgsA%3D%3D
D. Ratna (2001) Polym. Int. 50 179–184 Occurrence Handle10.1002/1097-0126(200102)50:2<179::AID-PI603>3.0.CO;2-E Occurrence Handle1:CAS:528:DC%2BD3MXpsFGmtg%3D%3D
F. Li R. C. Larock (2001) J. Polym. Sci. Part B Polym. Phys. 39 60–77 Occurrence Handle10.1002/1099-0488(20010101)39:1<60::AID-POLB60>3.0.CO;2-K Occurrence Handle1:CAS:528:DC%2BD3MXitlel
E. Can S. Kusefoglu R. P. Wool (2001) J. Appl. Polym. Sci. 81 69 Occurrence Handle10.1002/app.1414 Occurrence Handle1:CAS:528:DC%2BD3MXjsVagur0%3D
S. N. Khot J. J. LaScala E. Can S. S. Morye G. I. Williams G. R. Palmese S. H. Kusefouglu R. P. Wool (2001) J. Appl. Polym. Sci. 82 703–723 Occurrence Handle10.1002/app.1897 Occurrence Handle1:CAS:528:DC%2BD3MXmtFalsrw%3D
L. K. Belcher L. T. Drzal M. Misra A. K. Mohanty (2002) Polym. Mater.: Sci. Eng. 87 256–257 Occurrence Handle1:CAS:528:DC%2BD38XlsF2qsLc%3D
G. Mehta, M. Misra, L. T. Drzal, and A. K. Mohanty (2003) Proc. 14th International Conference on Composite Materials, July 14–18, CD-ROM #1754
Wool R.P., Khot S.N., LaScala J.J., Bunker S.P., Lu J., Thielemans W., Can E., Morye S.S., and Williams G.I. (2002). in ACS Symposium Series 823 (Advancing Sustainability through Green Chemistry and Engineering), pp. 177–204
H. Miyagawa A. K. Mohanty M. Misra L. T. Drzal (2004) Macromolecular Materials and Engineering 289 629–635 Occurrence Handle10.1002/mame.200400004 Occurrence Handle1:CAS:528:DC%2BD2cXmtFKmu70%3D
P. C. LeBaron Z. Wang T. J. Pinnavaia (1999) Appl.Clay. Sci. 15 11–29 Occurrence Handle10.1016/S0169-1317(99)00017-4 Occurrence Handle1:CAS:528:DyaK1MXkvVersL8%3D
P. B. Messersmith E. P. Giannelis (1994) Chem. Mater. 6 1719–1725 Occurrence Handle10.1021/cm00046a026 Occurrence Handle1:CAS:528:DyaK2cXmtVKrsLo%3D
T. Lan T. J. Pinnavaia (1994) Chem. Mater. 6 2216–2219 Occurrence Handle10.1021/cm00048a006 Occurrence Handle1:CAS:528:DyaK2cXmvVWrtrg%3D
C. Zilg R. Muelhaupt J. Finter (1999) Macromol. Chem. Phys. 200 IssueID3 661–670 Occurrence Handle10.1002/(SICI)1521-3935(19990301)200:3<661::AID-MACP661>3.3.CO;2-W Occurrence Handle1:CAS:528:DyaK1MXhvVaqsbs%3D
A. Lee J. D Lichtenhan (1999) J. Appl. Polym. Sci. 73 1993–2001 Occurrence Handle10.1002/(SICI)1097-4628(19990906)73:10<1993::AID-APP18>3.0.CO;2-Q Occurrence Handle1:CAS:528:DyaK1MXktFCgtrw%3D
J. M. Brown D. Curliss R. A. Vaia (2000) Chem. Mater. 12 3376–3384 Occurrence Handle10.1021/cm000477+ Occurrence Handle1:CAS:528:DC%2BD3cXntFynuro%3D
A. S. Zerda A. J. Lesser (2001) J. Polym Sci.: Part B: Polym. Phys. 39 1137–1146 Occurrence Handle10.1002/polb.1090 Occurrence Handle1:CAS:528:DC%2BD3MXjsVekt7c%3D
X. Kornmann R. Thomann R. Muelhaupt J. Finter L. Berglund (2002) J. Appl. Polym. Sci. 86 2643–2652 Occurrence Handle10.1002/app.11279 Occurrence Handle1:CAS:528:DC%2BD38Xnsl2nurk%3D
X. Kornmann R. Thomann R. Muelhaupt J. Finter L. Berglund (2002) Polym. Eng. Sci. 42 IssueID9 1815–1826 Occurrence Handle10.1002/pen.11074 Occurrence Handle1:CAS:528:DC%2BD38XotVGgtro%3D
H. Miyagawa M. J. Rich L. T. Drzal (2005) Polymer Composites 26 42–51 Occurrence Handle10.1002/pc.20071 Occurrence Handle1:CAS:528:DC%2BD2MXhvVChs7w%3D
H. Miyagawa, W.-A. Chiou, and I. M. Daniel (2001) Microscopy and Microanalysis, vol. 7 (suppl. 2), Proceedings: Microscopy&Microanalysis 2001, Long Beach CA, pp. 946–947.
G. P. Tandon G. J. Weng (1986) Composites Sci. Technol. 27 111–132 Occurrence Handle10.1016/0266-3538(86)90067-9 Occurrence Handle1:CAS:528:DyaL28Xmt1Orsrw%3D
D. Shia C. Y. Hui S. D. Burnside E. P. Giannelis (1998) Polym. Composites 19 IssueID5 608–617 Occurrence Handle10.1002/pc.10134 Occurrence Handle1:CAS:528:DyaK1cXnsVersr4%3D
Miyagawa H., Rich M.J., and L. T. Drzal (2003) 31st Annual Conference of North American Thermal Analysis Society (NATAS), Albuquerque NM, #109 (CD-ROM)
H. Miyagawa L. T. Drzal (2004) Journal of Adhesion Science and Technology 18 1571–1588 Occurrence Handle1:CAS:528:DC%2BD2MXot1emsA%3D%3D
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Miyagawa, H., Misra, M., Drzal, L.T. et al. Biobased Epoxy/Layered Silicate Nanocomposites: Thermophysical Properties and Fracture Behavior Evaluation. J Polym Environ 13, 87–96 (2005). https://doi.org/10.1007/s10924-005-2940-1
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DOI: https://doi.org/10.1007/s10924-005-2940-1