Abstract
The pseudo-phase dispersion model gave the basis for the invention of ionic surfactant with a bivalent counterion applicable in hard water on one hand, and for the discovery of infinitely aggregated micelle, i.e., surfactant phase on the other hand. In earlier days, surfactants soluble in water or oil were the focus of interest, but presently, a surfactant balanced with hydrophile lipophile operties is the center of attention. With such balance the surfactant is practically insoluble in water and hydrocarbon. But, the solubility of water or oil in surfactant phase becomes infinitely large and normal or inversed micelles are formed, provided the HLB of the surfactant is slightly changed to hydrophilic or lipophilic.
Micellar dispersion, surfactant phase separation ans reversed micellar dispersion are inclusively discussed based on the concept of the relative dissolution of water and oil in surfactant phase. Solubilization of oil (or water) in micelle (or reversed micelle) and surfactant phase is also inclusively understood as the solubility in speudo-surfactant phase and surfactant phase. The oil-water interfacial tension passes through minimum when the hydrophile lipophile property of surfactant just balances for a given oil and water. The relations among the interfacial tensions, the types of oils, the amount of cosurfactant, temperatuyre etc. are elucidated.
Overview lecture at the International Symposium on Surfactants in Solution, Lund, Sweden, June 27–July 2, 1982.
This is a preview of subscription content, log in via an institution to check access.
Preview
Unable to display preview. Download preview PDF.
References
Shinoda, K., Nakagawa, T., Tamamushi, B., Isemura T., “Colloidal Surfactants” Academic Press Inc. N.Y. 1963, pp. 8–9.
Hato, M., Shinoda, K., J. Phys. Chem. 77, 378 (1973).
Shinoda, K., Hirai, T., J. Phys. Chem. 81, 1842 (1977).
Weil, J. K., Stirton, A. J., Nuñez-Ponzoa, M. V., J. Am. Oil Chemists’ Soc. 43, 603 (1966).
Murata, M., Tsumadori, M., Suzuki, A., Tsujii, K., Mino, J., XII Meeting of the Spanish Committee on Surface Active Agents, Barcelona (1981).
Shinoda, K., J. Phys. Chem. 85, 3311 (1981).
Weil, J. K., Stirton A. J., Barr, E. A., J. Am. Oil Chemists’ Soc. 43, 157 (1966).
Shinoda, K., Minegishi, Y., Arai, H., J. Phys. Chem. 80, 1987 (1976).
Tsujii, K., Takeuchi, T., J. Phys. Chem. 84, 2287 (1980).
Shinoda, K., Kunieda H., J. Colloid Interface Sci. 42, 381 (1973).
To be published.
Shinoda, K., Saito, H., J. Colloid Interface Sci. 26, 70 (1968).
Saito, H., Shinoda, K., J. Colloid Interface Sci. 32, 647 (1970).
Eriberg, S. E., Lapczynska, L., Prog. Colloid Polym. Sci. 56, 16 (1975).
Lindman, B., Kamenka, N., Kathopoulis, T., Brun, B., Nilsson P., J. Phys. Chem. 84, 2485 (1980).
Healy, R. N., Reed, R. L., Stenmark, D. G., Soc. Pet Eng. J., 147, (June 1976).
Healy, R. N., Reed, R. L., Soc. Pet. Eng. J., 129 (April 1977).
Bansal, V. K., Shah, D. O., Soc Pet. Eng. J., 167 (June 1978).
Shinoda, K., in “Solvent Properties of Surfactant solutions,” Marcel, Dekker, N. Y. 1967, pp. 29–33.
Shinoda, K., Arai, H., J. Colloid Sci. 20, 93 (1965).
Kunieda H., Friberg, S. E., Bull. Chem. Soc. Jpn. 54, 1010 (1981).
Kunieda, H., Shinoda, K., J. Dispersion Sci. and Tech. 3, 233 (1982).
Atack, D., Rice, O. K., Discuss. Faraday Soc. 15, 210 (1953).
Shinoda, K., “Principles of Solution and Solubility” Marcel Dekker Inc., N.Y. 1978, p. 160.
Balmbra, R. R., Clunie, J. S., Corkill J. M., Goodman, J. F., Trans. Faraday Soc. 60, 979 (1946)
p. 144, equations (8.19)–(8.21) in Ref. 24.
Hall, D. G., Pethica, B. A., in: “Nonionic Surfactants” Edited by Schick, M., Marcel, Dekker, Inc., N. Y. 1967, pp. 516–557.
Kunieda H., Shinoa, K., Bull. Chem. Soc. Jpn. 55, 1777 (1982).
To be published.
Author information
Authors and Affiliations
Editor information
Additional information
Dedicated to Professor Dr. B. Tamamushi.
Rights and permissions
Copyright information
© 1983 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
About this paper
Cite this paper
Shinoda, K. (1983). Solution behavior of surfactants: The importance of surfactant phase and the continuous change in HLB of surfactant. In: Nakagaski, M., Shinoda, K., Matijević, E. (eds) Frontiers in Colloid Science In Memoriam Professor Dr. Bun-ichi Tamamushi. Progress in Colloid & Polymer Science, vol 68. Steinkopff. https://doi.org/10.1007/BFb0114132
Download citation
DOI: https://doi.org/10.1007/BFb0114132
Received:
Accepted:
Published:
Publisher Name: Steinkopff
Print ISBN: 978-3-7985-0637-4
Online ISBN: 978-3-7985-1703-5
eBook Packages: Springer Book Archive