Abstract
Herein, flexible polyvinylidenefluoride (PVDF) nanocomposite films reinforced with different concentrations of graphene nanoplatelets (GNPs), montmorillonite (MMT) nanoclay and titanium dioxide (TiO2) nanoparticles (NPs) were prepared using a simple and low-cost solution casting method. The surface morphology of PVDF/GNPs/TiO2/MMT nanocomposites and the interaction between PVDF, GNPs, TiO2 NPs and MMT nanofillers was examined using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) techniques. The dielectric properties of the prepared nanocomposite films were evaluated using a frequency response impedance analyzer in the frequency range from 50 Hz to 20 MHz at various temperatures. The electromagnetic interference (EMI) shielding effectiveness (SE) of PVDF/GNPs/TiO2/MMT nanocomposites was measured in the Ku-band region (12–18 GHz) and the maximum SE of 12.6 dB was obtained for nanocomposites with GNPs-2.5%, MMT-1% and TiO2-11.5%. Considering the excellent EMI shielding performance, these nanocomposites can have promising applications in smart electronics and flexible devices.
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1 Introduction
The boundless and explosive growth in the electrical, electronics and telecommunication industries have enabled the substantial generation of unwanted electromagnetic (EM) pollution which is known as electromagnetic interference, EMI [1, 2]. The EM radiation emitted from the source generates considerable heat emissions thereby affecting the normal operation of electronic equipment and also leads to the malfunctioning of the neighbouring instruments [3, 4]. The EM radiations are also hazardous and can have serious effects on human health. Therefore, EMI shielding materials are essential to shield or to reduce the effect of this undesired pollution [5, 6]. The shielding material must have high absorption, high reflection and very less or negligible transmittance of EM radiation [3,4,5,6,7,8]. Traditionally, metals have been frequently used for EMI shielding because of their excellent conductivity, but they exhibit several drawbacks such as poor processability, high density, narrow absorption bandwidth, corrosive nature and heavyweight, etc. [5,6,7,8,9]. Therefore, nowadays, researchers are gradually replacing metal-based materials with flexible and low-cost polymer nanocomposites (PNCs) for the development of novel and efficient EMI shielding materials.
Recently, PNCs have attracted great attraction in different research fields because of their lightweight, easy processability, flexibility, low cost and excellent properties which can be tailored as per specific application needs [10,11,12,13,14,15]. Based on the intended applications, different types of conducting nanoparticles (NPs), metal oxides, metal and fibers or clay nanopowders can be added to a polymer matrix to achieve effective and homogeneous dispersion within the polymer matrix to obtain significant enhancement in the desired properties [16,17,18,19,20]. Furthermore, studies have shown that integrating two or more fillers into the polymer matrix can be more resourceful in achieving enhanced EMI SE [21,22,23,24]. Polyvinylidene fluoride (PVDF) is one of the most frequently investigated polymers especially used for preparing flexible PNCs. It is a semi-crystalline, ferroelectric polymer with good thermal stability, high melting point, excellent mechanical and dielectric properties [25, 26]. PVDF has mainly four crystal polymorphic phases namely α, β, γ and δ. Among them, the α-phase is the most common and stable polymorph [25,26,27]. The phase behaviour of PVDF has been studied extensively where the β-phase of PVDF was found to have good functionality, high tensile toughness, excellent piezoelectric and pyroelectric properties and good processability [28,29,30]. Thus, PVDF is a very promising polymeric material in the field of EMI shielding nanocomposites.
Graphene is an outstanding two-dimensional (2D) material comprising sp2 bonded carbon atoms arranged in a honeycomb structure [31]. Graphene exhibits excellent optical, electrical, thermal and tensile properties [31, 32]. These intriguing properties of graphene have triggered enormous interest in its implementation in a vast number of applications such as supercapacitors [33], fuel cells [34], photonics and optoelectronics [35] and lithium-ion batteries [36]. Graphene nanoplatelets (GNPs) are composed of single or few-layer graphene with thicker graphite [37]. GNPs exhibit a planar structure with excellent properties such as large aspect ratio, lightweight, excellent electrical and thermal conductivity and mechanical strength [37, 38]. Furthermore, GNPs based PNCs have demonstrated improved flexural and tribological properties [39, 40]. Montmorillonite (MMT) consists of an intercalated structure with an expanded interlayer spacing of layered aluminosilicates [41]. MMT nanoclay particles are frequently used as filler materials that can be efficiently dispersed within the polymer matrix. Studies have revealed enhanced structural and tribological properties of PNCs when MMT was dispersed into the PVDF matrix [42, 43]. Titanium dioxide (TiO2) NPs have been the most widely used nanofiller in the development of PNCs owing to their promising properties such as good chemical stability, high refractive index, good dielectric properties and excellent corrosion resistance [44, 45]. TiO2 NPs reinforced PNCs have been shown to display considerable antibacterial activity, mechanical, dielectric and flame retardant properties [46,47,48].
The EMI shielding properties of various PNCs or hybrid materials have been investigated by several authors owing to their superior electrical properties. For example; Sabira et al. [49] developed 20 μm thick, flexible, and mechanically stable PVDF/graphene nanocomposite films and observed an EMI SE value of 47 dB in the X-band frequency region. Hamidinejad et al. [50] fabricated high-density polyethylene/GNPs composite foams by supercritical fluid treatment and physical foaming process. The resultant composite foam exhibited an EMI SE of 31.6 dB at 19 vol% GNPs loading. In another study, Vyas and Chandra [23] reported poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanocomposite films comprising multi-walled carbon nanotubes (MWCNTs) as an electron-conducting network and barium titanate (BaTiO3) as ferroelectric ceramic nanofiller. The resultant composite exhibited EMI SE value of ~ 81 dB in the X-band (8–12 GHz) region. These studies demonstrate that several factors such as size, shape, structure, thickness, filler content, conductivity and percolation threshold are responsible for achieving enhanced EMI SE of PNCs [38, 49,50,51]. Also, increasing the nanofiller content into the polymer matrix leads to an improved conductivity and low leakage current of the nanocomposites thereby providing enhanced EMI SE values [23]. Thus, with this background knowledge, in the present work, GNPs, MMT and TiO2 NPs reinforced PVDF nanocomposites were prepared and their dielectric and EMI shielding properties were examined.
2 Experimental Procedure
2.1 Materials
PVDF powder was purchased from Pragati Plastics PVT Ltd., New Delhi, India. GNPs (Type 1) of carbon content 99.5%, thickness 6–8 nm and average particle size of 15 μm and MMT nanopowder of average particle size 80–150 nm and elemental compositions SiO2-65%, Al2O3-15%, Fe2O3-1.3%, Ti2O-0.19%, K2O-1.3%, Na2O-0.65%, CaO-3.31% and MgO-0.99% was purchased from Sisco Research Laboratories (SRL) Pvt. Ltd., Mumbai, India. TiO2 NPs employed in this study was AEROXIDE hydrophilic fumed TiO2 P25 with an average particle size of 21 nm, high specific surface area of 50 ± 15 m2/g and crystallographic composition of 80% anatase and 20% rutile was supplied by Degussa, Germany. N, N-dimethylformamide (DMF) with > 99% purity used as the solvent in the present study was supplied by Qualigens Fine Chemicals, Mumbai, India.
2.2 Preparation of PVDF/GNPs/MMT/TiO2 Nanocomposite Films
The PVDF/GNPs/MMT/TiO2 nanocomposite films were prepared using the solution casting method as illustrated in Fig. 1. The feed compositions used for the preparation of nanocomposite films are shown in Table 1. Initially, the desired amount of PVDF powder was dissolved in 20 ml DMF by heating at 70 °C in the hot air oven until a clear solution was obtained. Meanwhile, GNPs were dispersed in 15 ml DMF and sonicated using an ultrasonic bath (Model: LMUC-2, capacity 2 l, ultrasonic frequency 40 kHz, heating ambient to 80 °C, timer 0 to 60 min, power supply 220 V, 50 Hz) for 1 h. Similarly, the TiO2 NPs and MMT nanopowder was dispersed separately in 15 ml DMF by ultrasonication. The sonicated GNPs dispersion was then added to the PVDF solution followed by continuous stirring for 3 h. Likewise, the sonicated TiO2 NPs and MMT nanoclay dispersions were respectively added to the PVDF/GNPs mixture. Later, the resulting PVDF/GNPs/MMT/TiO2 mixture was stirred vigorously overnight at room temperature to obtain a homogeneous dispersion of nanofillers into the polymer matrix. Finally, the homogeneous PVDF/GNPs/MMT/TiO2 dispersion was poured onto the Teflon Petri dish and dried at 60 °C for 6 h to obtain PVDF/GNPs/MMT/TiO2 nanocomposite films that were used for further characterizations.
2.3 Characterization Details
The FTIR spectra of pristine PVDF and PVDF/GNPs/MMT/TiO2 nanocomposite films were obtained using Fourier transform infrared spectrophotometer (Shimadzu, IR Tracer-100, Japan) in the transmission mode within 400 to 4000 cm−1 wavenumber range.
The XRD patterns of pristine PVDF, GNPs, MMT, TiO2 NPs and PVDF/GNPs/MMT/TiO2 nanocomposite films were taken using the X-ray source (Philips XPert MPD diffractometer, Eindhoven, The Netherlands) with Cu Kα radiation of wavelength λ = 1.5406 Å in the 2θ range from 10 to 80° with 1°/min scanning speed and 0.01° step size.
The surface morphology of PVDF/GNPs/MMT/TiO2 nanocomposite films was evaluated using the field emission scanning electron microscope (FESEM; Tescan, MIRA3, Czech Republic) at different magnifications with an applied accelerating voltage of 20 kV.
Dielectric properties of the prepared PVDF/GNPs/MMT/TiO2 nanocomposite films were studied using a frequency response impedance analyzer (N4L PSM 1735 NumetriQ, UK). The nanocomposite films were examined as a function of frequency ranging from 50 Hz to 20 MHz at different temperatures.
The EMI SE properties of PVDF and PVDF/GNPs/MMT/TiO2 nanocomposite films were measured by using an 8510C vector network analyzer (VNA), Agilent Technologies, USA, in Ku-band (12–18 GHz) frequency region.
3 Results and Discussion
3.1 FTIR Spectroscopy
Figure 2 shows the FTIR transmittance spectra of pristine PVDF, PVDF/GNPs/MMT/TiO2 and PVDF/GNPs/TiO2 nanocomposite films for different content of GNPs, MMT and TiO2 NPs into the PVDF matrix. In the FTIR spectrum of pristine PVDF (Fig. 2a), the small peaks at 3014 cm−1 and 2978 cm−1 are attributed to symmetric and asymmetric stretching vibrations of –CH2 group respectively [29]. The peak at 1400 cm−1 can be assigned to –CH2 bending vibrations while the peaks at 1067, 1160 and 1400 cm−1 show the presence of the α-PVDF phase [46]. The peak at 893 cm−1 can be assigned to CH2 rocking and CF2 asymmetric stretching vibrations. Moreover, the peaks at 822, 893 and 1331 cm−1 show the presence of the β-PVDF phase [52, 53]. The peaks around 621 cm−1 can be assigned to –CF2 bending while the peak at 490 cm−1 can be attributed to –CF2 bending and wagging vibrations [53]. The FTIR spectra of PVDF/GNPs/MMT/TiO2 nanocomposites (Fig. 2b–g) show new peaks due to the incorporation of GNPs, MMT and TiO2 NPs into the PVDF matrix. The peaks appearing at 1055 cm−1 can be assigned to stretching vibrations of the Si–O group while the peaks at 540 cm−1 and 473 cm−1 are attributed to Al–O and Si–O–Si bending vibrations respectively. Also, the peak at 625 cm−1 can be assigned for Al–O and Si–O out of plane vibrations of MMT [54]. The peaks for GNPs at 1067 and 1160 cm−1 are merged with peaks of PVDF and the peak corresponding to the stretching vibrations of Ti–O–Ti bonds of TiO2 NPs appears at 462 cm−1 [46]. Therefore, the FTIR spectra of PVDF/GNPs/MMT/TiO2 nanocomposites confirm the good interaction of nanofillers and the PVDF matrix.
3.2 XRD Analysis
The XRD patterns of pristine PVDF, TiO2 NPs, GNPs and MMT nanoclay are shown in Fig. 3. The pristine PVDF showed a characteristic diffraction peak at 2θ = 20.05° which is attributed to the (110) crystal plane of α-phase while the second peak at 2θ = 44.65° is attributed to the (200) crystal plane of β-phase [21]. Besides, the diffraction pattern of PVDF also showed another prominent peak at 2θ = 64.95° which can be attributed to the (220) crystal plane [21]. The diffraction pattern of TiO2 NPs showed several prominent XRD peaks at 2θ = 25.24° (101), 2θ = 27.58° (110), 2θ = 37.98° (004), 2θ = 48.22° (200), 2θ = 53.98° (105), 2θ = 55.22° (211), 2θ = 62.76° (204), 2θ = 68.98° (116), 2θ = 70.36° (220) and 2θ = 75.28° (215) which are attributed to 80% anatase and 20% rutile crystallographic compositions [16]. The XRD pattern of GNPs showed a sharp and intense diffraction peak at 2θ = 26.44° and a small peak at 2θ = 54.52° demonstrating the highly crystalline graphite-like structure [55, 56]. The XRD pattern of MMT nanoclay also displayed several prominent diffraction peaks associated with its lamellar structure. The diffraction peak at 2θ = 12.52° is attributed to (001) reflection while the peaks at 2θ = 20.62° (100) and 2θ = 35.08° (110) are associated with pyrophyllite mineral phase of MMT [57, 58]. The XRD patterns of PVDF/GNPs/MMT/TiO2 and PVDF/GNPs/TiO2 nanocomposite films are depicted in Fig. 4. All the characteristics diffraction peaks of the polymer matrix and the nanofillers were observed in the XRD patterns of the nanocomposite films. However, the intensity of these XRD peaks in nanocomposites was lower as compared with the intensity of the XRD peaks of pristine components. This suggests good compatibility and strong interaction between the polymer matrix and the nanofillers that resulted in the formation of homogeneous nanocomposites.
3.3 FESEM Analysis
Figure 5a–f shows FESEM images of three varied compositions of PVDF/GNPs/MMT/TiO2 nanocomposite films at different magnifications which revealed that the nanofillers i.e. GNPs, MMT and TiO2 NPs are homogeneously dispersed within the PVDF matrix. The FESEM image of PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-1%, MMT-4% and TiO2-10% (Fig. 5a) shows randomly distributed intercalated layered stacks of MMT and also shows evenly distributed GNPs and TiO2 NPs. On higher loading of GNPs and TiO2 NPs with a decrease in MMT loading, the FESEM image of PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-2%, MMT-2% and TiO2-11% (Fig. 5b) shows some aggregation of TiO2 NPs with segregated GNPs. However, the little aggregation of TiO2 NPs with the intercalated layers of MMT enhances the properties of the nanocomposites. On further increasing the TiO2 NPs loading along with GNPs, the FESEM image of PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-2%, MMT-2% and TiO2-11% (Fig. 5c) showed big aggregates of TiO2 NPs. The FESEM micrographs of the nanocomposites demonstrates the uniform distribution of nanofillers throughout the PVDF matrix.
3.4 Dielectric Properties
In the present study, the dielectric properties of the prepared nanocomposite films were investigated and the dielectric constant was determined using the relation [59];
where Cp is capacitance, t is thickness of the film, ε0 is permittivity of free space, A is area of the film.
Figure 6a–g shows the variation in dielectric constants for pristine PVDF and PVDF/GNPs/MMT/TiO2 nanocomposite films as a function of frequency for various temperatures. The maximum value of the dielectric constant observed for pristine PVDF film was 47.11 at 50 Hz and 150 °C. On incorporating the nanofillers into the PVDF matrix, the dielectric constant of the nanocomposites increased i.e. for PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-0.5%, MMT-5% and TiO2-9.5%, the maximum dielectric constant value was found to be 66.94 at 50 Hz and at 150 °C. On higher loading of GNPs and TiO2 NPs with decreasing MMT loading, the dielectric constant of the nanocomposites reached the maximum value of 210.92 at 50 Hz and at 150 °C for PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-2%, MMT-2% and TiO2-11%. The high aspect ratio of GNPs and MMT effectively enhances the dielectric properties of the nanocomposites. Also, the fact that the addition of conducting fillers such as GNPs acts as electrodes and non-conducting counterparts as MMT and TiO2 NPs act as a dielectric medium, when they are embedded into the polymer matrix forming microcapacitors [46]. It can be observed that all the nanocomposite films exhibit high dielectric constant values at low frequencies. When the frequency was increased, the dielectric constant decrease to very low values. This can be attributed to the interfacial polarization or Maxwell–Wagner–Sillar (MWS) effect [60], i.e. the dielectric constants are higher at lower frequencies due to the induced and permanent dipoles which get aligned easily in this region. When the frequencies are higher, the dipoles have no time to get aligned, i.e., decreasing interfacial polarization or MWS effect [61]. On further increasing the concentration of GNPs and TiO2 NPs and decreasing MMT loading, the dielectric constant values decrease. This can be due to the agglomeration of TiO2 NPs and further settling down on GNPs that deteriorate the dielectric properties of the nanocomposites.
Dielectric loss is another important parameter of dielectric materials that results from the inability of the polarization to follow the rate of change of applied electric field. In general, the distortional, dipolar, interfacial, and conduction loss in the dielectric materials constitutes the dielectric loss of the material [60]. Figure 7a–g show the variations in the dielectric loss tangents for pristine PVDF and PVDF/GNPs/MMT/TiO2 nanocomposite films as a function of frequency at various temperatures. The maximum value of dielectric loss tangent observed for pristine PVDF film was 5.4 at 50 Hz and 150 °C. For PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-2%, MMT-2% and TiO2-11%, the maximum dielectric loss tangent value was found to be 10.4 at 50 Hz and 150 °C. This indicates that the addition of conducting GNPs into the polymer increases the conductivity of the nanocomposites which leads to the leakage of charge current causing an increase in loss tangent values [62, 63]. However, the dielectric constant values of all the nanocomposites are very much higher than their respective dielectric loss tangent values. This can be attributed to the good dispersion of nanofillers into the polymer matrix [60]. Table 2 gives the maximum dielectric constant and loss tangent values of the prepared nanocomposite films.
3.5 EMI SE
Figure 8 shows the EMI SE graph in the Ku band region for pristine PVDF and the PVDF/GNPs/MMT/TiO2 nanocomposites. The pristine PVDF film shows EMI SE of ~ 5.39 dB, which indicates its transparent shielding nature to EMI [4]. After the incorporation of nanofillers into the PVDF, the EMI SE raises to ~ 10.3 dB for PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-0.5%, MMT-5% and TiO2-9.5%, then to ~ 11.5 dB for PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-2%, MMT-2% and TiO2-11%. The maximum value of EMI SE attained for the prepared nanocomposites was ~ 12.6 dB for PVDF/GNPs/MMT/TiO2 nanocomposite film with GNPs-2.5%, MMT-1% and TiO2-11.5%. This increase in EMI SE can be attributed to the increased conductivity of nanocomposites due to the incorporation of GNPs. This shows that the GNPs form interconnected layers of conducting network and high specific surface area is provided by MMT and TiO2 NPs. The effective enhancement in EMI SE can also be due to the attenuation in the scattering of EM waves using TiO2 NPs [16]. The intercalated layers of MMT with its high aspect ratio along with GNPs i.e. flake or disc-like pieces play an effective role in absorbing the EM radiation [64]. Further enhancement of EMI SE can also be possible with increased loading of nanofillers into the PVDF matrix, but the mechanical stability of the resulting nanocomposite gets deteriorated on a higher concentration of fillers [8]. For the maximum loading of GNPs and TiO2 NPs i.e., for PVDF/GNPs/TiO2 nanocomposite film with GNPs-3% and TiO2-12%, the EMI SE value slightly decreases as compared with the lower loadings of GNPs and TiO2 NPs. Table 3 depicts the literature survey for EMI SE of various PNCs [2, 5, 16, 23, 49, 64,65,66]. Therefore, with minimal incorporation of GNPs, MMT and TiO2 NPs, a significant enhancement in EMI SE was observed which signifies that this nanocomposite material can be a potential candidate for EMI shielding application.
4 Conclusions
In the present work, PVDF/GNPs/MMT/TiO2 nanocomposite films were successfully prepared using the solution casting method. The properties of prepared nanocomposites were investigated using different analysis techniques such as FTIR, XRD, FESEM and dielectric analysis. The FTIR results infer good interaction between the nanofillers and the polymer matrix. FESEM micrographs demonstrate the homogenous dispersion of the nanofillers in the polymer matrix. The good interaction between the nanofillers and the polymer matrix with the homogeneous dispersion of the nanofillers within the polymer matrix led to the enhancement of the dielectric properties of the nanocomposites. The maximum dielectric constant of PVDF film was found to be 47.11 at 50 Hz, 150 °C and that of the PVDF/GNPs/MMT/TiO2 nanocomposite film was observed to be 210.92 at 50 Hz, 150 °C for GNPs-2%, MMT-2% and TiO2-11% loading. This value of the dielectric constant of nanocomposite film was 4.5 times greater than that of pristine PVDF film. On the other hand, the maximum dielectric loss tangent value was determined to be 10.4 at 50 Hz, 150 °C for the same compositions of the PVDF/GNPs/MMT/TiO2 nanocomposite film which can be due to the increased conductivity of the nanocomposites. The maximum EMI SE of 12.6 dB was obtained in the Ku-band region for PVDF/GNPs/MMT/TiO2 nanocomposites with GNPs-2.5%, MMT-1% and TiO2-11.5% loading. The enhanced EMI SE values in the Ku-band frequency region can be attributed to the higher aspect ratio of nanofillers and the formation of conducting interconnected network between the nanofillers and the PVDF matrix. The obtained results suggest the potential of the prepared nanocomposites as an EMI shielding material.
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Acknowledgement
The authors Dr. M. Basheer Ahamed and A. Harish Kumar are very grateful to the Department of Science and Technology-Science and Engineering Research Board (DST-SERB), Government of India, for providing the financial support to this research work under the sanctioned Project Number EMR/2016/006705.
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Harish Kumar, A., Ahamed, M.B., Deshmukh, K. et al. Morphology, Dielectric and EMI Shielding Characteristics of Graphene Nanoplatelets, Montmorillonite Nanoclay and Titanium Dioxide Nanoparticles Reinforced Polyvinylidenefluoride Nanocomposites. J Inorg Organomet Polym 31, 2003–2016 (2021). https://doi.org/10.1007/s10904-020-01869-z
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DOI: https://doi.org/10.1007/s10904-020-01869-z