Abstract
Formation of the homologous series of layered compounds nBi2-mBi2Te3 and nGeTe mBi2Te3 is analyzed. For both series, the crystal structure contains two-layer (Bi2 or GeTe) and five-layer (Bi2Te3) packets perpendicular to the c axis. Unlike the Bi2 packets, the GeTe packets do not retain their individuality during crystal structure formation; they are linked to the Bi2Te3 five-layer packets to form new multilayer packets leading to a considerable change in the character of interatomic interactions.
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Translated from Zhumal Struktumoi Khimii, Vol. 41, No. 1, pp. 97-105, January–February, 2000.
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Shelimova, L.E., Karpinskii, O.G., Kosyakov, V.I. et al. Homologous series of layered tetradymite-like compounds in Bi-Te and GeTe-Bi2Te3 systems. J Struct Chem 41, 81–87 (2000). https://doi.org/10.1007/BF02684732
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DOI: https://doi.org/10.1007/BF02684732