Abstract
The influence of sodium dodecyl sulfate (SDS) on the cloud point temperature (T cp) of the aqueous solution of thermoresponsive hyperbranched polyethylenimine derivative HPEI-IBAm was studied systematically. When pH was below 8.5, HPEI-IBAm was positively-charged. Initially, the T cp of HPEI-IBAm decreased significantly, followed by an obvious increase with the increase of SDS concentration. The lower the pH was, the higher the SDS concentration was required to achieve the minimum T cp. When pH was above 8.5, HPEI-IBAm was neutral and raising the SDS concentration led to the gradual increase of T cp. Compared to linear poly(N-isopropyl acrylamide) (PNIPAm), the T cp of the current hyperbranched HPEI-IBAm was more sensitive to SDS. The thermoresponsive HPEI-IBAm/SDS complex was used as host to accommodate the non-polar pyrene in water. The lowest SDS concentration for effectively enhancing the solubility of pyrene in water was around 6.4 mmol·L-1. When HPEI-IBAm was present, the SDS concentration threshhold was decreased to about 0.31 mmol·L-1. Fluorescence technique with pyrene as the hydrophobic probe demonstrated that the SDS concentration of 7.2 mmol·L-1 was required to form the hydrophobic domain to accommodate pyrene guests without HPEI-IBAm, while only 0.2 mmol·L-1 of SDS was required in the presence of HPEI-IBAm.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Galaev, I.Y. and Mattiasson, B., Trends Biotechnol., 1999, 17: 335
Yoshimatsu, K., Lesel, B.K., Yonamine, Y., Beierle, J.M., Hoshino, Y. and Shea, K.J., Angew. Chem. Int. Ed., 2012, 51: 2405
Moon, H.J., Ko, D.Y., Park, M.H., Joo, M.K. and Jeong, B., Chem. Soc. Rev., 2012, 41: 4860
Weber, C., Hoogenboom, R. and Schubert, U.S., Prog. Polym. Sci., 2012, 37: 686
Alarcón, C.d.l.H., Pennadam, S. and Alexander, C., Chem. Soc. Rev., 2005, 34: 276
Wang, B., Liu, H.J., Jiang, T.T., Li, Q.H. and Chen, Y., Polymer, 2014, 55: 6036
Yang, Y., Tang, G., Hu, M., Shao, L., Li, J. and Bi, Y., Polymer, 2015, 68: 213
Yoshida, T., Aoyagi, T., Kokufuta, E. and Okano, T., J. Polym. Sci. Part A: Polym. Chem., 2003, 41: 779
Kimura, M., Kato, M., Muto, T., Hanabusa, K. and Shirai, H., Macromolecules, 2000, 33: 1117
Xu, J., Luo, S., Shi, W. and Liu, S., Langmuir, 2006, 22: 989
Wever, D.A.Z., Riemsma, E., Picchioni, F. and Broekhuis, A.A., Polymer, 2013, 54: 5456
Nakabayashi, K., Noda, D., Watanabe, Y. and Mori, H., Polymer, 2015, 68: 17
Nakayama, M. and Okano, T., Biomacromolecules, 2005, 6: 2320
Haba, Y., Harada, A., Takagishi, T. and Kono, K., J. Am. Chem. Soc., 2004, 126: 12760
Aathimanikandan, S.V., Savariar, E.N. and Thayumanavan, S., J. Am. Chem. Soc., 2005, 127: 14922
Haba, Y., Kojima, C., Harada, A. and Kono, K., Macromolecules, 2006, 39: 7451
Jia, Z., Chen, H., Zhu, X. and Yan, D., J. Am. Chem. Soc., 2006, 128: 8144
Shen, Y., Kuang, M., Shen, Z., Nieberle, J., Duan, H. and Frey, H., Angew. Chem. Int. Ed., 2008, 47: 2227
Schömer, M., Seiwert, J. and Frey, H., ACS Macro Lett., 2012, 1: 888
Wang, R.C., Fu, X.B., Liu, X., Liu, H.J., Chen, Y. and Cui, J., RSC Adv., 2013, 3: 17016
Tao, X., Liu, K., Li, W. and Zhang, A., Polymer, 2014, 55: 3672
Liu, H.J., Dong, R.H. and Chen, Y., Chinese J. Polym. Sci., 2014, 32(7): 961
Qin, H.W., Liu, H.J. and Chen, Y., Chinese J. Polym. Sci., 2014, 32(10): 1338
Fan, W.W., Fan, X.D., Tian, W., Zhang, X., Wang, G., Zhang, W.B., Bai, Y. and Zhu, X.Z., Polym. Chem., 2014, 5: 4022
Liu, Y., Li, W., Hou, L. and Wu, P., RSC Adv., 2014, 4: 24263
Liu, H., Chen, Y. and Shen, Z., J. Polym. Sci., Part A: Polym. Chem., 2007, 45: 1177
Wu, C. and Wang, X.H., Phys. Rev. Lett., 1998, 80: 4092
Wang, X.H., Qiu, X.P. and Wu, C., Macromolecules, 1998, 31: 2972
Haba, Y., Kojima, C., Harada, A. and Kono, K., Angew. Chem. Int. Ed., 2007, 46: 234
Zhang, J., Liu, H.J., Yuan, Y., Jiang, S., Yao, Y. and Chen, Y., ACS Macro Lett., 2013, 2: 67
Mu, X.R., Tong, J.G., Liu, Y., Liu, X.Y., Liu, H.J. and Chen, Y., Polymer, 2013, 54: 2341
Liu, X.Y., Mu, X.R., Liu, Y., Liu, H.J., Chen, Y., Cheng, F. and Jiang, S.C., Langmuir, 2012, 28: 4867
Liu, X., Cheng, F., Liu, H. and Chen, Y., Soft Matter, 2008, 4: 1991
Liu, Y., Liu, X.Y., Liu, H.J., Cheng, F. and Chen, Y., Macromol. Res., 2012, 20: 578
Schild, H.G. and Tirrell, D.A., J. Phys. Chem., 1990, 94: 4352
Zhang, Y., Furyk, S., Bergbreiter, D.E. and Cremer, P.S., J. Am. Chem. Soc., 2005, 127: 14505
Suwa, K., Yamamoto, K., Akashi, M., Takano, K., Tanaka, N. and Kunugi, S., Colloid Polym. Sci., 1998, 276: 529
Bloksma, M.M., Bakker, D.J., Weber, C., Hoogenboom, R. and Schubert, U.S., Macromol. Rapid Commun., 2010, 31: 724
Shechter, I., Ramon, O., Portnaya, I., Paz, Y. and Livney, Y.D., Macromolecules, 2010, 43: 480
Mori, T., Fukuda, Y., Okamura, H., Minagawa, K., Masuda, S. and Tanaka, M., J. Polym. Sci., Part A: Polym. Chem., 2004, 42: 2651
Okamura, H., Morihara, Y., Masuda, S., Minagawa, K., Mori, T. and Tanaka, M., J. Polym. Sci., Part A: Polym. Chem., 2002, 40: 1945
Durme, K.V., Rahier, H. and Mele, B.V., Macromolecules, 2005, 38: 10155
Eeckman, F., Amighi, K. and Moes, A.J., Int. J. Pharm., 2001, 222: 259
Schild, H.G. and Tirrell, D.A., Langmuir, 1990, 6: 1676
Schild, H.G. and Tirrell, D.A., Langmuir, 1991, 7: 665
Winnik, F.M., Ringsdorf, H. and Venzmer, J., Langmuir, 1991, 7: 912
Winnik, F.M., Ringsdorf, H. and Venzmer, J., Langmuir, 1991, 7: 905
Chen, J., Xue, H., Yao, Y., Yang, H., Li, A., Xu, M., Chen, Q. and Cheng, R., Macromolecules, 2012, 45: 5524
Chen, J., Gong, X., Yang, H., Yao, Y., Xu, M., Chen, Q. and Cheng, R., Macromolecules, 2011, 44: 6227
Coughlan, D.C. and Corrigan, O.I., Int. J. Pharm., 2006, 313: 163
Hofmann, C. and Schönhoff, M., Colloid Polym. Sci., 2009, 287: 1369
Schild, H.G., Muthukumar, M. and Tirrell, D.A., Macromolecules, 1991, 24: 948
Winnik, F.M., Ringsdorf, H. and Venzmer, J., Macromolecules, 1990, 23: 2415
Otake, K., Inomata, H., Konno, M. and Saito, S., Macromolecules, 1990, 23: 283
Kono, K., Miyoshi, T., Haba, Y., Murakami, E., Kojima, C. and Harada, A., J. Am. Chem. Soc., 2007, 129: 7222
Hou, Y., Yu, C., Liu, G., Ngai, T. and Zhang, G., J. Phys. Chem. B, 2010, 114: 3799
Boström, M., Tavares, F. W., Finet, S., Skouri-Panet, F., Tardieu, A. and Ninham, B. W., Biophys. Chem., 2005, 117: 217
Finet, S., Skouri-Panet, F., Casselyn, M., Bonneté, F. and Tardieu, A., Curr. Opin. Colloid Interface Sci., 2004, 9: 112
Zhang, Y. and Cremer, P.S., Proc. Natl. Acad. Sci. U.S.A., 2009, 106: 15249
Wang, H., Sun, S. and Wu, P., J. Phys. Chem. B, 2011, 115: 8832
Hunter, R., “Foundations of colloid science”, Clarendon Press, Oxford, 1987
Author information
Authors and Affiliations
Corresponding author
Additional information
This work was financially supported by the National Natural Science Foundation of China (Nos. 20804027 and 21274106).
Rights and permissions
About this article
Cite this article
Liu, Hj., Xu, Yy. & Chen, Y. Influence of sodium dodecyl sulfate on the phase transition of thermoresponsive hyperbranched polymer in water. Chin J Polym Sci 34, 585–593 (2016). https://doi.org/10.1007/s10118-016-1779-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10118-016-1779-3