Abstract
Urban expansion into traditional agricultural lands has augmented the potential for heavy metal contamination of soils. This study examined the utility of field portable X-ray fluorescence (PXRF) spectrometry for evaluating the environmental quality of sugarcane fields near two industrial complexes in Louisiana, USA. Results indicated that PXRF provided quality results of heavy metal levels comparable to traditional laboratory analysis. When coupled with global positioning system technology, the use of PXRF allows for on-site interpolation of heavy metal levels in a matter of minutes. Field portable XRF was shown to be an effective tool for rapid assessment of heavy metals in soils of peri-urban agricultural areas.
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References
Bartkiewicz, S. A., & Hammatt, E. A. (1964). X-ray fluorescence determination of cobalt, zinc, and iron in organic matrices. Analytical Chemistry, 36(4), 833–836.
Chen, M., & Ma, L. Q. (1998). Comparison of four USEPA digestion methods for trace metal analysis using certified and Florida soils. Journal of Environmental Quality, 27(6), 1294–1300.
Delgado, J., Nieto, J. M., & Boski, T. (2010). Analysis of the spatial variation of heavy metals in the Guadiana Estuary sediments (SW Iberian Peninsula) based on GIS-mapping techniques. Esturaine, Coastal and Shelf Science, 88, 71–83.
Devall, M. S., Thien, L. B., Ellgaard, E., & Flowers, G. (2006). Lead transport into Bayou Trepagnier wetlands in Louisiana, USA. Journal of Environmental Quality, 35, 758–765.
Dia, M., Weindorf, D. C., Thompson, C., Cummings, H., Rusu, T., & Cacovean, H. (2009). Spatial distribution of heavy metals in the soils of Erath County, Texas. Studia Geographia, 54(2), 99–114.
Environmental Protection Agency (1996). “Method 3050B. Acid Digestion of Sediments, Sludges, and Soils.” Revision 2 (December1996).” In Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, EPA SW-846, Third Ed., Vol. I, Section A, Chapter 3 (Inorganic Analytes), pp. 3050B-1-3050B-12, U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response, Washington, D.C. Available at: http://www.epa.gov/epaoswer/hazwaste/test/pdfs/3050b.pdf.
Environmental Protection Agency (2010). Method 6200: Field portable X-ray fluorescence spectrometry for the determination of elemental concentrations in soil and sediment [online]. Available at http://www.epa.gov/. Verified 14 Jun 2010.
Food and Agriculture Organization of the United Nations (1999). Issues in urban agriculture [online]. Available at http://www.fao.org/ag/magazine/9901sp2.htm. Accessed 7 Jan 2010.
Grousset, F. E., Quetel, C. R., Thomas, B., Donard, O. F., Lambert, C. E., Guillard, F., & Monaco, A. (1995). Anthropogenic vs. lithogenic origins of trace elements (As, Cd, Pb, Rb, Sb, Sc, Sn, Zn) in water column particles: Northwestern Mediterranean Sea. Marine Chemistry, 48, 291–310.
Hao, X. Z., Zhou, D. M., Huang, D. Q., Cang, L., Zhang, H. L., & Wang, H. (2009). Heavy metal transfer from soil to vegetable in southern Jiangsu Province, China. Pedosphere, 19(3), 305–311.
Herut, B., Hornung, H., Krom, M. D., Kress, N., & Cohen, Y. (1993). Trace metals in shallow sediments from the Mediterranean coastal region of Israel. Marine Pollution Bulletin, 26(12), 657–682.
Horowitz, A. J., Elrick, K. A., Demas, C. R., & Demcheck, D. K. (1991). The use of sediment-trace element geochemical models for the identification of local fluvial baseline concentration. In: Sediment and Stream Water Quality in a Changing Environment: Trends and Explanation—Proceeding of the Vienna Symposium, August 1991. IAHS Publ. no. 203, 339–348.
Hu, K. L., Zhang, F. R., Li, H., Huang, F., & Li, B. G. (2006). Spatial patterns of soil heavy metals in urban–rural transition zone of Beijing. Pedosphere, 16(6), 690–698.
Ingwersen, J., & Streck, T. (2006). Modeling the environmental fate of cadmium in a large wastewater irrigation area. Journal of Environmental Quality, 35, 1702–1714.
Innov-X Systems (2010). DeltaTM Family: Handheld XRF Analyzers User Manual. Innov-X Systems, Inc. pp. 124.
Largueche, F. Z. B. (2006). Estimating soil contamination with kriging interpolation method. American Journal of Applied Science, 3(6), 1894–1898.
Li, J., Lu, Y., Yin, W., Gan, H., Zhang, C., Deng, X., & Lian, J. (2008). Distribution of heavy metals in agricultural soils near a petrochemical complex in Guangzhou, China. Environmental Monitoring and Assessment, 153, 365–375. doi:10.1007/s10661-008-0363-x.
Loring, D. H. (1991). Normalization of heavy-metal data from estuarine and coastal sediments. ICES Journal of Marine Science, 48, 101–115.
Loska, K., & Wiechula, D. (2003). Application of principal component analysis for the estimation of source of heavy metal contamination in surface sediments from the Rybnik Reservoir. Chemosphere, 51, 723–733.
Minasny, B., & McBratney, A. (2006). A conditioned Latin hypercube method for sampling in the presence of ancillary information. Computers and Geosciences, 32, 1378–1388.
Sharman, P., Borole, D. V., & Zigde, M. D. (1984). 210 Pb based trace element fluxes in the nearshore and estuarine sediments of Bombay, India. Marine Chemistry, 47, 227–241.
Soil Survey Staff (2004). Soil survey laboratory methods manual. USDA-NRCS, Washington, DC.
Sollitto, D., Romic, M., Castrignano, A., Romic, D., & Bakic, H. (2010). Assessing heavy metal contamination in soils of the Zagreb Region (Northwest Croatia) using multivariate geostatistics. Catena, 80, 182–194.
Stehouwer, R., Day, R. L., & Macneal, K. E. (2006). Nutrient and trace element leaching following mine reclamation with biosolids. Journal of Environmental Quality, 35, 1118–1126.
US Composting Council (2002). Test methods for the evaluation of composts and composting [CD-ROM computer file]. USCC, Rokonkoma, NY.
Weber, D. D., & Englund, E. J. (1994). Evaluation and comparison of spatial interpolators II. Mathematical Geology, 26(5), 589–603.
Welt, M., Mielke, H. W., Gonzales, C., Cooper, K. M., Batiste, C. G., Cresswell, L. H., & Mielke, P. W. (2003). Metal contamination of sediments and soils of Bayou Saint John: A potential health impact to local fishermen? Environmental Geochemistry and Health, 25, 387–396.
Zhang, H. H., Li, F. B., Wu, Z. F., Li, D. Q., Xu, D. R., & Yuan, H. X. (2008). Baseline concentrations and spatial distribution of trace metals in surface soils of Guangdong Province, China. Journal of Environmental Quality, 37, 1752–1760.
Zhao, Y. F., Shi, X. Z., Huang, B., Yu, D. S., Wang, H. J., Sun, W. X., Öboern, I., & Blomback, K. (2007). Spatial distribution of heavy metals in agricultural soils of an industry-based peri-urban area in Wuxi, China. Pedosphere, 17(1), 44–51.
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Weindorf, D.C., Zhu, Y., Chakraborty, S. et al. Use of portable X-ray fluorescence spectrometry for environmental quality assessment of peri-urban agriculture. Environ Monit Assess 184, 217–227 (2012). https://doi.org/10.1007/s10661-011-1961-6
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DOI: https://doi.org/10.1007/s10661-011-1961-6