Abstract
The adsorption of methyl tert-butyl ether by granular activated carbon was investigated. The experimental data were analyzed using the Freundlich isotherm and the Langmuir isotherm. Although equilibrium data were found to follow Freundlich isotherm model, it were fitted better by the Langmuir model with a maximum adsorption capacity of 204.1 mg/g. The kinetic data obtained at different concentrations were analyzed to predict the constant rate of adsorption using three common kinetic models: pseudo-first-order, pseudo-second-order equation and intraparticle diffusion equation. The pseudo-second-order model was suitable for describing the adsorption kinetics for the removal of methyl tert-butyl ether from aqueous solution onto granular activated carbon. Both the Lagergren first-order rate constant k 1 and pseudo-second-order rate constant k 2 decrease with increasing initial concentrations of methyl tert-butyl ether and the intraparticle diffusion rate constant k p shows the reverse characteristic. Analysis of sorption data using a boyd plot confirmed that external mass transfer is the main rate-limiting step at the initial stage of adsorption. Results illustrate that granular activated carbon is an effective adsorbent for methyl tert-butyl ether and also provide specific guidance into adsorption of methyl tert-butyl ether on granular activated carbon in contaminated groundwater.
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References
Abdel-Ghani, N. T.; Hegazy, A. K.; El-Chaghaby, G. A., (2009). Typha domingensis leaf powder for decontamination of aluminium, iron, zinc and lead: Biosorption kinetics and equilibrium modeling. Int. J. Environ. Sci. Tech., 6 (2), 243–248 (6 pages).
Acero, J. L.; Haderlein, S. B.; Schmidt, T. C.; Suter, M. J. F.; Von Gunten, U., (2001). MTBE oxidation by conventional ozonation and the combination ozone/hydrogen peroxide: efficiency of the processes and bromate formation. Environ. Sci. Tech. 35 (21), 4252–4259 (8 pages).
Achten, C.; Puttmann, W., (2000). Determination of methyl tert-butyl ether in surface water by use of solid-phase microextraction. Environ. Sci. Tech., 34, 1359–1364 (6 pages).
AlDuri, B.; McKay, G., (1991). Prediction of binary-system for kinetics of batch adsorption using basic-dyes onto activated carbon. Chem. Eng. Sci., 46 (1), 193–204 (12 pages).
Ayotte, J. D.; Argue, D. M.; McGarry, F. J.; Degnan, J. R.; Hayes, L.; Flanagan, S. M.; Helsel, D. R., (2008). Methyl tert-butyl ether (MTBE) in public and private wells in New Hampshire: Occurrence, factors and possible implications. Environ. Sci. Tech., 42, 677–684 (8 pages).
Ben Hamissa, A. M.; Ncibi M. C.; Mahjoub, B.; Seffen, M., (2008). Biosorption of metal dye from aqueous solution onto Agave americana (L. ) fibres. Int. J. Environ. Sci. Tech., 5 (4), 501–508 (8 pages).
Boyd, G. E.; Adamson, A. W.; Meyers, L. S., (1947). The exchange adsorption of ions from aqueous solutions by organic zeolites II. J. Am. Chem. Soc., 69, 2836–2848 (13 pages).
Chang, C. Y.; Tsai, W. T.; Ing, C. H.; Chang, C. F., (2003). Adsorption of polyethylene glycol (PEG) from aqueous solution onto hydrophobic zeolite. J. Coll. Interf. Sci., 260 (2), 273–279 (7 pages).
Chang, M. Y.; Juang, R. S., (2004). Adsorption of tannic acid, humic acid, and dyes from water using the composite of chitosan and activated clay. J. Colloid Interf. Sci., 278 (1), 18–25 (8 pages).
Chang, P. B. L.; Young, T. M., (2000). Kinetics of methyl tert-butyl ether degradation and by-product formation during UV/hydrogen peroxide water treatment. Water Res., 34 (8), 2233–2240 (8 pages).
Chatzopoulos, D.; Varma, A.; Irvine, R. L., (1993). Activated carbon adsorption and desorption of toluent in the aqueous-phase. Aiche. J., 39 (12), 2027–2041 (15 pages).
Chen, C. S.; Hseu, Y. C.; Liang, S. H.; Kuo, J. Y.; Chen, S. C., (2008). Assessment of genotoxicity of methyl-tert-butyl ether, benzene, toluene, ethylbenzene and xylene to human lymphocytes using comet assay. J. Hazard. Mater., 153, 351–356 (6 pages).
Chen, D. Z.; Chen, J. M.; Zhong, W. H., (2009). Enhancement of methyl tert-butyl ether degradation by the addition of readily metabolizable organic substrates. J. Hazard. Mater., 167 (1-3), 860–865 (6 pages).
Chen, D. Z.; Chen, J. M.; Zhong, W. H.; Cheng, Z. W., (2008). Degradation of methyl tert-butyl ether by gel immobilized Methylibium petroleiphilum PM1. Bioresour. Tech., 99 (11), 4702–4708 (7 pages).
El Diwani, G.; El Rafie, S.; Hawash, S., (2009). Degradation of 2, 4, 6-trinitotoluene in aqueous solution by ozonation and multi-stage ozonation biological treatment. Int. J. Environ. Sci. Tech., 6 (4), 619–628 (10 pages).
Fiorenza, S.; Rifai, H. S., (2003). Review of MTBE biodegradation and bioremediation. Bioremed. J., 7 (1), 1–35 (35 pages).
Hsieh, L. T.; Yang, H. H.; Chen, H. W., (2006). Ambient B TEX a nd MTBE in the neighborhoods of different industrial parks in Southern Taiwan. J. Hazard. Mater., 128 (2–3), 106–15 (10 pages).
Ji, B.; Shao, F.; Hu, G.; Zheng, S.; Zhang, Q.; Xu, Z., (2009). Adsorption of methyl tert-butyl ether (MTBE) from aqueous solution by porous polymeric adsorbents. J. Hazard. Mater., 161 (1), 81–87 (7 pages).
Johnson, R.; Pankow, J.; Bender, D.; Price, C.; Zogorski, J., (2000). MTBE — To what extent will past releases contaminate community water supply wells? Environ. Sci. Tech., 34, 210A–217A (8 pages).
Kharoune, M.; Pauss, A.; Lebeault, J. M., (2001). Aerobic biodegradation of an oxygenatesmixture: ETBE, MTBE and TAME in an upflow fixed-bed reactor., Water Res., 35 (7), 1665–1674 (10 pages).
Kim, Y. H.; Kim, C. M.; Choi, I. H.; Rengaraj, S.; Yi, J. H., (2004). Arsenic removal using mesoporous alumina prepared via a templating method. Environ. Sci. Tech., 38 (3), 924–931 (8 pages).
Kumar, K. V.; Ramamurthi, V.; Sivanesan, S., (2005). Modeling the mechanism involved during the sorption of methylene blue onto fly ash. J. Colloid Interf. Sci., 284 (1), 14–21 (8 pages).
Ozcan, A. S.; Erdem, B.; Ozcan, A., (2004). Adsorption of Acid Blue 193 from aqueous solutions onto Na-bentonite and DTMA-bentonite. J. Coll. Interface Sci., 280 (1), 44–54 (11 pages).
Rengaraj, S.; Kim, Y.; Joo, C. K.; Yi, J., (2004). Removal of copper from aqueous solution by aminated and protonated mesoporous aluminas: kinetics and equilibrium. J. Coll. Interf. Sci., 273 (1), 14–21 (8 pages).
Shih, T. C.; Wangpaichitr, M.; Suffet, M., (2003). Evaluation of granular activated carbon technology for the removal of methyl tertiary butyl ether (MTBE) from drinking water. Water Res., 37 (2), 375–385 (11 pages).
Soltanali, S.; Shamshagani, Z., (2008). Modeling of air stripping from volatile organic compounds in biological treatment processes. Int. J. Environ. Sci. Tech., 5 (3), 353–360 (8 pages).
Squillace, P. J.; Zogorski, J. S.; Wilber, W. G.; Price, C. V., (1996). Preliminary assessment of the occurrence and possible sources of MTBE in groundwater in the United States, 1993-1994. Environ. Sci. Tech., 30 (5), 1721–1730 (10 pages).
Suffet, I. H.; Wable, O., (1995). Removal of taste-and-odor compounds by activated carbon, in: Suffet, I. H.; Mallevialle, J.; Kawczyski, E. (Eds.), Advances in taste-and-odor treatment and control. American Water Works Research Foundation, Colombia.
Suidan, M. T.; Esperanza, M.; Zein, M.; McCauley, P.; Brenner, R. C.; Venosa, A. D., (2005). Challenges in biodegradation of trace organic contaminants — Gasoline oxygenates and sex hormones. Water Environ. Res., 77 (1), 4–11 (8 pages).
Sutherland, J.; Adams, C.; Kekobad, J., (2004). Treatment of MTBE by air stripping, carbon adsorption, and advanced oxidation: Technical and economic comparison for five groundwaters. Water Res., 38 (1), 193–205 (13 pages).
Wilhelm, M. J.; Adams, V. D.; Curtis, J. G.; Middlebrooks, E. J.,(2002). Carbon adsorption and air-stripping removal of MTBE from river water. J. Environ. Eng., 128 (9), 813–823 (11 pages).
Wu, F. C.; Tseng, R. L.; Juang, R. S., (2001). Kinetic modeling of liquid-phase adsorption of reactive dyes and metal ions on chitosan. Water Res., 35 (3), 613–618 (6 pages).
Yang, X. Y.; Al-Duri, B., (2005). Kinetic modeling of liquidphase adsorption of reactive dyes on activated carbon. J. Coll. Interf. Sci., 287 (1), 25–34 (10 pages).
Yang, X. Y.; Otto, S. R.; Al-Duri, B., (2003). Concentration-dependent surface diffusivity model (CDSDM): Numerical development and application. Chem. Eng. J., 94 (3), 199–209 (11 pages).
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Chen, D.Z., Zhang, J.X. & Chen, J.M. Adsorption of methyl tert-butyl ether using granular activated carbon: Equilibrium and kinetic analysis. Int. J. Environ. Sci. Technol. 7, 235–242 (2010). https://doi.org/10.1007/BF03326133
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DOI: https://doi.org/10.1007/BF03326133