Abstract
This article illustrates the analysis by synchrotron micro-analytical techniques of an azurite painting presenting greenish chromatic degradation. The challenge of the experiments was to obtain the spatial distribution of the degradation products of azurite. Copper hydroxychlorides, carbonates and copper oxalates have been mapped by SR FTIR imaging of cross sections in transmission mode. To complement the information, Py/GC/MS and GC/MS techniques were applied in order to characterize the binding media and organic materials present as well as their degradation products. Results contribute to a better understanding of the decay of blue areas in ancient paintings not only from the particular point of view of azurite weathering, but also by adding information regarding the oxalates’ formation and their distribution in painting samples. Synchrotron radiation demonstrates its capability for the mapping in painting cross sections.
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References
A. Roy, Artists Pigments: A Handbook of Their History and Characteristics, vol. 2 (National Gallery of Art, Oxford, 1993)
A. Andreotti, I. Bonaduce, M.P. Colombini, C. Baracchini, A. Caleca, A. Paolucci, Saving the Medieval Paintings by the Master Painter of the Triumph of Death in Pisa in 15th Triennial Conference New Delhi (Allied Publishers, India, 2008)
S. Mugnaini, A. Bagnoli, P. Bensi, F. Doghini, A. Scala, G. Guasparri, J. Cult. Heritage 7, 171 (2006)
C. Cennini, Il Libro del Arte (Akal Ediciones, Madrid, 2002)
O. Vitruvio, Los Diez Libros de Arquitectura (Alianza Forma, Madrid, 2000)
M.P. Merrifield, The Art of Fresco Painting in the Middle Ages and Renaissance (Dover, New York, 2004)
N. Salvadó, T. Pradell, E. Pantos, M.Z. Papiz, J. Molera, M. Seco, M. Vendrell-Saz, J. Synchrotron Radiat. 9, 215 (2002)
P. Vandenabeele, K. Lambert, S. Matiz, W. Schudel, A. Bergmans, L. Monees, Anal. Bioanal. Chem. 383, 707 (2005)
L. Dei, A. Ahle, P. Baglioni, D. Dini, Stud. Conserv. 43, 80 (1998)
I. Bonaduce, M.P. Colombini, J. Chromatogr. A 1028, 297 (2004)
A. Andreotti, I. Bonaduce, M.P. Colombini, G. Gautier, F. Modugno, E. Ribechini, Anal. Chem. 78(13), 4490 (2006)
R.J. Gettens, M.E. Mrose, Stud. Conserv. 1(4), 174 (1954)
C. Genesta, Matter Lett. 54, 382 (2002)
K. Helwig, IRUG at the V&A 83
D. Biakiaris, S. Danilia, S. Sotiropoulou, O. Katsimbiri, E. Pavlidou, A.P. Moutsatsou, Y. Chryssoulakis, Spectrochim. Acta A 56, 3 (1999)
A. Nevin, J. Loring Melia, I. Osticioli, G. Gautier, M.P. Colombini, J. Cult. Heritage 9(2), 154 (2008)
E. Abelev, N. Sezin, Y. Ein-Eli, Rev. Sci. Instrum. 76, 106105 (2005)
J. Madejová, Vibr. Spectrosc. 31(1), 1 (2003)
I. Adrover Gracia, Applicazioni Della Spettrofotometria IR Allo Studio dei Beni Culturali (Collana I Talenti, Padova, 2001)
R.L. Frost, Y. Jing, Z. Ding, Chin. Sci. Bull. 48(17), 1844 (2003)
M.C. D’Antonio, D. Palacios, L. Coggiola, E.J. Baran, Spectrochim. Acta, Part A 68(3), 424 (2007)
S. Bruni, F. Cariati, F. Casadio, L. Toniolo, Vibr. Spectrosc. 20, 15 (1999)
A. Andreotti, I. Bonaduce, M.P. Colombini, F. Modugno, E. Ribechini, Int. J. Mass Spectrom. (2008). ISSN 1387-3806
G. Gautier, M.P. Colombini, Talanta 73, 95 (2007)
I. Donati, Enzimi, acidi organici ed altri metaboliti coinvolti nella patogenesi di penicillium spp. PhD thesis, Universita di Bologna Italy (2008)
A. Lluveras, S. Boularand, J. Roqué, M. Cotte, G. Martinez-Ruiz, P. Giráldez, M. Vendrell-Saz, Appl. Phys. A 90(1), 23 (2008)
M. Cotte, J. Susini, V.A. Solé, Y. Taniguchi, J. Chillida, E. Checroun, P. Walter, J. Anal. At. Spectrom. 23, 820 (2008)
J. van der Weerd, R.M.A. Heeren, J.J. Boon, Stud. Conserv. 49, 193 (2004)
M. Garcia-Vallès, M. Vendrell-Saz, J. Molera, F. Blázquez, Environ. Geol. 36, 137 (1998)
J.K. Magnuson, L.L. Lasure, Advances in Fungal Biotechnology for Industry, Agriculture, and Medicine (Kluwer Academic/Plenum, Norwell/New York, 2003)
M.V. Dutton, C.S. Evans, Can. J. Microbiol. 42, 881 (1996)
F. Cariati, L. Rampazzi, L. Toniolo, A. Pozzi, Stud. Conserv. 45, 180 (2000)
P. Maravelaki-Kalaitzaki, Anal. Chim. Acta 532, 187 (2005)
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Lluveras, A., Boularand, S., Andreotti, A. et al. Degradation of azurite in mural paintings: distribution of copper carbonate, chlorides and oxalates by SRFTIR. Appl. Phys. A 99, 363–375 (2010). https://doi.org/10.1007/s00339-010-5673-5
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DOI: https://doi.org/10.1007/s00339-010-5673-5