Abstract
Single-hole hollow polymer nanospheres were fabricated by raspberry-like template method using “graft-from” strategy through atom transfer radical polymerization (ATRP). Nanometer-sized silica spheres were covalently attached onto the surfaces of micrometer-sized silica spheres. Crosslinked polymer shells on the nano-sized spheres outside the attached area were formed by “graft-from” strategy through ATRP. After removal of the silica cores, single-hole hollow crosslinked polymer nanospheres were obtained. In this strategy, most of ATRP monomers may be used and thus many functional groups can be easily incorporated into the single-hole hollow crosslinked polymer nanospheres.
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This work was supported by the National Natural Science Foundation of China (No. 20974052) and the Natural Science Foundation of Tianjin Municipality (No. 09JCZDJC22900).
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Zhang, Y., Chen, Jj., Zhang, Gh. et al. Preparation of single-hole hollow polymer nanospheres by raspberry-like template method. Chin J Polym Sci 31, 294–301 (2013). https://doi.org/10.1007/s10118-013-1190-2
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DOI: https://doi.org/10.1007/s10118-013-1190-2