Introduction

The aim of this study is firstly to characterize the extruder flow behaviour of frictional plastic materials—such as cement-based materials—and to study the physical mechanisms that govern the forming process. Secondly, the paper establishes a method of predicting the extrusion force of such materials. This modelling enables one to predict the coupled behaviour of different extruder/paste combinations.

In the ram extrusion process, plastic materials flow as a plug and slip with friction along the extruder wall (Von Obermayer 1865; Tresca 1872; Zienkiewicz and Godbole 1974; Zienkiewicz et al. 1977; Jay et al. 2002). The extrusion of cement-based materials has already been studied in previous works, but none of them mentioned the time-dependent ram extrusion behaviour of such paste materials (Mori and Baba 1994; Stang and Pedersen 1996; Srinivasan et al. 1999; Mu et al. 1999; Qian et al. 2003).

In the present work, the rheological and tribological behaviour of the extrudible cement-based material is linked to the ram extrusion geometry to predict the flow evolution during the process. Extrudible cement-based materials behave as high yield stress and heterogeneous materials (liquid phase and granular skeleton). The effects of the extrusion process (long time, high pressure gradient, low velocities) may affect the local composition of the material and change the flow conditions. Such a paste presents a behaviour that depends on the stress path induced by the extrusion process. Our extrudible cement paste behaves as a consolidating plastic soil with time-dependent flow properties. Such variations of paste homogeneity inside the extruder are included in the present modelling.

During the process, friction creates a high pressure gradient that induces liquid or cement paste filtration through the granular skeleton.

Liquid filtration during the extrusion of high solid volume fraction pastes is a well-known process that has already been observed by Burbidge et al. (1995) and Götz et al. (2002). Recently, the extrusion ability of cement pastes has been studied (Toutou et al. 2004, 2005) using a simple squeeze flow. The authors have shown that cement-based materials with a high solid volume fraction behave as a frictional plastic material. This induces a high sensitiveness to fluid filtration during slow flow and high pressure gradient. During extrusion flow, the cement paste can be modelled as a consolidated soil where the interparticular friction is dominant. Modelling commonly used in soil mechanics (Coulomb or Drücker–Prager models) describes such behaviour. The first one is presently used for our frictional plastic material. In ram extrusion, the material is confined, and the internal pressure increases as the process goes on. As a result, friction forces between particles increase and induce a higher macroscopic yield stress. The rheological and tribological modelling parameters depend also on the paste location. Finally, during the process, yield stress and wall friction stress always increase, because the paste is always submitted to consolidation. Extrusion force increases and may lead to a blockage of the extrusion process.

Along the extruder wall, in the plug flow zone, the granular paste slips with friction. To model the tribological behaviour, the wall shear stress is linked to the normal stress. Then, the wall shear stress is related to the axial stress acting on the material in the direction of the ram movement. This relationship is based on the Janssen theory used by Ovarlez et al. (2002) to study the behaviour of confined sands. In the Janssen theory, the pressure acting on the granular media is linearly linked to the axial and normal stresses.

In the case of axisymmetrical extruder with square entry die, we assume that the extrusion force can be decomposed in two different force components: the shaping force required to deform the plastic material through the die and the friction force due to friction of the material during the plug flow occurring in the pipe zone (Fig. 1).

Fig. 1
figure 1

Modelled force acting on the axisymmetrical cylinder of extruded material

The shaping force of a plastic body has already been modelled by Benbow and Bridgwater (1993), Mortreuil et al. (2000) or Hill (1950). These authors showed that there is a relationship between the ratio of extrusion (the ratio of the exiting diameter d to the entering diameter D) and the force needed to deform the material. These works only deal with perfect plastic or viscoplastic materials. During the extrusion process of purely plastic materials, the required force that ensures extrusion is constant. This constant force is not reached in the extrusion of frictional plastic materials as the paste is evolving inside the extruder during the process.

To apply the developed model, we performed ram extrusion tests on a cement paste. Two extruder bodies initially filled with different quantities of paste were used. The extrusion ratio is kept constant (d/D=0.35). Ram displacement and extrusion force were recorded during time, and the paste homogeneity is particularly observed during the process to evaluate water filtration effects. Experimental results are compared with the proposed model.

Description of the ram extrusion process

The properties of extrusion flow are well known for plastic and viscoplastic materials. Numerical simulations (see, for example, Zienkiewicz et al. 1977) show that axisymmetrical extrusion flow is divided into three parts (Fig. 2):

  • A plug flow, in the central area where the paste slips along the wall. Near the extruder wall, a highly shearing flow zone can be located in a very thin layer.

  • Near the die, a sheared flow zone, where the material is forming. This zone is called the “shaping zone”.

  • A zone where the material remains stationary around the die entry. This area is called the “dead zone”.

Fig. 2
figure 2

Extrusion flow properties obtained by numerical simulations of the extrusion flow of a plastic material (Zienkiewicz et al. 1977)

The numerical works of Horrobin and Nedderman (1998) or Jay et al. (2002) have confirmed this kind of flow behaviour for viscoplastic materials with a high yield stress. Experimental results on kaolin paste extrusion were presented by Toutou (2002) and confirmed the numerical results (Fig. 3).

Fig. 3
figure 3

Flow properties of a purely plastic material: application to a kaolin paste (Toutou 2002). Experimental extrusion performed with coloured layers superposition

We decompose the extrusion force in both different forces acting in different zones as shown on Fig. 4:

  • The shaping force described by Hill (1950), Benbow and Bridgwater (1993) or Mortreuil et al. (2000) which is required to give the final shape to the material. We assume that the shaping force F pl varies as the material flows. This variation is due to the material consolidation that depends on the pressure history of the material flowing through the pipe of the extruder. Then, F pl is proportional to the plastic yield value K.

  • The friction force F fr, which is required to allow the material to slip at the wall of the pipe extruder. The friction force also increases because of the material consolidation. F fr is linked to the friction yield value K w.

Fig. 4
figure 4

Flow model and stress localisation in the example of extrusion flow of frictional plastic material

As described on Fig. 4, L dz denotes the dead zone length, and L is the friction length. σ(L) represents the mean axial stress, and σ(0) is the mean axial stress at the shaping zone entry. Reference pressure is the external pressure P atm=0.

Cement pastes: an extrudible frictional plastic material

Concept of extrudability

The concept of extrudability is described by Toutou et al. (2004) and is shown in Fig. 5. The authors describe for a ram extruder an extrudability domain, defined by appropriated geometrical parameters and material behaviour parameters. In this work, results are expressed using extrusion stress and forming ration d/D.

Fig. 5
figure 5

Extrudability domain defined in Toutou (2002); Toutou et al. (2004, 2005)

A good quality of extrudates requires a balance between the process and the rheological properties of the material. The material must be soft enough to flow into the pipe and through the extrusion die, and sufficiently firm to retain the shape given by the die geometry without skin defects. The extrusion ability of a cement-based paste relies on the pastes’ behaviour. The paste cohesion provides the final shape of the material. In addition, plastic and friction yield stresses are directly linked to the energy required to deform the material through the die and may affect the surface quality of the final product. The relationship between extrusion force and both rheological and tribological properties are crucial for the choice of an extruder that ensures the extrusion flow.

Rheological behaviour of extrudible frictional plastic behaviour

Mansoutre et al. (1999), Toutou (2002) and Toutou et al. (2004, 2005) showed that extrudible cement-based material exhibits both frictional and plastic behaviours. Consequently, such materials are very sensitive to fluid filtration with a redistribution of the interstitial fluid pressure. Such occurring process is enhanced by the stress gradient that appears during extrusion flow. Squeeze tests carried out by Toutou (2002) and Toutou et al. (2004, 2005) showed that the cement pastes’ behaviour depends on shear rate. At high shear rate, cement pastes exhibit purely plastic behaviour, whereas at low shear rate (which corresponds to extrusion), water filtration produces and induces paste hardening. This hardening induced a yield stress increase that is typical of a frictional plastic behaviour. To model the rheological behaviour of the cement-based material, we use the Coulomb model to describe the sensitive behaviour to pressure (see Eq. 1).

$$K = K_{0} + b.P_{{max}} $$
(1)

where K is the plastic yield stress, K 0 is the cohesion (plastic yield stress at reference pressure), b is a friction parameter, and P max denotes the maximal value of pressure known by the media. This model is validated by performing simple Casagrande box tests on a cement paste (cement, water and a water-reducing admixture) defined in “Material”. Shear velocity is 1 mm/min and the evolution of the apparent yield stress according to the applied normal stress is plotted on Fig. 6. Results show a linear relationship between yield stress and applied normal stress. The linearity is characteristic of a Coulomb material.

Fig. 6
figure 6

Results of the Casagrande box tests on the studied cement paste (shear velocity 1 mm/s). Study of the material sensitivity to normal stress σ n. Linear evolution of the yield stress according to normal stress

We also have to take into account the fact that pastes keep the yield stress value obtained when the pressure acting on the granular media is the highest known by the material (under P max). In such conditions, the material consolidates, and the pressure effect is irreversible. This memory effect, which characterizes consolidated soils study, is very important in this model and makes the material dependent on the stress path (similarly to consolidating soils).

The initial pressure gradient, created at the beginning of the extrusion, induces variations of the material properties, such as yield stress or wall stress, that become dependent on the paste location. The paste located in the plug flow zone and reaching the shaping zone presents evolving rheological properties. In our extrusion tests, carried out at very high pressure gradient, we consider that filtration time is negligible compared with extrusion process time. This is the reason why consolidation is assumed to be an instantaneous phenomenon.

In the case of mortars or concrete, there can be different scales of filtration as the material presents different scales of heterogeneity (liquid phase through cement grains or cement paste through sand grains...). We assume that all filtration processes reach the paste consolidation. As a result, all the filtration processes are integrated in our modelling like a global process that induces paste hardening.

To simplify the flow modelling, compressibility is neglected. Therefore, a compressibility of the granular skeleton is suspected but not integrated to the modelling.

Tribological behaviour of cement pastes

The tribological behaviour is modelled by a Coulomb law. We assume that wall stress depends on the normal stress acting on the material. Moreover, when the paste consolidates, the friction yield stress increases. We model the wall stress by a Coulombian law defined by Eq. 2.

$$K_{w} = K_{{w0}} + a.N_{{max}} $$
(2)

where K w is the friction yield stress, K w0 is the friction yield stress at reference pressure, and a is a friction parameter. N max is the maximal value of the normal stress acting on the wall surface.

Paste behaviour in the axisymmetrical extrusion flow

To link the model parameters which describe the material behaviour in the axisymmetrical extrusion flow to the axial stress σ, the Janssen theory is used. It gives a simple way to model the stress distribution in a granular media in the axisymmetrical cylinder. According to the Janssen theory, the pressure P acting on the granular media is proportional to the mean axial stress σ. The normal stress acting on the extruder wall surface N is also proportional to σ. The Janssen stress distribution allows us to write the following relationships suitable in a granular media confined in an axisymmetrical extruder pipe.

$$K_{0} = K + \beta .\sigma _{{max}} $$
(3)
$$K_{w} = K_{{w0}} + \alpha .\sigma _{{max}} $$
(4)

where α and β are frictional local parameters, and σ max is the maximum value of the axial pressure acting on the studied material.

Theoretical analysis of the extrusion flow of frictional plastic material

Stress profile in the extruder

When the ram moves, friction stress occurs at the paste/extruder boundary interface. The friction force creates a pressure gradient in the paste that induces liquid filtration. Liquid pressure equilibrium and consolidation in the paste affect the local rheological and tribological properties of the extruded paste. It is assumed that paste consolidation is instantaneous. Hence, actualized yield stress and wall stress are directly linked to the axial stress inside the extruder (Eqs. 1 and 2). At a given position z (Fig. 4), the mean axial stress σ(z) is assumed to be constant. From the force balance equation on an elementary cylindrical layer, the following relationship is obtained:

$$\frac{{\pi D^{2} }} {4}{\left[ { - \sigma {\left( {z + dz} \right)} + \sigma {\left( z \right)}} \right]} + \pi D\tau _{w} {\left( z \right)}dz = 0$$
(5)

where τ w(z) is the wall friction stress at the position z. The previous equation becomes:

$$\frac{{d\sigma {\left( z \right)}}} {{dz}} = \frac{{4\tau _{w} {\left( z \right)}}} {D}$$
(6)

Combining Eqs. 4 and 6, we finally obtain the following equation depending on the axial stress σ(z)

$$\frac{{d\sigma {\left( z \right)}}} {{dz}} - \frac{{4\alpha }} {D}\sigma {\left( z \right)} - \frac{{4K_{{w0}} }} {D} = 0$$
(7)

Equation 5 is solved to find the axial stress profile which is created when the material is submitted to the axial stress at the starting of the process.

$$\sigma {\left( z \right)} = \frac{{K_{{w0}} }} {\alpha }{\left[ {exp{\left( {\frac{{4\alpha z}} {D}} \right)} - 1} \right]} + \sigma {\left( 0 \right)}$$
(8)

where σ(0) is the vertical stress needed to ensure the plastic shaping of the material through the die. To evaluate this shaping stress, the Hill’s equation is used and links linearly the extrusion force to the paste yield stress. It represents the plastic energy required to ensure the flow of the material in a channel of diameter d.

$$\sigma {\left( 0 \right)} = K_{0} {\left( {\pi + 2} \right)}{\left( {1 - \frac{d} {D}} \right)} = \gamma K_{0} $$
(9)

When the extrusion flow is initiated, the local axial stress increases. The local stress σ(z) is the maximum stress known by the material. As a result, the material consolidates. As the process goes on, this stress value increases and the material consolidates. Consequently, the value σ(z) calculated in Eq. 8 is equal to the value σ max(z), the highest value of axial stress which has been applied to the granular media.

The initial stress profile is totally determined, allowing the computation of the initial force that initiates the material shaping. The stress profile in the extruder induces a relationship between the flow properties of the paste and its location in the extruder. As a consequence, the yield stress K and the wall friction stress K w depend on z (Fig. 7).

Fig. 7
figure 7

Evolution of the local material properties due to local paste consolidation as a result of the increase of the extruder axial stress

This first modelling step gives us the force needed to initiate the flow. This force is influenced by the quantity of the paste in the extruder. L 0 denotes the length of paste moving along the extruder wall (zone concerned by the plug flow). The length of the dead zone L dz (Fig. 4) has to be withdrawn to the original total paste length to calculate L 0.

For a given ram advance, the paste arriving in the shaping zone presents a higher yield stress related to the paste formed the moment before. In fact, the consolidation process continues. Therefore, the axial stress σ(z) becomes a function of the ram position, the axial stress σ is now noted σ(z,L), where L is the ram position.

Shaping force evolution

The shaping force increases when more consolidated material flows into the shaping zone. We calculate the evolution of rheological properties according to the ram advance. As a result, the evolution of K according to the ram position L is written as the L derivate of K (the K profile follows the ram displacement).

$$\frac{{\partial K{\left( {0,L} \right)}}} {{\partial L}} = \frac{{4\beta K_{{w0}} }} {D} \cdot exp{\left( {\frac{{4\alpha }}{D}L} \right)}$$
(10)

Then, the evolution of the shaping stress vs the ram position is easily deduced.

$$\frac{{\partial \sigma {\left( {0,L} \right)}}} {{\partial L}} = \frac{{4\beta \gamma K_{{w0}} }} {D} \cdot exp{\left( {\frac{{4\alpha }}{D}L} \right)}$$
(11)

To calculate the plastic shaping stress σ(0,L) at a given ram position L, we integrate the shaping force variation between the initial ram position L 0 and the calculated position L.

$$\sigma {\left( {0,L} \right)} = \gamma {\left[ {K_{0} + \frac{{\beta K_{{w0}} }} {\alpha }{\left( {exp{\left( {\frac{{4\alpha }} {D}{\left( {L_{0} - L} \right)}} \right)} - 1} \right)}} \right]}$$
(12)

The increase of the shaping force increases the axial stress values. Afterwards, the effect of the evolution of the shaping force is included for the computation of the axial stress acting on the ram σ(L,L).

Friction force evolution

The axial stress value increases exponentially with ram advance due to the evolution of the shaping force, as seen on Eq. 12. Then, this increase of σ(z,L) according to L affects the value of friction force. A derivation of Eq. 8 according to L writes

$$\frac{{\partial \sigma {\left( {z,L} \right)}}} {{\partial L}} = \frac{{4\beta \gamma K_{{w0}} }} {D} \cdot exp{\left( {\frac{{4\alpha }} {D}L} \right)}$$
(13)

From Eqs. 4 and 13, the L derivate of K w(z,L) is obtained.

$$\frac{{\partial K_{w} {\left( {z,L} \right)}}} {{\partial L}} = \frac{{4\alpha \beta K_{w} }} {D} \cdot exp{\left( {\frac{{4\alpha }} {D}L} \right)}$$
(14)

From the evolution of the friction stress K w according to the ram position, the total vertical stress acting on the ram is calculated by combining the integrated friction force with the shaping force given by Eq. 10.

$$\sigma {\left( {L,L} \right)} = \gamma {\left[ {K_{0} + \frac{{\beta K_{w} }} {\alpha }{\left[ {exp{\left( {\frac{{4\alpha }} {D}L_{0} } \right)}{\left( {exp{\left( {\frac{{4\alpha }} {D}{\left( {L_{0} - L} \right)}} \right)} - 1} \right)}} \right]}} \right]}$$
(15)

The stress acting on the ram is now determined for every ram position, integrating friction and consolidation effect due to physical characteristics of frictional plastic media.

Experimental results

Material

The chosen material fills all the extrudability criterion defined by Toutou et al. (2004, 2005). The material must be rigid enough to retain its shape under gravity and handy solicitations. We carried out tests with cement pastes with a water/cement weight ratio of 0.22. A water-reducing admixture (sika plastiment 22S) was added to the water in the following proportion: P/C=0.01. The binder used was a mix of 70% of Portland cement 32.5 CEM IIB with 20% of volcanic rock (pozzolane) finely crushed (15-μm maximum particle diameter), 5% of silica fume (0.1-μm maximum particle diameter) and 5% of amorphous crushed quartz (10-μm maximum particle diameter). The addition of filler fines gives better homogenisation and plastic performance to the final paste.

Procedure

A planetary Hobart mixer was used for the mix. It provides sufficient high shear rates for small batches. Dry ingredients were first mixed for 2 min at the lowest revolution per minute setting. Then, water and plasticizer were added. Once the dry ingredients were moistened, a higher rotation speed was applied for 5 min. Tests were performed 30 min after the mixing to avoid aging and setting effects. Vane tests were performed to control plastic properties of the cement pastes. Then, the required quantity of paste was put in the closed extruder and pre-compressed at 100 N to ensure same initial conditions between each test. The highest ram speed was used to limit filtration effects in this pre-compression phase. Then, the die was put on the extruder instead of the plug, and the test was performed. Two steel extruder pipes with diameters D 1=43.3 and D 2=55.37 mm were used; the extrusion ratio d/D remained constant and equaled to 0.35. The wall surface of the steel pipes is smooth. For each extruder, three different quantities of pastes were tested (initial length L ini=L 0+L dz) to observe the influence of paste quantity on extrusion force. Extrusion force and ram displacement were recorded vs time using a data acquisition system.

Results and discussions

For the six tests configurations, it is assumed that the material is in the same conditions and aging state. The plastic yield stress of the cement pastes K 0 is measured using a vane test and is equal to 20 kPa (result obtained as the maximum shear stress value at low rotational rate). The internal friction parameter β is measured with a squeeze test method given by Toutou et al. (2004, 2005) and is equal to 0.53. This result is confirmed by Casagrande box tests, as previously described. Friction stress K w0 is measured with a translation tribometer, and its value is 15 kPa. At this step, the parameters α and L 0 are not identified or measured. They are finally determined from the best match estimation between modelled and experimental curves. The model parameters for the six tests are given in Table 1.

Table 1 Parameters used in the test modelling

Experimental and modelled effort vs remaining material length curves are shown in Fig. 8a–b. In all cases, the modelled curves (obtained with same α, β, γ, K 0, K w and with close values of L 0), as expected, match quite perfectly the experimental ones.

Fig. 8
figure 8

F=f(L) effort vs remaining material length curves: experimental vs modelled for three initial lengths and two extruder diameters (a D=43.3 mm, b D=55.3 mm; d/D=0.35)

However, for two tests (noted D55.3 L71 and D43 L41), there is a slight variation between experimental and modelled curves. This variation is due to the material state of aging. Slight variation in the material aging and composition can explain the curve difference. Moreover, there can be a small error in the evaluation of the friction length.

To verify these arguments, we computed the model for different values of the material behaviour parameters. The variations of extrusion forces according to the slight variation of modelling parameters (Fig. 9a–d) are sufficiently large to explain the difference between experimental and modelled curves. The experimental error is located in the area of reproducibility defined by the material sensibility at aging, mixing and composition procedures.

Fig. 9
figure 9

Model sensitivity to modelling parameters (a K w, b α, c K 0, d β). L initial=58 mm and D=43.3 mm

Figure 9a–d shows the influence of the material modelling parameters on the computed extrusion force. It is obvious that plastic yield stress and internal friction parameter β do not subsequently influence the extrusion force. Therefore, the material shaping is not responsible for the extrusion force increase. In contrast, we can say that a slight deviation in the wall friction stress and in the wall friction parameter α greatly affects the extrusion force. The material wall friction stress K w and the sensibility of wall friction to the axial stress (model by the α parameter) are the key parameters that govern the extrusion force increase. Equation 15 shows that the extrusion force increases linearly with α and exponentially with K w. Indeed, friction is the source of the material consolidation. Moreover, an increase of α affects the gradient pressure, which enhances the paste consolidation. Due to the material consolidation, wall friction stress value also increases. This double mechanism explains how influent the parameter α is in our modelling.

The physical phenomenon which is responsible for the extrusion force increase and extrusion blockage is the friction along the extruder wall. Friction induces paste consolidation, which makes the paste harder to extrude. At the beginning of the process, the force required to overcome wall friction is ten times the force required to form the material through the die (Table 2). The model can be written as follows, using exponential law and splitting effects of friction from plasticity effects. The friction (Y0pl and Apl) and plastic components (Y0fr and Afr) can be calculated.

$$F = Y0pl + Y0fr + {\left( {Apl + Afr} \right)} \times exp{\left( {{ - L} \mathord{\left/ {\vphantom {{ - L} {t0}}} \right. \kern-\nulldelimiterspace} {t0}} \right)}$$
(16)
Table 2 Friction and plastic proportion in the total extrusion force

Table 2 shows that the component of extrusion force due to friction effects is dominant over the component due to plastic forming. This table confirms that friction is the parameter that governs extrusion force and extrusion blockage.

Friction lengths determination

The friction surface modelled by the parameter L 0, as mentioned in “Stress profile in the extruder”, has to be estimated according to experimental observations. Agreement should be found between experimental results and modelling fit. To evaluate this parameter similarly to slip lines theory, flow geometry is assumed for the forming process, as shown in Fig. 10.

Fig. 10
figure 10

Visualisation of the influence of paste quantity on the dead zone length

No physical phenomena depending on the cement paste intrinsic behaviour have been found to explain the variation of L 0 with the change of initial paste quantity.

Tests and model fit show that the initial friction zone length tends towards a critical value of 42 mm with an increase of initial paste quantity (Fig. 11). A study of paste consolidation and cement paste skeleton permeability has to be performed. This study may validate the hypothesis of a dead zone length limited by a critical relative velocity between liquid and the granular skeleton. In this case, our assumption of instantaneous material consolidation is a practical approximation; but for more accuracy, a hydromechanic coupling must be studied. Without this coupling, no relationship linking L 0 with L ini and the modelling parameters of the granular media behaviour appears.

Fig. 11
figure 11

Evolution of the initial friction length according to the initial total length of material in the extruder for the studied cement paste

Conclusions

The proposed model gives a simple way to predict the extrusion force of a frictional plastic material. The modelling is suitable to characterize the extrusion conditions of an extrudible firm cement paste. The modelling enables one to understand the mechanism of increasing extrusion force and extrusion blockage. Friction at the extruder wall creates a pressure gradient that induces hardening and consolidation of the paste. As the process goes on, the material arriving in the die land becomes firmer, and the friction force increases as the material becomes more and more consolidated. As a result, the extrusion force increases exponentially. The crucial role of wall friction force as a dominant part of the total extrusion force is highlighted. The model was confronted with tests on a firm cement pastes. Rheological modelling parameters are measured and are included in the model. The length of the friction zone is evaluated and tends to a critical value with the increase of paste quantity. Additional tests and investigations have to be performed to link the friction length value to the microstructure and physics of the cement pastes. A hydromechanical coupling may be envisaged to complete the study of paste consolidation during extrusion process. This work has to be extended to optimize the extrusion process of such materials with a minimisation of the friction force. Tests with lubricated walls or flow coupling with vibration have to be performed to reduce wall friction effects.