Abstract
For the last few years fast ion conducting lithium glasses are being studied due to their potential use in advanced electrochemical devices. A number of glass systems containing oxides, sulphides and other lithium compounds prepared by both conventional cooling and rapid quenching techniques have been reported. In this paper we review the transport properties of lithium ion conducting glasses. The special features of the ionic conduction process have been highlighted and some experimental techniques to study transport properties have been described. Some of the common observations of the properties have been discussed and finally some important problems for future development have been pointed out.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Abou El Anour A 1979 Ph.D. Thesis, Besancon
Abour El teil M, Heasley J and Omer M H 1978Phys. Chem. Glasses 19 37
Angell C A 1981Solid State Ionics 5 659
Armstrong R D, Dickinson T and Wills P M 1974J. Electroanal. Chem. 53 389
Barsoum M, Velez M H, Tuller H L and Uhlmann D R 1981Surfaces and interfaces in ceramic and ceramicmetal systems (eds) J Pask and A Evans (New York: Plenum) p. 567
Basu B, Maiti H S and Paul A 1983Bull. Mater. Sci. 5 21
Bauck F G K 1975Mass transport phenomena in ceramics (eds) A R Cooper and A H Heuer (New York: Plenum) p. 337
Baurale J E 1969J. Phys. Chem. Solids 30 2657
Biefeld R M, Johnson R T and Banghman R J 1978J. Electrochem. Soc. 125 179
Boehm L and Angell C A 1979Fast ion transport in solids (eds) P Vashishtha, G K Shenoy and J N Mundy (North-Holland: Elsevier) p. 721
Bottelberghs P H 1978Solid electrolytes, general principles, characterization, materials applications (eds) P Hagenmuller and W vanGool (New York: Academic Press) p. 145
Bray P J and O’Keefe J G 1963Phys. Chem. Glasses 4 37
Bray P J, Feller S A, Jellinson G E Jr and Yen Y H 1980J. Non Cryst. Solids 38, 39 93
Britzs D 1980Anal. Chem. 52 1166
Button D P, Tondon R P and Uhlmann D R 1980J. Non Cryst. Solids 42 297
Button D P, Tondon R P, King C, Velez M H, Tuller H L and Uhlmann D R 1982J. Non Cryst. Solids 49 129
Charles R J 1961J. Appl. Phys. 32 1115
Charles R J 1966J. Am. Ceram. Soc. 49 55
Doreau M, Anou El Anour A and Robert G 1980aMat. Res. Bull. 15 285
Doreau M and Robert G 1980Mater. Res. Bull. 15 1499
Downing H L, Peterson N L and Jain H 1982J. Non Cryst. Solids 50 203
Evastrop’eV K K, Veksler G I and Kondrat’eva B S 1974Dokl. Akad. Nauk. SSR 215 902
Geissberger A E, Bucholty F and Bray P J 1982aJ. Non Cryst. Solids 49 117
Glass A M, Nassau K and Negram T J 1978J. Appl. Phys. 49 4808
Glass A M, Nassau K and Olson D H 1979Fast ion transport in solids (eds) P Vashishtha, G K Shenoy and J N Mundy (North Holland: Elsevier) p. 707
Glass A M and Nassau K 1980J. Appl. Phys. 51 3756
Grant R J, Ingram M D and West A R 1977J. Electroanal. Chem. 80 239
Hagenmuller P, Levasseur A, Lucat C, Reau J M and Villeneuve G 1979Fast ion transport in solids (eds) P Vashishtha, G K Shenoy and J N Mundy (North-Holland: Elsevier) p. 637
Hakim R M and Uhlmann D R 1971Phys. Chem. Glasses 12 132
Hodge I M, Ingram M D and West A R 1976J. Electroanal. Chem. 74 125
Hughes K and Isard J O 1972Physics of electrolytes (ed.) J H Hladik (New York: Academic Press) Vol. 1 p. 351
Irion M, Couzi M, Levasseur A, Reau J M and Brethous J C 1980Solid State Chem. 31 285
Jagla M and Isard J O 1980Mat. Res. Bull. 15 1327
Jeitschko W and Bither T A 1972aZ. Naturforsch. B27 1423
Jeitschko W 1972bActa Crystallogr. B28 60
Jeitschko W, Bither T A and Bierstedt 1977Acta Crystallogr. B33 2767
Johnscher A K 1978J. Mater. Sci. 13 553
Johnson R T, Morrison B, Knotek M L and Biefeld R M 1975Phys. Lett. A54 403
Johnson R T, Biefeld R M, Knotek M L and Morrison B 1976J. Electrochem. Soc. 123 680
Kone A, Barrau B, Souquet J L and Ribes M 1979Mat. Res. Bull. 14 393
Kone A, Ribes M and Souquet J L 1982Phys. Chem. Glasses 23 18
Kulkarni A R, Maiti H S and Paul A 1981Glass formation and electrical conductivity in the system LiF-Li 2 O-Al(PO 3)3, paper presented in the 45th Annual Session of Indian Ceramic Society
Kulkarni A R, Maiti H S and Paul A 1984 (to be published)
Kulkarni A R 1984aLithium ion conducting glassy solid electrolytes in the LiF-Li 2 O-Al(PO3)3 system. Ph.D. Thesis submitted to IIT Kharagpur
Levasseur A, Cales B, Reau J M and Hagenmuller P 1978Mat. Res. Bull. 13 205
Levasseur A, Brethous J C, Reau J M and Hagenmuller P 1979Mater. Res. Bull. 14 921
Levasseur A, Kabla M, Brethous J C, Reau J M, Hagenmuller P and Couzi M 1979aSolid State Commun.32 839
Levasseur A, Brethous J C, Hagenmuller P, Berge R and Vignand G 1979bSolid State Commun.32 115
Levasseur A, Brethous J C, Reau J M, Hagenmuller P and Couzi M 1980Solid State Ionics 1 117
Levasseur A 1981Report EUR 7070FR Comm. European Communities Luxemberger p. 40
Levasseur A, Olazcuaga R, Kabla M, Zahir M, Hagenmuller P and Couzi M 1981Solid State Ionics 2 205
Levasseur A, Brethous J C, Kabla M and Hagenmuller P 1981bSolid State Ionics 5 651
MacDonald J R 1976aSuperionic conductors (eds) G D Mahan and W L Roth (New York: Plenum Press) p. 81
MacDonald J R and Jacobs P W M 1976bJ. Phys. Chem. Solids 37 1117
Maiti H S, Kulkarni A R and Paul A 1983Lithium conducting glassy solid electrolytes in the LiF-Li 2 O-Al(PO3)3 system Paper presented in the 4th International Conference on Solid State Ionics Grenoble France
Malugani J P, Wasniewski A, Doreau M and Robert G 1978C R Acad. Sci. Paris 287 455
Malugani J P and Robert G 1979Mater. Res. Bull. 14 1075
Malugani J P and Robert G 1980Solid State Ionics 1 519
Mercier R, Malugani J P, Fahys B and Robert G 1981Solid State Ionics 5 663
Nakajima T 19721971 annual report conference on electrical insulation and dielectric phenomena, Natl. Acad. Sci.
Nassau K, Wang C A and Grasso M 1979aAm. Ceram. Soc. 62 74
Nassau K, Wang C A and Grasso M 1979bAm. Ceram. Soc. 62 503
Nassau K, Glass A M and Olson D H 1980J. Electrochem. Soc. 127 2743
Nassau K, Cava R J and Glass A M 1981aSolid State Ionics 2 163
Nassau K and Glass A M 1981bJ. Non. Cryst. Solids 44 97
Otto K 1966Phys. Chem. Glasses 7 29
Otto K and Milberg M E 1968J. Am. Ceram. Soc. 51 326
Peterson N L 1982Philos. Mag. 46 351
Prasad E, Sayer M and Vyas H M 1980J. Non Cryst. Solids 40 119
Pronkin A A 1978Sov. J. Phys. Chem. 4 388
Ravaine D and Souquet J L 1973Proc. 24th Meeting ISE Eindhoven
Ravaine D and Souquet J L 1974J. Chim. Phys. 71 693
Ravaine D and Souquet J L 1977Phys. Chem. Glasses 18 27
Ravaine D and Souquet J L 1978Solid electrolytes, general principles, characterization, materials application (eds) P Hagenmuller and W vanGool (New York: Academic Press) p. 277
Ribes M, Ravaine D, Souquet J L and Maurin M 1979Rev. Chim. Miner. 16 339
Ribes M, Barrau B and Souquet J L 1980J. Non-Cryst. Solids 38, 39 271
Smedly S I and Angell C A 1978Solid State Commun. 27 21
Smedely S I and Angell C A 1980Mat. Res. Bull. 15 421
Shlesing M 1980Bull. Am. Phys. Soc. 25 434
Souquet J L, Kone A and Ribes M 1980J. Non Cryst. Solids 38, 39 307
Stevels J M 1957The Electrical properties of glass in Handbook der Physics (Berlin: Springer-Verlag) Vol. 20 p. 380
Tabby M P and Hendrickson J R 1980J. Non Cryst. Solids 38, 39 51
Takahashi T and Yamamoto Y 1979Chem. Lett. 135
Taylor H E 1959J. Soc. Glass Tech. 43 124T
Tomozawa M 1977Treattse on materials science and technology (eds) M Tomozawa and R H Doremus (New York: Academic Press) Vol 12 p. 283
Tubandt C 1932Handbuch der Experimental Physik (eds) W Weiss and F Harms (Leipzig: Akademische Verlagsgesellschaft) Vol 21 p. 383
Tuller H L, Button D P and Uhlmann D R 1980J. Non Cryst. Solids 40 93
Velez M H, Tuller H L and Uhlmann D R 1982J. Non Cryst. Solids 49 351
Wagner C 1956Z. Electrochem. 60 4
Wagner C 1957International Committee of Electrochemical Thermodynamics and Kinetics, Proceeding 7th Meeting Butterworths London
Walraffen G E 1965J. Chem. Phys. 43 479
Warburg G 1884Ann. Phys. 21 622
Yakoto I 1955J. Phys. Soc. Jpn. 8 595
Yasui I, Ohta E, Hasegawa H and Imaoka M 1982J. Non Cryst. Solids 52 283
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kulkarni, A.R., Maiti, H.S. & Paul, A. Fast ion conducting lithium glasses—Review. Bull. Mater. Sci. 6, 201–221 (1984). https://doi.org/10.1007/BF02743897
Issue Date:
DOI: https://doi.org/10.1007/BF02743897