Abstract
The Central Saurashtra mafic dyke swarm in the northwestern Deccan Traps contains a few picrites, several subalkalic basalts and basaltic andesites, and an andesite. We have obtained precise 40Ar/39Ar ages of 65.6 ± 0.2 Ma, 66.6 ± 0.3, and 62.4 ± 0.3 Ma (2σ errors) for three of the dykes, indicating the emplacement of the swarm over several million years. Mineral chemical and whole-rock major and trace element and Sr–Nd isotopic data show that fractional crystallization and crystal accumulation were important processes. Except for two dykes (with εNd t values of –8.2 and –12.3), the magmas were only moderately contaminated by continental crust. The late-emplaced (62.4 Ma) basalt dyke has compositional characteristics (low La/Sm and Th/Nb, high εNd t of +4.3) suggesting little or no crustal contamination. Most dykes are low-Ti and a few high-Ti, and these contrasting Ti types cannot be produced by fractional crystallization processes but require distinct parental magmas. Some dykes are compositionally homogeneous over tens of kilometers, whereas others are heterogeneous, partly because they were formed by multiple magma injections. The combined field and geochemical data establish the Sardhar dyke as ≥62 km long and the longest in Saurashtra, but this and the other Central Saurasthra dykes cannot have fed any of the hitherto studied lava-flow sequences in Saurashtra, given their very distinct Sr–Nd isotopic compositions. As observed previously, high-Ti lavas and dykes only outcrop east–northeast of a line joining Rajkot and Palitana, probably because of underlying enriched mantle at ~65 Ma.
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Introduction
Recent geochemical studies of the Deccan Traps lava flows and dyke swarms (Fig. 1a) have shown that whereas many lava-flow successions, separated by hundreds of kilometers, correlate stratigraphically with each other (e.g., Peng et al. 2014), many others do not, and thus the Deccan lava eruptions were polycentric (e.g., Sheth and Melluso 2008; Sheth et al. 2013). Three major mafic dyke swarms outcropping in the Deccan province (Fig. 1a) have been studied extensively in the search for the feeder dykes of the Deccan Traps lava flows, and some of the dykes are inferred to have fed lava flows several hundred kilometers in length (e.g., Bondre et al. 2006; Ray et al. 2007; Sheth et al. 2009, 2013, 2014; Vanderkluysen et al. 2011).
The northwestern Deccan Traps (including the Saurashtra, Kachchh, and Rajasthan regions, Fig. 1a) remain poorly studied in comparison to the southwestern Deccan (Western Ghats), the central Deccan (the Dhule area), and the northern and northeastern Deccan regions. Geochronological data for the northwestern Deccan Traps are particularly scarce. Here, we present a study of the large Central Saurashtra mafic dyke swarm in the northwestern Deccan Traps. With varied datasets (field, petrographic, 40Ar/39Ar geochronological, mineral chemical, and whole-rock geochemical data, including major and trace element and Sr–Nd isotopic data), we discuss the magmatic evolution and magma transport in these dykes and examine the tectonomagmatic relationship of this dyke swarm with the lava-flow sequences in the Saurashtra region.
Geology
Saurashtra (Fig. 1a, b) is mostly flat and low-lying and covered by the Deccan flood basalts in large part. Geological, geophysical and drilling data suggest that the basalts are up to a few hundred meters thick (e.g., West 1958; Sheth et al. 2013). Mesozoic sedimentary rocks outcrop in the northern areas and Tertiary and Quaternary sediments outcrop along the coastal fringes of Saurashtra. Unlike the main Deccan province to the east–southeast, dominated by tholeiitic flood lavas, the Deccan Traps of Saurashtra include several volcano-plutonic complexes and a great range of rock types including picrite and ankaramite, lamprophyres, diorite, granophyre, and rhyolite (e.g., Melluso et al. 1995; Sheth et al. 2011, 2012; Kshirsagar et al. 2012, and references therein). Mafic dykes are abundant (Auden 1949), and the Eastern Saurashtra dykes studied by Sheth et al. (2013) represent a westerly extension of the large, ENE–WSW trending Narmada-Tapi dyke swarm (NTDS, Fig. 1a) into Saurashtra across the Cambay rift.
The Central Saurashtra dykes studied here form a large swarm exposed between the cities of Rajkot and Amreli, ~150 km northwest of the Eastern Saurashtra dyke swarm (Fig. 1b). This area is the relatively elevated (~200 m above mean sea level) but flat central highland region of Saurashtra, and the dykes form linear topographic ridges many kilometers long. They intrude basaltic lava flows at the current level of exposure and may have fed lava flows at higher levels subsequently eroded away. The Central Saurashtra dyke swarm (Fig. 1c) contains several dykes trending ENE–WSW, and others with different orientations including ~ E–W and NW–SE. We collected 19 samples of the Central Saurashtra dykes, which are all mafic and medium to very fine grained. Field notes and sample descriptions are provided in the Supplementary Table S1.
Analytical methods
Small fresh chips of these samples were cleaned in an ultrasonic bath and ground to powders of <75 μm grain size using a Retsch PM-100 planetary ball mill and stainless steel grinding balls, in the Department of Earth Sciences, IIT Bombay. Major oxide compositions of the dykes by inductively coupled plasma atomic emission spectrometry (instrument: Jobin Yvon Ultima 2), and loss on ignition (LOI) values, were also determined there (Table 1), following the procedure described by Sheth et al. (2013). Trace elements including the rare earth elements (REE) were analyzed in 12 selected dyke samples by inductively coupled plasma mass spectrometry at the Institute of the Earth’s Crust, of the Siberian Branch of the Russian Academy of Sciences, Irkutsk (Table 2). 50 mg of sample powders were weighed in 40 ml PFA vials. Dissolution was done using open vials by a mixture of HF, HNO3, and HClO4 following Panteeva et al. (2003). The measurements were performed using an Agilent 7500ce (Agilent Technologies Inc., USA) mass spectrometer operated at the Limnological Institute of the Siberian Branch of the Russian Academy of Sciences, Irkutsk. 10 ppb of In and Bi were added as internal standards to correct for instrumental drift and matrix effects. The measured mass spectra were analyzed and elemental concentrations in the samples calculated offline using Excel software and data for certified reference materials MGR-N, JB-2, and BCR-2.
Strontium and neodymium isotopic ratios were also measured in these 12 samples at the Institute of the Earth’s Crust, Irkutsk (Table 3). The procedures followed Pin and Santos-Zalduegui (1997) for Nd and Pin et al. (1994) for Sr, with minor modifications outlined by Rasskazov et al. (2002) and Ivanov et al. (2008), respectively. Isotopic ratios were measured using a Finnigan MAT262 thermal ionization mass spectrometer. Accuracy of the analyses was tested by measurements on the reference materials SRM 987 (0.710263 ± 0.000011, 2σ, n = 10) and JNd-1 (0.512102 ± 0.000005, 2σ, n = 12).
Whole-rock samples of three of the longer and fresher aphyric dykes were dated by the 40Ar/39Ar incremental heating technique at the National Facility for 40Ar/39Ar Geochronology and Thermochronology, located in the Department of Earth Sciences, IIT Bombay. This employed a Thermo Fisher ARGUS mass spectrometer and the procedures described in Sen et al. (2012). The results are summarized in Table 4, and the stepwise analytical data are given in the Supplementary Table S2. The plateau spectra and isochron plots for the three samples are shown in Fig. 2. We define a plateau as comprising a minimum of 60 % of the total 39Ar released and four or more successive degassing steps whose mean ages overlap at the 2σ level including the error contribution from the J value. The data were plotted using the program ISOPLOT v. 3.75 (Ludwig 2012).
Mineral compositions were obtained at Centro Interdipartimentale Strumentazioni per Analisi Geomineralogiche, University of Naples, utilizing an Oxford Instruments Microanalysis Unit equipped with an INCA X-act detector and a JEOL JSM-5310 microscope. An accelerating voltage of 15 kV and a filament current of 50–100 mA was used for all the analyses. Measuring times were of 50 s. Silicates and oxides were used as standards (see Cucciniello et al. 2014 for details). The complete dataset of mineral analyses is available in the Supplementary Table S3.
Nomenclature and petrography
We used the SINCLAS program of Verma et al. (2002) to recalculate the major oxide compositions on a LOI-free basis and to obtain Mg Numbers [Mg# = 100 Mg / (Mg + Fe2+)], CIPW norms, and standardized, IUGS-recommended rock names (Le Bas et al. 1986; Supplementary Fig. 1) for the samples. Total iron was divided into Fe2+ and Fe3+ varieties based on the Middlemost (1989) scheme offered by SINCLAS. The Central Saurashtra dykes range in composition from picrite (with >12 wt. % MgO) to basalt, basaltic andesite, and andesite (Table 1). All samples are subalkalic with normative hypersthene (4.06–27.3 wt. %), and several samples have normative quartz (from 1.57 wt. % to as much as 18.0 wt. % in the andesite CSD13).
The picrites (e.g. CSD8 and CSD9) have subophitic or porphyritic textures (Supplementary Fig. 2a, b). Phenocrysts commonly make up 15–20 % and rarely exceed 30 % by volume of the picrites. Olivine occurs as phenocrysts, microphenocrysts, or microlites in the groundmass. Olivine phenocrysts and microphenocrysts are euhedral or subhedral, zoned, generally altered along fractures to iddingsite and often contain small rounded spinel inclusions (Supplementary Fig. 2a, b). Clinopyroxene forms euhedral to subhedral phenocrysts or microphenocrysts, or subophitic or intergranular phases in the groundmass (Supplementary Fig. 2a, b). Plagioclase forms euhedral to subhedral lath-shaped crystals (Supplementary Fig. 2a, b). Opaque oxides occur as microphenocrysts or microlites. Apatite is an accessory groundmass phase.
The basaltic dykes (Supplementary Fig. 2c–f) are porphyritic with phenocrysts of olivine and subordinate clinopyroxene constituting 10–20 % by volume, but some samples show a subophitic texture. They consist of subhedral or rounded olivine (always altered to iddingsite along fractures), subhedral, interstitial, or oikocrystic clinopyroxene, euhedral to subhedral lath-shaped plagioclase, and interstitial anhedral opaque oxides. Chromiferous spinels are enclosed in olivine phenocrysts and sometimes also in clinopyroxene grains. Pigeonite is found at boundaries of clinopyroxene grains, or within the groundmass (Supplementary Fig. 2f). Orthopyroxene has been found only in the sample CSD18 as a late-crystallized phase in the groundmass with quartz, alkali feldspar, pigeonite, and opaque oxides (Supplementary Fig. 2f). Interstitial glass (of rhyolitic composition) is rarely observed (CSD1). The Sardhar basaltic andesite (CSD5) is a fine-grained rock with microphenocrysts of plagioclase and clinopyroxene in a groundmass of plagioclase, quartz, clinopyroxene, pigeonite, and opaque oxides (Supplementary Fig. 2 g, h).
40Ar/39Ar dating
The three dated samples (sample CSD5 from the N87°-trending Sardhar basaltic andesite dyke, sample CSD8 from a N77°-trending picrite dyke, and sample CSD11 from a N113°-trending basalt dyke) yielded very good plateau spectra (Fig. 2a, b, c). Also, the concordant plateau, isochron and inverse isochron ages for each sample, the large amounts of total released 39Ar (70.4–95.4 %) for the plateau steps, the acceptable mean square weighted deviate (MSWD) values of the isochrons and inverse isochrons, as well as the atmospheric 40Ar/36Ar ratio (295.5) of the trapped argon given by their intercepts (Fig. 2a, b, c), suggest that these ages represent true crystallization ages. We therefore take the plateau ages as the crystallization ages. The dyke CSD5 has an age of 65.6 ± 0.2 Ma (2σ), dyke CSD8 has an age of 66.6 ± 0.3 Ma (2σ), and dyke CSD11 has an age of 62.4 ± 0.3 Ma (2σ). The first two ages are essentially the same as those determined for the bulk of the Deccan Traps (e.g., Baksi 2014 and references therein).
Mineral chemistry
Olivines
Olivine has a wide range of composition from Fo84 to Fo51 in picrites and from Fo85 to Fo18 in tholeiitic basalts (where Fo = 100 Mg / (Mg + Fe); Supplementary Fig. 3a). MnO in olivine ranges from 0.1 to 1.4 wt. %. NiO ranges from below detection limits to 0.7 wt. % and tends to decrease with decreasing MgO. CaO ranges from 0.1 to 0.8 wt. % (Supplementary Table S3).
Pyroxenes
Clinopyroxenes of the Central Saurashtra dykes belong to the augite–ferroaugite and diopside–hedenbergite series (nomenclature of Morimoto et al. 1988; Supplementary Table S3; Supplementary Fig. 3b). The first series occurs in the basaltic samples CSD1, CSD5, and CSD18 (En46Fs9Wo45 to En32Fs41Wo27) and shows Fe enrichment and Ca depletion from clinopyroxene cores to rims and with increasing differentiation. TiO2 and Al2O3 contents are low (0.3–1.6 wt. % TiO2 and 1.0–3.7 wt. % Al2O3). Pigeonite is relatively abundant in the groundmass of these samples. It has a compositional range from En50Fs40Wo10 to En22Fs63Wo15. Fe-rich orthopyroxene (En27Fs70Wo3) has been found in the tholeiitic dyke CSD18. Equilibration temperatures of groundmass clinopyroxenes and pigeonites in the Mg-rich basaltic dyke CSD18 and the basaltic andesite CSD5, based on the two-pyroxene geothermometer of Lindsley (1983), range from 1100 to 1000 °C. Similar temperatures (~1059–961 °C) are obtained for groundmass pigeonites using the algorithm of Ishii (1975). Temperatures calculated using equilibrium clinopyroxene phenocrysts or microphenocrysts and the Putirka (2008) clinopyroxene-liquid geothermometer range from ~1200 °C for the Mg-rich basaltic dyke CSD18 to ~1100 °C for the basaltic andesite CSD5. Clinopyroxenes in the picrites and some of the basalts (CSD7, CSD16, and CSD17) fall in the diopside–hedenbergite field close to augite–ferroaugite boundary (En46Fs9Wo45 to En17Fs39Wo43). Their Mg# values [where Mg# = 100 Mg / (Mg + Fe)] range from 83 to 31. TiO2 and Al2O3 range from 0.3 to 2.7 and from 2.0 to 6.2 wt. %, respectively. Clinopyroxenes belonging to the diopside–hedenbergite series have been also observed in the transitional lavas of Pavagadh (e.g., Sheth and Melluso 2008) and in some Gujarat basalts with weakly alkaline affinity (e.g., Melluso et al. 1995, 2006; Krishnamurthy et al. 2014; Supplementary Fig. 3b). The clinopyroxene compositions of the Central Saurashtra picrite dykes plot well within the field defined by clinopyroxenes of the more primitive NE Saurashtra drillhole lavas (Krishnamurthy and Cox 1977; Supplementary Fig. 3b).
Feldspars
Feldspars in the Central Saurashtra dykes have been classified following the method of Deer et al. (2001). Plagioclase in the picrites and basaltic dykes varies from bytownite (An85–69) to oligoclase (An29–19). Alkali feldspar (Or14–61) is rare and occurs in the groundmass (Supplementary Table S3; Supplementary Fig. 3c). In the basaltic andesite CSD5, plagioclase varies from labradorite (An56) to andesine (An36). The feldspars analyzed in all Central Saurashtra dykes plot well within the field of feldspars of other Deccan Traps rocks (Supplementary Fig. 3c).
Oxides
Magnetite is the main oxide mineral in the Central Saurashtra dykes. The ulvöspinel concentration of magnetite ranges from 49 to 77 mol % in the picrites and from 41 to 88 mol % in the basaltic dykes (Supplementary Table S3; Supplementary Fig. 3d). Al2O3 is variable (0.7–4.1 wt. %). Ilmenite usually cocrystallizes with magnetite in the Central Saurashtra dykes. It is homogeneous in composition (ilm91–97) and has low Al2O3 (<0.4 wt %) and MnO (0.3–1.1 wt %) contents (Supplementary Table S3). Equilibrium temperatures and oxygen fugacities of coexisting magnetite and ilmenite, calculated using the ILMAT program of Lepage (2003), range from 1141 to 845 °C and from −15 to −10logfO2 units in the picrites, and from 1100 to 671 °C and from −20 to −10logfO2 units in the basaltic rocks. These values plot close to the quartz–fayalite–magnetite (QFM) buffer and are similar to the values reported by Melluso and Sethna (2011) for other Deccan Traps rocks. Chromiferous spinel occurs as small inclusions in olivine phenocrysts and microphenocrysts. The compositional range observed is wide with Al2O3 varying from 35.1 to 11.1 wt. %, Cr2O3 varying from 42.3 to 23.8 wt. % (Cr# = 64-32; where Cr# = 100Cr / (Cr + Al)), and MgO varying from 14.0 to 4.1 wt. % (Mg# = 63-19; Supplementary Table S3). The most Cr-rich spinels have been found in the basaltic dykes (e.g., CSD1 and CSD18). In the Cr–Al–(Fe3+ + 2Ti) diagram (Supplementary Fig. 3e), data for the chromiferous spinels of the Central Saurashtra dykes plot within the field of spinels of other Deccan Traps rocks (Melluso and Sethna 2011).
Whole-rock geochemistry
Alteration effects on whole-rock composition
The majority of the Central Saurashtra dykes have values of loss on ignition (LOI) below 1.5–1.8 wt. % (and well below 1.0 wt. % for several), suggesting that the samples are relatively fresh (consistent with petrographic observations), and their analyzed major and trace element and Sr–Nd isotopic compositions reflect magmatic compositions. However, this may not be true of Pb concentrations. Compared to the common 2–5 ppm Pb concentrations in Deccan lavas and dykes (e.g., Peng et al. 1994, 1998, 2014; Vanderkluysen et al. 2011), the Central Saurashtra dykes have Pb concentrations ranging from 23.6 ppm (CSD6) to as much as 152 ppm (CSD15). Similar or higher Pb concentrations observed in the highly weathered lavas and dykes from eastern Saurashtra and Mumbai areas were ascribed to probable hydrothermal alteration (Sheth et al. 2013, 2014). This explanation is unlikely for the Central Saurashtra dykes, and we suspect that the very high Pb values reflect contamination, from an unidentified source, during the preparation of sample powders. We therefore do not use the Pb data in this paper and use only the alteration-resistant elements (Ti, Zr, Nb, Y, Th, and the REE) and their ratios, as well as isotopic ratios (particularly of Nd) for geochemistry-based modeling and interpretations.
Major and trace elements
The whole-rock major and trace element data for the Central Saurashtra dykes are presented in Tables 1 and 2. The picrites have MgO contents between 15.6 and 12.4 wt. %, and Mg# values of 75–69. MgO content of the basaltic dykes ranges from 11.5 to 8.5 wt. % and the Mg# varies from 68 to 62 (Table 1). The Ni and Cr contents (Ni = 247–183 ppm; Cr = 860–613 ppm) of the picritic and Mg-rich basaltic dykes are within the ranges expected for mantle-derived melts (but see below). Unlike three basaltic andesites (CSD3, 5, and 15) and one andesite (CSD13) with 2.8–3.2 wt. % TiO2, the picrites and basalts have low concentrations of the immobile high field strength elements such as TiO2 (0.7–1.3 wt. %), P2O5 (0.1–0.2 wt. %), and Zr (30–101 ppm). They have moderate Zr/Nb (6–19) and Lu/Hf (0.1–0.4), and low Zr/Y (1–4) and Ti/V (13–26) typical of enriched mid-ocean ridge basalt (E-MORB) magmas (e.g., Sun and McDonough 1989).
Flood basalts of the world have often been classified into low-Ti and high-Ti types which cannot be related by fractional crystallization but require distinct parental magmas (e.g., Hergt et al. 1991; Peate 1997; Shellnutt et al. 2014). Based on combined TiO2 and Nb contents and Zr/Y and Ti/Y ratios, Melluso et al. (1995) classified the Deccan rocks of Saurashtra into low-Ti, high-Ti, and intermediate-Ti types, with 1.8 wt. % TiO2 as the upper limit for the low-Ti type (Fig. 3). The low-Ti rocks have Nb < 10–12 ppm (mostly <9 ppm), even when highly evolved, and low Zr/Y (average 3.7) and low Ti/Y (average 281) ratios. Based on their scheme, Sheth et al. (2013) found that the Palitana lava flows are dominantly low-Ti with a few high-Ti and intermediate-Ti members, and the Eastern Saurashtra dykes include all three types. The NE Deccan drillhole sequences (and the Pavagadh basalts further east) are high-Ti (Melluso et al. 2006; Sheth and Melluso 2008). We find that the Central Saurashtra dykes are dominantly low-Ti, with four samples (CSD3, 5, 13, and 15) being high-Ti and the intermediate-Ti type absent (Fig. 3). The high-Ti rocks are considerably more evolved than the rest of the suite, with MgO < 5 wt. % and Mg# ranging from 48.0 to as low as 32.3 (Table 1).
Primitive mantle-normalized multielement patterns of the Central Saurashtra mafic dykes (picrites and basalts, excluding basalt CSD11) are variably enriched in Rb, Ba, and the LREE relative to Zr, Hf, Ti, and the HREE (Fig. 4a, b). The patterns are relatively flat with low normalized abundances from Eu to Lu (less than ten times primitive mantle values) and show no Nb anomalies (excluding the basalt CSD1 with a marked negative Nb anomaly). In some samples (e.g. CSD8, CSD16, and CSD18), the concentrations of many elements are similar to those in average E-MORB (Sun and McDonough 1989). Primitive mantle-normalized incompatible element patterns of the high-Ti basaltic andesites (CSD3, 5, and 15) show marked troughs at Ba and Sr and peaks at Th (Fig. 4c). The pattern of the low-Ti basaltic andesite CDS6 displays a marked trough at Nb, a weak trough at Sr and lower normalized abundances than the high-Ti basaltic andesites.
Sr and Nd isotopic ratios
Strontium and neodymium isotopic ratios for 12 Central Saurashtra dykes, corrected for an age of 65 Ma, are reported in Table 3 (age correcting the isotopic ratios for sample CSD11 to 62.4 Ma makes little difference). Of these 12 dykes, ten show a range of (87Sr/86Sr)t from 0.70496 to 0.70852 and (143Nd/144Nd)t from 0.512863 (εNd t = +4.2) to 0.512346 (εNd t = –5.2; Fig. 5). The isotopic ratios correlate with the degree of LREE enrichment (143Nd/144Nd decreases with increasing La/Sm ratio). Two dykes (basalt CSD1 and basaltic andesite CSD6) have highly radiogenic (87Sr/86Sr)t (0.71421 and 0.71705, respectively) and highly unradiogenic (143Nd/144Nd)t (0.512205 and 0.511988, corresponding to εNd t = –8.2 and –12.3, respectively; Fig. 5). The Central Saurashtra dykes have similar Nd isotopic ratios to the Eastern Saurashtra dykes (εNd t = +1.1 to –5.2 for six samples, with two other samples having εNd t = –17.4 and –18.0; Sheth et al. 2013). However, the Central Saurashtra dykes have systematically lower Sr isotopic ratios than the Eastern Saurashtra dykes (0.70635–0.72959). This difference cannot be explained by the significantly weathered nature of the latter, because the isotopic data for both swarms define strongly anticorrelated and well-separated arrays, whereas any disturbance of the isotopic ratios by weathering would have resulted in at least some overlap between both arrays. We interpret this as indicating petrogenetically independent magmatic evolution in both dyke swarms.
Magmatic evolution
The entirely subalkalic Central Saurashtra dykes show a considerable variation in major element composition (ranging from picrite to andesite), trace element (including REE) contents, and Sr–Nd isotopic ratios. We now discuss mechanisms to generate these variations, including fractional crystallization and crystal accumulation, and crustal contamination.
Fractional crystallization and crystal accumulation
Petrographic features and major and trace element variations observed in the Central Saurashtra dykes (e.g. 46.4–55.4 wt. % SiO2) are consistent with fractional crystallization and crystal accumulation processes. The dykes show significant variations in SiO2, TiO2, Al2O3, and CaO with MgO (Fig. 6a–d). Ni and Cr are strongly correlated with MgO, suggesting fractional crystallization of olivine + Cr-spinel (Fig. 6e, f). Al2O3 and CaO first increase with decreasing MgO and begin to decrease when MgO reaches 9 wt. % (Fig. 6c, d), suggesting fractionation of clinopyroxene and plagioclase. However, some dykes (CSD1, 2, 4, 12, 14, 16, and 19) show higher Al2O3 and lower CaO and Sc contents, for a given MgO content, than the other dykes. This characteristic is not due to excess plagioclase (as none of the samples show plagioclase phenocrysts in thin section) and may suggest higher pyroxene:plagioclase ratios in the fractionation assemblages or different parental magmas. Incompatible trace elements, such as Rb and Zr, also show negative correlation with MgO (Fig. 6g, h).
An important question is whether the Central Saurashtra picrites are high-MgO liquids or cumulus-enriched rocks. Picritic rocks in the NE Saurashtra drillholes have been interpreted as near-primary liquids with ~16 wt. % MgO (West 1958; Krishnamurthy and Cox 1977; Krishnamurthy et al. 2000), whereas most picritic rocks in the Western Ghats sequence appear to be evolved basaltic liquids which have accumulated olivine and clinopyroxene (Beane and Hooper 1988), with such accumulation reaching an extreme level in the Khopoli olivine gabbro (Cucciniello et al. 2014). We plotted the olivine compositions (Fo %) in Central Saurashtra picrites CSD8 and CSD9 against their whole-rock Mg# values (Fig. 7). The olivine compositions plot well below the equilibrium K d band (drawn using a Fe/Mg K d = 0.30 ± 0.03; Roeder and Emslie 1970), implying forsterite contents too low to be in equilibrium with the whole-rock Mg# (69–70) values. The most Mg-rich olivine compositions (Fo84 in CSD8) would have been in equilibrium with a melt with Mg# = 64. This means that cumulus enrichment of low-Fo olivines has raised the bulk-rock MgO contents and Mg# values, and the resultant picritic rocks do not represent high-MgO liquids (cf. Cucciniello et al. 2014; Chatterjee and Sheth 2015). In fact, olivine compositions of five of the tholeiitic dykes also plot below or well below the equilibrium K d band (Fig. 7), suggesting that cumulus enrichment of olivine phenocrysts (or xenocrysts) was a widespread process in the Central Saurashtra dyke magmas.
To model the effects of fractional crystallization on major element compositions, we performed mass balance calculations (Stormer and Nicholls 1978) on pairs of samples from the same dykes (or from dykes located nearby). Thus, for the Isapur-Charkha dyke (Fig. 1c), ~6 % olivine fractionation from the picrite CSD8 generates the basalt CSD7 (∑R 2 = 0.45). The transition from basalt dyke CSD16 to the nearby basaltic dyke CSD14 is modeled by 35 % fractional crystallization of olivine (12 %), clinopyroxene (54 %), plagioclase (28 %), and magnetite (6 %; ∑R 2 = 0.22). The transition from basalt dyke CSD19 to the nearby basaltic andesite dyke CSD15 is modeled by 61 % fractional crystallization of olivine (17 %), clinopyroxene (40 %), and plagioclase (43 %; ∑R 2 = 0.25). For the transition from basalt CSD1 to basaltic andesite CSD5 in the Sardhar dyke, the extract removed (62 %) is composed of olivine (22 %), plagioclase (42 %) and clinopyroxene (36 %; ∑R 2 = 0.37). For the transition from basalt CSD1 to basaltic andesite CSD6, the extract removed (58 %) is composed of olivine (24 %), plagioclase (52 %), and clinopyroxene (24 %; ∑R 2 = 0.42). The mass balance calculations are in agreement with the observed mineral assemblages.
Crustal contamination
Fractional crystallization and crystal accumulation processes (and prior partial melting processes) cannot have generated the variability observed in the incompatible element ratios and the Sr–Nd isotopic ratios of the Central Saurashtra dykes. Therefore, these variations must reflect open-system processes, most importantly contamination of the dyke magmas by lithospheric materials. Trace element ratios, such as Nb/U, Th/Nb, and La/Nb, and radiogenic isotope ratios (e.g., 87Sr/86Sr and 143Nd/144Nd) are commonly used to assess the role of crustal contamination because of the strongly contrasted compositions of mantle-derived mafic magmas and continental crustal materials. Ocean island basalt (OIB) and MORB (e.g., E-MORB and N-MORB) have high Nb/U (>45) and low La/Nb (0.8–1.1) and Th/Nb (<0.1) ratios (e.g., Sun and McDonough 1989). The continental crust has lower Nb/U (4.4–25) and higher La/Nb (1.6–2.6) and Th/Nb (0.24–0.88) ratios than MORB and ocean island basalts (e.g., Rudnick and Gao 2003).
The Central Saurashtra picrites and most basaltic dykes have Nb/U (45–54), Th/Nb (0.09–0.15), and La/Nb (0.6–0.9) ratios similar to MORB and OIB, suggesting little or no crustal contamination. In contrast, the basalts CSD1 and CSD19 and the basaltic andesites have lower Nb/U (8–17) and higher La/Nb (1.0–2.1) and Th/Nb (0.25–0.6) ratios trending toward crust-like compositions. Plots of εNd t and the alteration-resistant incompatible trace element ratios Th/Nb, La/Nb, and Zr/Nb (Fig. 8a, b, c) show that the Central Saurashtra dyke data plot along broad crustal contamination trends which are parallel or subparallel to the arrays defined by the Palitana and Eastern Saurashtra dykes (Sheth et al. 2013). Notably, the Central Saurashtra dykes mostly lie along the lower ends of the overall mixing arrays, with the exception of basalt CSD1 and basaltic andesite CSD6 (having εNd t = –8.2 and –12.3, respectively, suggesting much higher degrees of crustal contamination). The elongation of the individual arrays also suggests that two-component mixing between mantle-derived magmas and a single crustal end member may not be adequate and that several mixing end members may have been involved.
Figure 9 is a plot of Ti/Y vs. Zr/Nb, employing four elements that are highly alteration-resistant, and these ratios are insensitive to crystal fractionation of the main basaltic minerals. Crustal contamination of mafic magmas would raise their Zr/Nb while lowering Ti/Y. Most Central Saurashtra dykes form a distinct cluster from not only the Western Ghats lavas but also all other Saurashtra mafic rocks including the NE Saurashtra drillhole lavas, the Palitana lavas, and the Eastern Saurashtra dykes (Fig. 9). Most of the Central Saurashtra dyke data (with small negative εNd t values) plot at the lower left end of the diagram, indicating that they have been contaminated to low degrees. On the other hand, data for dykes CSD1 and CSD6 plot at much higher Zr/Nb, overlapping with the highly crustally contaminated Bushe Formation of the Western Ghats sequence (e.g., Beane et al. 1986). Dykes CSD1 and CSD6 are thus significantly contaminated by upper continental crust, an inference supported by their Sr–Nd isotopic ratios. The scenario is similar to that observed by Sheth et al. (2013) for the Eastern Saurashtra dyke swarm, in which four dykes are highly crustally contaminated, but the majority much less so.
We performed modeling of combined assimilation and fractional crystallization (AFC, DePaolo 1981) to reproduce the trace element and isotopic variations in the Central Saurashtra dykes. The nature of the Precambrian crustal basement beneath Saurashtra is unknown because of lack of outcrops or xenoliths, but the Western Dharwar Craton, exposed south of the Deccan Traps, may extend to at least the central Deccan Traps (the Dhule area, Fig. 1a, Ray et al. 2008). We therefore took a granite from the Western Dharwar Craton (Jayananda et al. 2006) as a putative contaminant and the low-Ti basalt dyke CSD16 (initial 143Nd/144Nd = 0.512621; εNd t = +1.3) as the starting magma. Note that low-Ti basalt dyke CSD11 has the most “primitive” or mantle-like isotopic ratios (initial 143Nd/144Nd = 0.512770; εNd t = +4.2) of all dykes, but its 40Ar/39Ar age of 62.4 Ma shows that it was emplaced several million years after the bulk of the swarm and is therefore unsuitable as the magma end member in the AFC modeling.
The results of the AFC modeling are shown in Fig. 10a, b. The AFC curve indicates that the most contaminated sample (low-Ti basaltic andesite CSD6) could be derived by ~40 % fractional crystallization coupled with ~12 % assimilation of the granite. AFC modeling using a low-Ti starting magma fails to reproduce the geochemical variations observed in the high-Ti rocks CSD3, 5, 15 and requires unrealistically high degrees of fractionation (~80 %) with extreme iron enrichment. This further suggests that the low-Ti and high-Ti Central Saurashtra dyke rocks originated from distinct parental magmas.
Lateral geochemical variations in dykes, and their significance
Lateral geochemical variations (both elemental and isotopic) in individual Deccan dykes have been discussed by Bondre et al. (2006), Ray et al. (2007), Vanderkluysen et al. (2011), and Sheth et al. (2013), and our data provide some additional insights on this issue. As seen in Fig. 1c, the Central Saurashtra dyke swarm includes several long dykes, which we sampled at various locations in order to determine their lateral petrographic and geochemical variations. This can provide useful information about magma transport in the dyke including the magma flow direction. In the field, inadequate exposure often prevents continuous lateral tracing of dykes. Thus, the Sardhar dyke, the longest in Saurashtra (Auden 1949) forms a continuous topographic ridge over ~40 km from the west of Ribda (sample CSD1) to the east of Sardhar (sample CSD5), but its further eastward extension is less certain. It would appear from Fig. 1c that the dyke extends to the east of Kundani (sample CSD3). If so, it is slightly arcuate in trace and at least 62 km in length. As noted above, 62 % fractional crystallization of the Sardhar basalt CSD1 (with the extract containing olivine:plagioclase:clinopyroxene in 22:42:36 ratio) can reproduce the Sardhar basaltic andesite CSD5 located 23 km to the east. This scenario is however untenable if we consider the Nd–Sr isotopic ratios of CSD1 (εNd t = –8.2, initial 87Sr/86Sr = 0.714212) and CSD5 (εNd t = –3.7, initial 87Sr/86Sr = 0.707547), indicating that the latter is much less contaminated. A possible explanation is that, as seen in outcrop, the Sardhar dyke is made up of multiple magma injections (see Fig. 8c of Sheth and Cañón-Tapia 2015), and samples CSD1 and CSD5 do not belong to a single magma batch.
Interestingly, whereas the Sardhar dyke sample CSD1 is low Ti, sample CSD5 (taken at Sardhar village) is high Ti, and sample CSD3 (taken 20 km east of Sardhar near Kundani) is also high Ti. At Kundani (Fig. 1c), where CSD3 was sampled, only one dyke zone is exposed (see Fig. 5d of Sheth and Cañón-Tapia 2015). Nd–Sr isotopic ratios of CSD3 (εNd t = –3.6, 87Sr/86Sr = 0.707521) are identical within analytical error to those of sample CSD5. This provides some valuable insights: (i) sample CSD3 represents the eastward lateral extension of the Sardhar dyke, which is thus at least 62 km long, from the west of Ribda to the east of Kundani (Fig. 1c), (ii) samples CSD5 and CSD3 represent the same magma batch which flowed laterally in the dyke fissure over at least 20 km without wall-rock assimilation, and (iii) the dyke was formed by several magma injections of distinct compositions, but does not expose (probably, never developed) all the constituent zones along its whole length.
Other samples collected in this study may also represent different exposed segments of the same individual dykes. Two such pairs are CSD13–CSD15 and CSD16–CSD14 (Fig. 1c), but we did not analyze CSD13 and CSD14 for isotopic ratios and therefore cannot fully evaluate how homogeneous these dykes are laterally. However, as for the Sardhar dyke, we sampled the long (30 km) and prominently curved Isapur-Charkha dyke (Fig. 1c), at three locations (samples CSD8, CSD7 and CSD18 taken progressively eastwards). We do not have isotopic data for the middle sample (CSD7), but the isotopic data for picrite CSD8 (εNd t = –2.6, 87Sr/86Sr = 0.707096) and basalt CSD18 (εNd t = –2.1, 87Sr/86Sr = 0.707068) are identical within error. This is consistent with the two samples representing a single, isotopically homogeneous dyke with a prominently curved trace and a minimum length of 30 km, in which magma flowed eastward over ≥30 km fractionating olivine, but without wall-rock assimilation.
Stratigraphic implications of dyke geochemistry: dyke-flow correlations
As noted, the Central Saurashtra dykes cut Deccan basalt lava flows at the present level of exposure. One of the aims of this study was to determine whether these dykes fed lava flows at higher levels, whose erosional remnants are potentially represented in the variably Ti-enriched Saurashtra flows sampled by Melluso et al. (1995), the high-Ti drillhole sequences of NE Saurashtra (West 1958; Krishnamurthy and Cox 1977; Peng and Mahoney 1995; Melluso et al. 2006), and the low-Ti-dominated Palitana flow sequence (Sheth et al. 2013). The 40Ar/39Ar ages of 65–66 Ma for the Sardhar dyke (sample CSD5) and the Isapur-Charkha dyke (sample CSD8) indicate that these dykes were emplaced at the same time as the bulk of the Deccan province in the Western Ghats (see Baksi 2014 and references therein), the high-Ti drillhole sequences (Peng and Mahoney 1995) and the alkalic plugs of Kachchh (Pande et al. 1988). The dyke CSD11 was emplaced much later, in the Palaeocene, at ~62.4 Ma, and differs significantly from all other dykes by virtue of its highest (143Nd/144Nd)t (0.512770) and εNd t (+4.2), and its low La/Sm (1.85) and Th/Nb (0.15), suggesting little crustal contamination. Interestingly, Deccan basalt flows around Ninama, north of Vinchhiya (just out of the map in Fig. 1c), have been inferred to be of Palaeocene age based on palynoflora in the associated intertrappean sedimentary beds (Samant et al. 2014), and dyke CSD11 may have fed one of them. We have recently sampled these flows (H. Sheth and R. Duraiswami, December 2014) for a geochronological and geochemical study.
In regard to the geochemical correlations of the Central Saurashtra dykes to the Saurashtra lavas, the dykes are evolved in composition and dominantly low-Ti and cannot have been feeders to the NE Saurashtra high-Ti drillhole sequences (as well as the Pavagadh sequence 150 km further east) which include many picritic flows. Even the high-Ti segment of the very long Sardhar dyke (samples CSD3 and CSD5) cannot have fed the high-Ti drillhole sequences, given their distinct Ti/Y and Zr/Nb ratios (Fig. 9).
Sheth et al. (2013) found that the Eastern Saurashtra dykes studied by them could not have fed the mainly low-Ti Palitana sequence because of their clear and complete separation in Sr–Nd isotopic composition (Fig. 5). They considered that the Palitana lavas may have been fed by dykes on the Deccan “mainland” region (such as in the Nandurbar–Dediapada areas, Fig. 1a), or by the still poorly studied dykes in southern Saurashtra around Rajula, or by the Central Saurashtra dykes, all of which outcrop at relatively small distances (100–150 km) from Palitana (Fig. 1b). Our study shows that though the Central Saurashtra dykes and the Palitana sequence are both dominated by low-Ti tholeiitic basalts, they are completely distinct in Sr–Nd isotopic composition (Fig. 5), and thus petrogenetically unrelated. The Central Saurashtra dykes are thus ruled out as possible feeders to the NE Saurashtra drillhole sequences, as well as the Pavagadh and Palitana sequences.
We also explore whether the Central Saurashtra dykes were the feeders of any of the low-Ti surface lava flows studied by Melluso et al. (1995) from a wider region in Saurashtra (Fig. 3a). The Ti/Y vs. Zr/Nb plot (Fig. 9) shows that the Central Saurashtra dykes form a very distinct cluster away from not only the Palitana lavas but also the low-Ti lavas of Melluso et al. (1995). Because these ratios do not change during fractional crystallization, Fig. 9 conclusively shows, despite the variable degrees of magmatic evolution, that the Central Saurashtra dykes are not possible feeders to any of the hitherto analyzed lava-flow successions of Saurashtra. The same conclusion was reached by Sheth et al. (2013) for the Eastern Saurashtra dykes. The feeder dykes of these lava-flow successions remain to be found.
We also consider the relationship of the Central Saurashtra dykes to the Eastern Saurashtra dykes. As seen from Fig. 5, they possess similar 143Nd/144Nd ratios, but are distinct in 87Sr/86Sr ratios, and therefore must represent genetically unrelated suites. Both dyke swarms contain a few members (Eastern Saurashtra dykes ESD3 and ESD5 analyzed for Sr–Nd isotopic ratios, and dykes ESD2 and ESD7 not analyzed for isotopic ratios, and Central Saurashtra dykes CSD1 and CSD6) which are contaminated by continental crust to much greater degrees than the majority of the dykes, but the mixing-contamination arrays in Fig. 5 are linear and tight, indicating that any alteration processes did not significantly affect the isotopic compositions. Our geochemical data on the Central Saurashtra dykes, combined with those of Sheth et al. (2013) on the Palitana lava flows and Eastern Saurashtra dykes, as well as those of Melluso et al. (1995) on lava flows from a wider region in Saurashtra, show that low-Ti tholeiites dominate in this region.
Melluso et al. (1995) noted that high-Ti lavas only outcrop north–northeast of a line connecting Rajkot to Palitana (Fig. 1b). This observation was strengthened by the study of Sheth et al. (2013) which included not only lava flows (potentially far travelled from their source areas) but also dykes. Intriguingly, the same observation is further supported by our new results on Central Saurashtra dykes: a line joining Rajkot to Palitana cities would go right through the Sardhar dyke (Fig. 1b), and whereas the sample CSD1 collected to the west of the line is low Ti, samples CSD5 and CSD3 to the east of the line are high Ti. The interpretation of this observation is not clear at present, but if the high-Ti basalts were derived from clinopyroxene-rich, ocean island-type mantle as discussed by Melluso et al. (1995, 2006), such mantle apparently existed under Saurashtra only east of the Rajkot–Palitana line and under the adjacent Cambay rift ca. 65 Ma ago.
Conclusions
The Central Saurashtra mafic dyke swarm in the northwestern Deccan Traps contains many subalkalic basalts and basaltic andesites along with several picrites and one andesite. We have obtained 40Ar/39Ar ages of 66–65 Ma for two of the dykes and of 62.4 Ma for a third, indicating that the swarm was formed over several million years. Mineral chemical, and whole-rock major and trace element, and Sr–Nd isotopic data for the dykes show that fractional crystallization, crystal accumulation, and crustal contamination were widespread, though the degree of contamination was small for most dykes. Crustal contamination was significant in two dykes (CSD1 and CSD6), and negligible or absent in the late-formed (62.4 Ma) basalt dyke CSD11. Most dykes can be considered low-Ti and a few are high-Ti, and these Ti variations cannot be explained by fractional crystallization processes, requiring distinct parental magmas, as argued for several other flood basalt provinces (e.g., Peate 1997; Shellnutt et al. 2014). The geochemical data provide evidence for long-distance (≥30 km) compositional homogeneity in some of the dykes, and lateral heterogeneity in some other dykes, partly because these dykes were formed by multiple magma injections which are not exposed everywhere along strike. The combined field and geochemical data establish the Sardhar multiple-injection dyke as at least 62 km long and the longest in all of Saurashtra, and samples collected 20 km apart along this dyke have identical Sr–Nd compositions, indicating magma transport over at least that distance. However, this dyke cannot have fed the high-Ti lava sequences previously studied from Saurashtra, as shown by its distinct Ti/Y and Zr/Nb ratios, for example. The low-Ti Central Saurashtra dykes were also not feeders to the hitherto studied low-Ti lava-flow successions dominant in the Saurashtra region, because of their very distinct Sr–Nd isotopic compositions. The feeder dykes of these sequences remain to be identified. Our results support the observations of Melluso et al. (1995) and Sheth et al. (2013) that high-Ti basalt lavas and dykes in Saurashtra are found only north–northeast of a line joining Rajkot to Palitana, which therefore suggests the presence of enriched mantle under northeastern Saurashtra and under the adjacent Cambay rift at ~65 Ma.
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Acknowledgments
Field work was supported by the Industrial Research and Consultancy Centre (IIT Bombay) grant 09YIA001 to Sheth. Funds for EPMA analyses by Cucciniello were provided by Italian MIUR (PRIN grants 2008 to Leone Melluso). Leone Melluso is thanked for providing many unpublished Deccan Traps mineral analyses. Demonterova acknowledges the Russian Foundation for Basic Research (Grant No. 15-05-05130). ICPMS trace element and Sr–Nd isotope ratio measurements by Demonterova were performed under the framework of the Baikal Analytical Center, Irkutsk, Russia. Pande acknowledges Grant No. IR/S4/ESF-04/2003 from the Department of Science and Technology (Govt. of India) toward the development of the IIT Bombay-DST National Facility for 40Ar–39Ar Geo-thermochronology. Vijayan was supported by a Ph.D. fellowship from the Council of Scientific and Industrial Research (CSIR), Govt. of India. Vijayan thanks Trupti Gurav for assistance with the laboratory work at IIT Bombay. We thank Ajoy Baksi for helpful comments on an earlier version of this work. The present manuscript was much improved by the detailed, critical reviews of Zhan Peng, Greg Shellnutt, an anonymous reviewer, and Associate Editor David Peate.
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Supplementary Fig. 1
The Central Saurashtra dyke data on the total alkalis-silica (TAS) plot (Le Bas et al. 1986). Boundary line between the alkalic and subalkalic fields proposed by Irvine and Baragar (1971, curved dashed line) is shown. Also shown for comparison are the Palitana lavas and the Eastern Saurashtra dykes (Sheth et al. 2013) (JPEG 2213 kb)
Supplementary Fig. 2
Photomicrographs (left column) and back-scattered electron (BSE) images (right column) of selected Central Saurashtra dykes. a Picrite CSD8, with olivine phenocrysts in a groundmass of olivine, clinopyroxene, plagioclase, and opaque oxides. Parallel polars. Olivine phenocrysts in the BSE image (b) are zoned (light grey zones are Fe-rich) and contain small spinel inclusions. c Subalkalic basalt CSD17, with large clinopyroxene crystals completely or partially enclosing small plagioclase laths and subhedral or rounded olivine grains. Crossed polars. d Subalkalic basalt CSD16, with olivine phenocrysts set in a subophitic groundmass of clinopyroxene, plagioclase and opaque oxides. BSE image. e Subalkalic basalt CSD18, with subophitic to intergranular texture. Crossed polars. f Groundmass of tholeiitic basalt CSD18, with altered olivine, plagioclase, clinopyroxene, pigeonite, orthopyroxene, opaque oxides, and quartz. BSE image. g Basaltic andesite CSD5, with clinopyroxene and plagioclase microphenocrysts in a groundmass (h BSE image) of clinopyroxene, plagioclase, pigeonite, quartz and opaque oxides, parallel polars. ol olivine, pl plagioclase, cpx clinopyroxene, pg pigeonite, opx orthopyroxene, ox opaque oxides, cr chromiferous spinel, mt magnetite, ilm ilmenite, qz quartz, afs alkali feldspar (EPS 277 kb)
Supplementary Fig. 3
Mineral compositions in the Central Saurashtra dykes. a Olivines. b Pyroxene compositions projected in the Ca–Mg–Fe diagram. Also shown for comparison are compositional fields for pyroxenes in the NE Saurashtra drillhole lavas (Krishnamurthy and Cox 1977), the Palitana lavas and Eastern Saurashtra dykes, and in all other Deccan Traps rocks (Melluso and Sethna 2011 and references therein; Sheth et al. 2011, 2012, 2013; L. Melluso, unpublished data). c Feldspar compositions. d Fe–Ti oxides. e Chromium-rich spinels. The fields for feldspars and spinels of all Deccan Traps rocks are also shown in c and e, respectively [data sources as in (b)] (EPS 555 kb)
Table S1
Field notes and sample descriptions for the Central Saurashtra dyke swarm (DOC 51 kb)
Table S2
Stepwise 40Ar/39Ar results for the Central Saurashtra dykes CSD5, CSD8, and CSD11 (DOC 281 kb)
Table S3
Complete dataset of chemical analyses (in wt. %) of olivines, pyroxenes, feldspars, and oxides (magnetites, chromiferous spinels, and ilmenites) from the Central Saurashtra dyke swarm (XLS 220 kb)
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Cucciniello, C., Demonterova, E.I., Sheth, H. et al. 40Ar/39Ar geochronology and geochemistry of the Central Saurashtra mafic dyke swarm: insights into magmatic evolution, magma transport, and dyke-flow relationships in the northwestern Deccan Traps. Bull Volcanol 77, 45 (2015). https://doi.org/10.1007/s00445-015-0932-0
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DOI: https://doi.org/10.1007/s00445-015-0932-0