Abstract
One way of enhancing the thermal stability and NOx, THC and CO conversion of a catalyst is to improve the thermal stability and oxygen storage capacity (OSC) of the ceria. The appropriate mixing ratios of bulk and stabilized ceria are especially very important for designing Pd-only three-way catalysts. In this paper, we discuss the surface phenomena of stabilized and unstabilized (bulk) ceria, the OSC of catalysts, and the correlation between activity and OSC of Pd-only catalysts with mixing ratios of bulk ceria and stabilized ceria.
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Belton, D.N., Schmieg, S.J., Permana, H., Hori, C. E., Simon, K. Y. and Brenmer, A., “How and Why Incorporating ZrO2 into Automotive Catalysts Improves Their Catalytic Activity”, 15th NAM poster abstract, p.231 (1997).
Brisley, R. J., Chandler, G. R., Jones, H. R., Ander, P. J. and Shady, P. J., “The Use of Palladium in Advanced Catalysts”, SAE950259.
Diwell, A. F., Rajaram, R. R., Shaw, H. A. and Truex, T. J., “The Role of Ceria in Three-Way Catalysts”, Catalysis and Automotive Pollution Control II, 139 (1991).
Kubish, J. E., Rieck, J. S. and Spencer, N. D., “Cerium Oxide Stabilization: Physical Property and Three-way Activity Considerations”, Catalysis and Automotive Pollution Control II, 125 (1991).
Muraki, H., “Performance of Palladium Automotive Catalysts’, SAE910842.
Summers, J. C., Williamson, W. B. and Henk, M. G., “Uses of Palladium in Automotive Emission Control Catalysts”, SAE880281.
Yoon, K. J., Kang, H. K. and Yie, J. E., “Synergism and Kinetics in CO Oxidation over Palladium-Rhodium Bimetallic Catalysts,”Korean J. Chem. Eng.,14, 399 (1997).
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Shin, BS., Bae, JH., Yoo, JP. et al. Correlation between activity and oxygen storage capacity of ceria on Pd-only three-way catalysts. Korean J. Chem. Eng. 15, 474–479 (1998). https://doi.org/10.1007/BF02707094
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DOI: https://doi.org/10.1007/BF02707094