Summary
Theoretical equations based on kinetic scheme were developed to predict the average oligomerization number of products of Bisphenol-A and epichlorohydrin condensation catalysed by a quaternary ammonium salt. Ratio of rate constants of the terminal groups formation and chain extension reaction was found. The reactivity ratio varies from 0.05 at 25° to 0.50 at 120°.
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Received: 6 December 1995/Revised version: 3 March 1998/Accepted: 5 March 1998
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Medjitov, D., Shode, L. & Tseitlin, G. Composition of condensation products of bisphenol-A and epichlorohydrin. Polymer Bulletin 40, 509–516 (1998). https://doi.org/10.1007/s002890050284
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DOI: https://doi.org/10.1007/s002890050284