Abstract
For the idealized state of the gaseous components of an electrolytic plasma, we compute the thermodynamic parameters of their interaction with aluminum, magnesium, and zirconium (equilibrium constants and the characteristics of completeness of chemical reactions). It is shown that the process of synthesis of Al2O in the electrolytic plasma includes several stages and passes through the formation intermediate compounds such as AlO and Al2O3. We indicate preferable reactions for the maximum output of the final product in the process of synthesis of Al2O3 and ZrO2. As pressure increases to 1 MPa, the temperature dependences of the output of the products of synthesis must shift toward higher temperatures.
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Karpenko Physicomechanical Institute, Ukrainian Academy of Sciences, L'viv. Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 36, No. 1, pp. 56–64, January–February, 2000.
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Klapkiv, M.D., Chuchmarev, O.S., Sydor, P.Y. et al. Thermodynamics of the interaction of aluminum, magnesium, and zirconium with components of an electrolytic plasma. Mater Sci 36, 66–79 (2000). https://doi.org/10.1007/BF02805119
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DOI: https://doi.org/10.1007/BF02805119