Abstract
Thirty-five surface sediment samples from the Indian continental shelf were recovered offshore from the mouths of the major rivers (Brahmaputra, Ganges, Narmada, Tapti, Godavari, Krishna and Cauvery) discharging into the coastal region of both east and west coasts were analysed using inductively coupled plasma atomic emission spectroscopy for selected major (i.e. Al, Ca, Fe, K, Ti, Mg and Na) and trace elements (e.g. Ba, Co, Cr, Cu, Ga, Ni, P and V), after total dissolution. The main objectives are to understand the processes controlling major and trace elements in the surface sediments and to identify natural and anthropogenic sources in the coastal environment using statistically regressed elemental concentrations to establish regional baseline levels. Metal enrichments observed close to the major urban areas in the east and west coasts are associated with the industrialised activities areas rich in Cu and Co in both the east and west coast sediments. Normalisation of metals to Al indicated that high enrichment factors are in the order of Ca>Ti≥Fe>Na>Mg>Co>Cu>Ga>V>Ba except K and P depletion. This indicated that the characteristic of estuarine sediment showed higher level along the west coast of India, which was reflected in the coastal sediments as similar to the source of its origin from the riverine composition and its abundances.
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References
Alagarsamy, R., & Zhang, J. (2005). Comparative studies on trace metal geochemistry in Indian and Chinese rivers. Current Science, 89, 299–309.
Alagarsamy, R. (2006). Distribution and seasonal variation of trace metals in surface sediments of Mandovi estuary, Goa in the west coast of India. Estuarine, Coastal and Shelf Science, 67(1–2), 333–339. doi:10.1016/j.ecss.2005.11.023.
Bianchini, G., Laviano, R., Lovo, S., & Vaccaro, C. (2002). Chemical–mineralogical characterisation of clay sediments around Ferrara (Italy): A tool for an environmental analysis. Applied Clay Science, 21(3–4), 165–176. doi:10.1016/S0169-1317(01)00086-2.
Biksham, G., & Subramanian, V. (1988). Elemental composition of Godavari sediments (Central and Southern Indian Subcontinent). Chemical Geology, 70, 275–286. doi:10.1016/0009-2541(88)90098-8.
Bishop, J. K., Edmond, J. M., Ketten, D. R., Bacon, M. P., & Silker, W. B. (1977). The chemistry, biology, and vertical flux of particulate matter from the upper 400 m of the equatorial Atlantic Ocean. Deep-Sea Research, 24, 511–548. doi:10.1016/0146-6291(77)90526-4.
Bowen, H. J. M. (1979). Environmental chemistry of the elements (pp. 1–320). New York: Academic.
Broecker, W. S., & Peng, T.-H. (1982). Tracers in the sea. New York: Eldigio.
Bruland, K. W. (1980). Oceanographic distributions of cadmium, zinc, nickel and copper in the North Pacific. Earth and Planetary Science Letters, 47, 176–198. doi:10.1016/0012-821X(80)90035-7.
Brumsack, H. J. (2006). The trace metal content of recent organic carbon-rich sediments: Implications for Cretaceous black shale formation. Palaeogeography, Palaeoclimatology, Palaeoecology, 232, 344–361.
Collier, R., & Edmond, J. (1984). The trace element geochemistry of marine biogenic particulate matter. Progress in Oceanography, 13, 113–199. doi:10.1016/0079-6611(84)90008-9.
Das, A., & Krishnaswami, S. (2006). Barium in Deccan Basalt Rivers: Its abundance, relative mobility and flux. Aquatic Geochemistry, 12, 221–238. doi:10.1007/s10498-005-5856-4.
Horowitz, A. J., Elrick, K., & Callender, E. (1988). The effect of mining on the sediment-trace element geochemistry of cores from the Cheyenne River arms of Lake OaheSouth Dakota, USA. Chemical Geology, 67, 17–33. doi:10.1016/0009-2541(88)90003-4.
Jonathan, M. P., Ram-Mohan, V., & Srinivaslu, S. (2004). Geochemical variations of major and trace elements in recent sediments, off the Gulf of Mannar, the southeast coast of India. Environmental Geology, 45, 466–480. doi:10.1007/s00254-003-0898-7
Kolla, V., Bà, A. W. H., & Biscaye, P. E. (1976a). Calcium carbonate distribution in the surface sediments of the Indian Ocean. Journal of Geophysical Research, 81, 2605–2616. doi:10.1029/JC081i015p02605.
Kolla, V., & Biscaye, P. E. (1973). Clay mineralogy and sedimentation in the eastern Indian Ocean. Deep-Sea Research, 20, 727–738.
Kolla, V., & Biscaye, P. E. (1977). Distribution and origin of quartz in the sediments of the Indian Ocean. Journal of Sedimentary Petrology, 47, 642–649.
Kolla, V., Henderson, L., & Biscaye, P. E. (1976b). Clay mineralogy and sedimentation in the western Indian Ocean. Deep-Sea Research, 23, 949–961.
Kolla, V., Kostecki, J. A., Robinson, F., Biscaye, P. E., & Ray, P. K. (1981a). Distribution and origin of clay minerals and quartz in surface sediments of the Arabian Sea. Journal of Sedimentary Petrology, 51, 563–569.
Kolla, V., Ray, P. K., & Kostecki, J. A. (1981b). Surficial sediments of the Arabian Sea. Marine Geology, 41, 183–204. doi:10.1016/0025-3227(81)90080-3.
Krishnan, M. S. (1968). Geology of India and Burma (p. 536). Madras: Higginbothoms Ltd.
Loring, D. H. (1991). Normalization of heavy-metal data from estuarine and coastal sediments. ICES Journal of Marine Sciences, 48, 101–115.
Martin, J. M., & Meybeck, M. (1979). Elemental mass-balance of material carried by major world rivers. Marine Chemistry, 7, 173–206. doi:10.1016/0304-4203(79)90039-2.
Mil-Homens, M., Stevens, R. L., Abrantes, F., & Cato, I. (2006). Heavy metal assessment for surface sediments from three areas of the Portuguese continental shelf. Continental Shelf Research, 26, 1184–1205. doi:10.1016/j.csr.2006.04.002.
Nolting, R. F., Ramkema, A., & Everaarts, J. M. (1999). The geochemistry of Cu, Cd, Zn, Ni and Pb in sediment cores from the continental slope of the Banc d’Arguin (Mauritania). Continental Shelf Research, 19, 665–691.
Paropkari, A. L. (1990). Geochemistry of sediments from the Mangalore-Cochin shelf and upper slope off southwest India: Geological and environmental factors controlling dispersal of elements. Chemical Geology, 81, 99–119. doi:10.1016/0009-2541(90)90041-5.
Paropkari, A. L., Rao, Ch. M., & Murty, P. S. N. (1978). Geochemical studies on the shelf sediments off Bombay. Indian Journal of Marine Sciences, 7, 8–11.
Pedersen, T., Shimmield, G. B., & Price, N. B. (1992). Lack of enhanced preservation of organic matter in sediments under the oxygen minimum on the Oman margin. Geochimica et Cosmochimica Acta, 56, 545–551. doi:10.1016/0016-7037(92)90152-9.
Ramanathan, A. L., Vaithiyanathan, P., Subramanian, V., & Das, B. K. (1993). Geochemistry of the Cauvery estuary, East Coast of India. Estuaries, 16, 459–474. doi:10.2307/1352594.
Ramaswamy, V., & Nair, R. R. (1989). Lack of cross shelf transport of sediments on the western margin of India: Evidence of clay mineralogy. Journal of Coastal Research, 5, 541–546.
Ramesh, R., Subramanian, V., & Van Grieken, R. (1990). Heavy metal distribution in sediments of Krishna river basin, India. Environmental Geology and Water Sciences, 15, 207–216. doi:10.1007/BF01706412.
Rao, Ch. M. (1978). Distribution of CaCO3, Cu2 + and Mg2 + in sediments of the northern half of western continental shelf of India. Indian Journal of Marine Sciences, 7, 151–154.
Rao, Ch. M. (1985). Distribution of suspended particulate matter in the waters of eastern continental margin of India. Indian Journal of Marine Sciences, 14, 15–19.
Rao, K. L. (1975). India’s water wealth (p. 255) New Delhi: Orient Longman.
Rao, K. L. (1979). India’s water wealth: Its assessment, uses and projections (p. 267). New Delhi: Orient Longman.
Rao, V. P. (1991). Clay mineral distribution in the continental shelf and slope off Saurashtra, west coast of India. Indian Journal of Marine Sciences, 20, 1–6.
Rao, V. P., Rajagopalan, G., Vora, K. H., & Almeida, F. (2003). Late Quaternary sea level and environmental changes from relic carbonate deposits of the western margin of India. Journal of Earth System Science, 112, 1–25. doi:10.1007/BF02710040.
Rao, V. P., & Rao, B. R. (1995). Provenance and distribution of clay minerals in the sediments of the western continental shelf and slope of India. Continental Shelf Research, 15, 1757–1771. doi:10.1016/0278-4343(94)00092-2.
Rubio, B., Nombela, M. A., & Vilas, F. (2000). Geochemistry of major and trace elements in sediments of the Ria de Vigo (NW Spain): An assessment of metal pollution. Marine Pollution Bulletin, 40, 968–980. doi:10.1016/S0025-326X(00)00039-4.
Saager, P. M., DeBaar, H. J. W., & Howland, R. J. (1992). Cd, Zn, Ni and Cu in the Indian Ocean. Deep-Sea Research, 39, 9–35. doi:10.1016/0198-0149(92)90017-N.
Santos, I. R., Silva Filho, E. V., Schaefer, C. E., Albuquerque-Filho, M. R., & Campos, L. S. (2005). Heavy metal contamination in coastal sediments and soils near the Brazilian Antarctic Station, King George Island. Marine Pollution Bulletin, 50, 185–194. doi:10.1016/j.marpolbul.2004.10.009.
Sarkar, S. K., Bilinski, S. F., Bhattacharya, A., Saha, M., & Bilinski, H. (2004). Levels of elements in the surficial estuarine sediments of the Hugli River, northeast India and their environmental implications. Environment International, 30, 1089–1098. doi:10.1016/j.envint.2003.10.009.
Selvaraj, K., Ram Mohan, V., & Szefer, P. (2004). Evaluation of metal contamination in coastal sediments of the Bay of Bengal, India: Geochemical and statistical approaches. Marine Pollution Bulletin, 49, 174–185. doi:10.1016/j.marpolbul.2004.02.006.
Shankar, R., Subbarao, K. V., & Kolla, V. (1987). Geochemistry of surface sediments from the Arabian Sea. Marine Geology, 76, 253–279. doi:10.1016/0025-3227(87)90033-8.
Shimmield, G. B., Price, N. B., & Pedersen, T. F. (1990). The influence of hydrography, bathymetry and productivity on sediment type and composition of the Oman Margin and in the northwest Arabian Sea. In A. H. F. Robertson, M. P. Searle, & A. C. Ries (Eds.), The geology and tectonics of the Oman Region (pp. 759–769). Geological Society Special Publication.
Sirocko, F., Garbe-Schönberg, D., & Devey, C. (2000). Processes controlling trace element geochemistry of Arabian Sea sediments during the last 25,000 years. Global and Planetary Change, 26, 217–303. doi:10.1016/S0921-8181(00)00046-1.
Subramanian, V., Jha, P. K., & Van Grieken, R. (1988). Heavy metals in the Ganges estuary. Marine Pollution Bulletin, 19, 290–293. doi:10.1016/0025-326X(88)90602-9.
Taylor, S. R. (1964). The abundance of chemical elements in the continental crust–a new table. Geochimica et Cosmochimica Acta, 28, 1373–1285.
Turekian, K. K., & Wedepohl, K. H. (1961). Distribution of the elements in some major units of the earth’s crust. Geological Society of America Bulletin, 72, 175–192.doi:10.1130/0016-7606(1961)72[175:DOTEIS]2.0.CO;2.
Zhang, J. (1995). Geochemistry of trace metals from Chinese river/estuary systems: An overview. Estuarine, Coastal and Shelf Science, 41, 631–658. doi:10.1006/ecss.1995.0082.
Zhang, J., & Liu, C. L. (2002). Riverine composition and estuarine chemistry of particulate metals in China—Weathering features, anthropogenic impact and chemical fluxes. Estuarine, Coastal and Shelf Science, 54, 1051–1070. doi:10.1006/ecss.2001.0879.
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Alagarsamy, R., Zhang, J. Geochemical characterisation of major and trace elements in the coastal sediments of India. Environ Monit Assess 161, 161–176 (2010). https://doi.org/10.1007/s10661-008-0735-2
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DOI: https://doi.org/10.1007/s10661-008-0735-2