Abstract
4D printing has attracted great interest since the concept was introduced in 2012. The past 5 years have witnessed rapid advances in both 4D printing processes and materials. Unlike 3D printing, 4D printing allows the printed part to change its shape and function with time in response to change in external conditions such as temperature, light, electricity, and water. In this review, we first overview the history of 4D printing and discuss its definition. We then summarize recent technological advances in 4D printing with focuses on methods, materials, and their intrinsic links. Finally, we discuss potential applications and offer perspectives for this exciting new field.
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References
Hull, C. W., 1986, U.S. Pat., 5, 556, 590
Bower, C., Meitl, M., Gomez, D., Bonafede, S. and Kneeburg, D., 2016, U.S. Pat., 9358775
Tofail, S. A. M.; Koumoulos, E. P.; Bandyopadhyay, A.; Bose, S.; O’Donoghue, L.; Charitidis, C. Additive manufacturing: scientific and technological challenges, market uptake and opportunities. Materialstoday, in press.
Shirazi, S. F. S.; Gharehkhani, S.; Mehrali, M.; Yarmand, H.; Metselaar, H. S. C.; Kadri, N. A.; Osman, N. A. A. A review on powder-based additive manufacturing for tissue engineering: selective laser sintering and inkjet 3D printing. Sci. Technol. Adv. Mat. 2015, 16(3), 033502
Tumbleston, J. R.; Shirvanyants, D.; Ermoshkin, N.; Janusziewicz, R.; Johnson, A. R.; Kelly, D.; Chen, K.; Pinschmidt, R.; Rolland, J. P.; Ermoshkin, A. Additive manufacturing. Continuous liquid interface production of 3D objects. Science 2015, 347(6228), 1349–1352
Geier, B., Local Motors shows Strati, the world’s first 3D-printed car. http://fortune.com/2015/01/13/local-motors-shows-stratithe-worlds-first-3d-printed-car/.
Simmons, D., Airbus had 1,000 parts 3D printed to meet deadline. http://www.bbc.com/news/technology-32597809
Tibbits, S., The emergence of “4D printing”. http://www.ted.com/talks/skylar_tibbits_the_emergence_of_4d _printing.
Campbell, T.; Tibbits, S.; Garrett, B. The next wave: 4D printing-programming the material world. Frame, 2014
Xie, T. Tunable polymer multi-shape memory effect. Nature 2010, 464(7286), 267–270
Zhao, Q.; Qi, H. J.; Xie, T. Recent progress in shape memory polymer: New behavior, enabling materials, and mechanistic understanding. Prog. Polym. Sci. 2015, 49-50, 79−120
Zhao, Q.; Zou, W.; Luo, Y.; Xie, T. Shape memory polymer network with thermally distinct elasticity and plasticity. Sci. Adv. 2016, 2(1), DOI: 10.1126/sciadv.1501297
Zheng, N.; Fang, Z.; Zou, W.; Zhao, Q.; Xie, T. Thermoset shape-memory polyurethane with intrinsic plasticity enabled by transcarbamoylation. Angew. Chem. Int. Ed. 2016, 55(38), 11421–11425
Hj, V. D. L.; Herber, S.; Olthuis, W.; Bergveld, P. Stimulus-sensitive hydrogels and their applications in chemical (micro)analysis. Analyst 2003, 128(4), 325–331
Prabaharan, M.; Mano, J. F. Stimuli-responsive hydrogels based on polysaccharides incorporated with thermo-responsive polymers as novel biomaterials. Macromol. Biosci. 2006, 6(12), 991–1008
Tokarev, I.; Minko, S. Stimuli-responsive hydrogel thin films. Soft matter 2009, 5(3), 511–524
Qiu, Y.; Park, K. Environment-sensitive hydrogels for drug delivery. Adv. Drug. Deliv. Rev. 2012, 64(3), 49–60
Shankar, R.; Ghosh, T. K.; Spontak, R. J. Dielectric elastomers as next-generation polymeric actuators. Soft matter 2007, 3(9), 1116–1129
Yang, Z.; Herd, G. A.; Clarke, S. M.; Tajbakhsh, A. R.; Terentjev, E. M.; Huck, W. T. Thermal and UV shape shifting of surface topography. J. Am. Chem. Soc. 2006, 128(4), 1074–1075
Naficy, S.; Gately, R.; Gorkin, R.; Xin, H.; Spinks, G. M. 4D printing of reversible shape morphing hydrogel structures. Macromol. Mater. Eng. 2017, 302(1), DOI: 10.1002/mame.201600212
Raviv, D.; Zhao, W.; McKnelly, C.; Papadopoulou, A.; Kadambi, A.; Shi, B.; Hirsch, S.; Dikovsky, D.; Zyracki, M.; Olguin, C.; Raskar, R.; Tibbits, S. Active printed materials for complex self-evolving deformations. Sci. Rep. 2014, 4, DOI: 10.1038/srep07422
Tibbits, S.; McKnelly, C.; Olguin, C.; Dikovsky, D.; Hirsch, S. 4D printing and universal transformation. Proceedings of the 34th Annual Conference of the Association for Computer Aided Design in Architecture, 2014, 539−548
Zhao, Z.; Wu, J.; Mu, X.; Chen, H.; Qi, H. J.; Fang, D. Desolvation induced origami of photocurable polymers by digit light processing. Macromol. Rapid. Commun. 2017, 38(13), DOI: 10.1002/marc.201600625
3D SYSTEMS, https://cn.3dsystems.com/3d-printers/projet -mjp-3600-dental.
Stratasy, http://www.stratasys.com/3d-printers/technologies/ polyjet-technology.
Lewis, J. A.; Smay, J. E.; Stuecker, J.; Cesarano, J. Direct ink writing of three-dimensional ceramic structures. J. Am. Ceram. Soc. 2010, 89(12), 3599–3609
Ionov, L. 3D microfabrication using stimuli-responsive self-folding polymer films. Polym. Rev. 2013, 53(1), 92–107
Ma, C.; Li, T.; Zhao, Q.; Yang, X.; Wu, J.; Luo, Y.; Xie, T. Supramolecular lego assembly towards three-dimensional multiresponsive hydrogels. Adv. Mater. 2014, 26(32), 5665–5669
Zhao, Q.; Sun, J.; Ling, Q.; Zhou, Q. Synthesis of macroporous thermosensitive hydrogels: A novel method of controlling pore size. Langmuir 2009, 25(5), 3249–3254
Gong, J. P.; Katsuyama, Y.; Kurokawa, T.; Osada, Y. Double-Network hydrogels with extremely high mechanical strength. Adv. Mater. 2003, 15(14), 1155-1158
Ge, Q.; Qi, H. J.; Dunn, M. L. Active materials by four-dimension printing. Appl. Phys. Lett. 2013, 103(13), DOI: 10.1063/1.4819837
Ge, Q.; Dunn, C. K.; Qi, H. J.; Dunn, M. L. Active origami by 4D printing. Smart Mater. Struct. 2014, 23(9), DOI: 10.1088/0964-1726/23/9/094007
Genzer, J.; Liu, Y.; Shaw, B.; Dickey, M. In Light-induced sequential self-folding of pre-strained polymer sheets, APS Meeting 2014
Ying, L.; Shaw, B.; Dickey, M. D.; Genzer, J. Sequential self-folding of polymer sheets. Sci. Adv. 2017, 3(3), DOI: 10.1126/sciadv.1602417
Mao, Y.; Yu, K.; Isakov, M. S.; Wu, J.; Dunn, M. L.; Qi, H. J. Sequential self-folding structures by 3D printed digital shape memory polymers. Sci. Rep. 2015, 5, DOI: 10.1038/srep13616
Ding, Z.; Yuan, C.; Peng, X.; Wang, T.; Qi, H. J.; Dunn, M. L. Direct 4D printing via active composite materials. Sci. Adv. 2017, 3(4), DOI: 10.1126/sciadv.1602890
Mao, Y.; Ding, Z.; Yuan, C.; Ai, S.; Isakov, M.; Wu, J.; Wang, T.; Dunn, M. L.; Qi, H. J. 3D printed reversible shape changing components with stimuli responsive materials. Sci. Rep. 2016, 6, DOI: 10.1038/srep24761
Zarek, M.; Layani, M.; Cooperstein, I.; Sachyani, E.; Cohn, D.; Magdassi, S. 3D printing of shape memory polymers for flexible electronic devices. Adv. Mater. 2016, 28(22), 4449–4454
Zarek, M.; Mansour, N.; Shapira, S.; Cohn, D. 4D printing of shape memory-based personalized endoluminal medical devices. Macromol. Rapid Commun. 2017, 38(2), DOI: 10.1002/marc.201600628
Zarek, M.; Layani, M.; Eliazar, S.; Mansour, N.; Cooperstein, I.; Shukrun, E.; Szlar, A.; Cohn, D.; Magdassi, S. 4D printing shape memory polymers for dynamic jewellery and fashionwear. Virtual. Phys. Prototyp. 2016, 11(4), 263–270
Miao, S.; Zhu, W.; Castro, N. J.; Nowicki, M.; Zhou, X.; Cui, H.; Fisher, J. P.; Zhang, L. G. 4D printing smart biomedical scaffolds with novel soybean oil epoxidized acrylate. Sci. Rep. 2016, 6, DOI: 10.1038/srep27226
Yu, K.; Dunn, M. L.; Qi, H. J. Digital manufacture of shape changing components. Extreme. Mech. Lett. 2015, 4, 9–17
Huang, L. M.; Jiang, R. Q.; Wu, J. J.; Song, J. Z.; Bai, H.; Li, B. G.; Zhao, Q.; Xie, T. Ultrafast digital printing toward 4D shape changing materials. Adv. Mater. 2017, 29(7), DOI: 10.1002/adma.201605390
Yang, H.; Leow, W. R.; Wang, T.; Wang, J.; Yu, J.; He, K.; Qi, D.; Wan, C.; Chen, X. 3D printed photoresponsive devices based on shape memory composites. Adv. Mater. 2017, DOI: 10.1002/adma.201701627
Yang, K.; Grant, J. C.; Lamey, P.; Joshi-Imre, A.; Lund, B. R.; Smaldone, R. A.; Voit, W. Diels-alder reversible thermoset 3D printing: isotropic thermoset polymers via fused filament fabrication. Adv. Funct. Mater. 2017, DOI: 10.1002/adfm.201700318
Wei, H.; Zhang, Q.; Yao, Y.; Liu, L.; Liu, Y.; Leng, J. Direct-write fabrication of 4D active shape-changing structures based on a shape memory polymer and its nanocomposite. ACS Appl. Mater. Interfaces 2017, 9(1), 876–883
Gladman, A. S.; Matsumoto, E. A.; Nuzzo, R. G.; Mahadevan, L.; Lewis, J. A. Biomimetic 4D printing. Nat. Mater. 2016, 15(4), 413–418
Zhang, Q.; Yan, D.; Zhang, K.; Hu, G. Pattern transformation of heat-shrinkable polymer by three-dimensional (3D) printing technique. Sci. Rep. 2015, 5, DOI: 10.1038/srep08936
Zhang, Q.; Zhang, K.; Hu, G. Smart three-dimensional lightweight structure triggered from a thin composite sheet via 3D printing technique. Sci. Rep. 2016, 6, DOI: 10.1038/srep22431
Zhao, Z.; Wu, J.; Mu, X.; Chen, H.; Qi, H. J.; Fang, D. Origami by frontal photopolymerization. Sci. Adv. 2017, 3(4), DOI: 10.1126/sciadv.1602326
Sokol, Z., The U.S. Army is investing in 4D printing, expect craziness like self-altering camo. https://creators.vice.com/ en_us/article/yp5m8x/the-us-army-is-investing-in-4d-printing-e xpect-crazy-results.
Kuribayashi, K.; Tsuchiya, K.; You, Z.; Tomus, D.; Umemoto, M.; Ito, T.; Sasaki, M. Self-deployable origami stent grafts as a biomedical application of Ni-rich TiNi shape memory alloy foil. Sci. Eng. A Struct. Mater. 2006, 419(1-2), 131–137
Wache, H. M.; Tartakowska, D. J.; Hentrich, A.; Wagner, M. H. Development of a polymer stent with shape memory effect as a drug delivery system. J. Mater. Sci. Mater. Med. 2003, 14(2), 109–112
Acknowledgments
This work was financially supported by the National Natural Science Founds for Distinguished Young Scholar (No. 21625402) and the National Natural Science Founds for Youths (No. 21604070).
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Wu, JJ., Huang, LM., Zhao, Q. et al. 4D Printing: History and Recent Progress. Chin J Polym Sci 36, 563–575 (2018). https://doi.org/10.1007/s10118-018-2089-8
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DOI: https://doi.org/10.1007/s10118-018-2089-8