Abstract
Data on the mechanisms of primary recrystallization in covalent type ceramics under temperature-and-pressure treatment are generalized and discussed. There are three types of structural transformations governing nucleation during primary recrystallization. I. Formation of intragrain boundaries. As a result of plastic shears boundaries appear to be kinked due to dislocation pile-ups (materials based on 2H BN, 6H SiC). With deformation by total dislocations the boundaries arise as a result of dynamic recovery due to rebuilding of dislocation pile-ups (AlN, β-Si3N4, TiB2). II. Twinning. This structural transformation promotes the formation of recrystallization nuclei in the following cases: a) with insertion of lattice dislocations into the boundaries of strain-induced twins; b) with formation of annealing twins; c) with development of multiple twinning near grain boundaries (3C BN). III. Structural transformations in migrating boundaries: a) splitting of boundaries and ternary junctions (3C BN); b) local bulging of boundaries (3C BN); c) generation of high-angle and platelet twins (3C BN); d) plastic rotation of material microvolumes near grain boundaries (3C BN, SiC).
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References
S. S. Gorelik, Recrystallization of Metals and Alloys [in Russian], Metallurgiya, Moscow (1978).
F. Hessner (ed.), Recrystallization of Metallic Materials [Russian translation], Metallurgiya, Moscow (1982).
E. E. Zasimchuk, Polygonization, Recrystallization and Thermal Stability of Material Properties [in Russian], Naukova Dumka, Kiev (1976).
Metal Recovery and Recrystallization [in Russian], Metallurgiya, Moscow (1966).
L. N. Larikov, “Dynamic recovery and dynamic recrystallization,” Izv. Akad. Nauk SSSR, Metally, No. 2, 69–75 (1982).
T. Sakai and J. J. Jonas, “Dynamic recrystallization: mechanical and microstructural consideration,” Acta. Met.,32, No. 2, 189–209 (1984).
O. A. Kaibyshev, Superplasticity of Commercial Alloys [in Russian], Metallurgiya, Moscow (1982).
R. M. Pulrath, “Hot forming process,” Bull. Amer. Ceram. Soc.,43, No. 12, 880–885 (1964).
R. W. Rice, “Deformation, recrystallization, strength and fracture of press-formed ceramic crystals,” J. Amer. Ceram. Soc.,55, No. 2, 90–97 (1972).
G. S. Oleinik, N. V. Danilenko, and Yu. I. Lezhnenko, “Primary recrystallization of ceramic materials” in: Electron Microscopy and Strength of Materials [in Russian], Materials Science Institute, Ukrainian Academy of Sciences Kiev (1995).
J.-P. Puar’e, Creep of Crystals. Mechanisms of Metal, Ceramic and Mineral Deformation at High Temperature [Russian translation], Mir, Moscow (1988).
M. R. Drury, F. J. Hamphreys, and S. U. White, “Effect of dynamic recrystallization on the importance of grain-boundary sliding during creep,” J. Mater. Sci.,34, No. 1, 154–165 (1989).
H. G. Muller, “Nature of recrystallization: I–III,” Z. Physik,96, 279–327 (1935).
Ch. V. Kopetskii, N. M. Nadgornaya, and E. M. Nadgornyi, “Structure and properties of NaCl single crystals deformed under conditions of dynamic recrystallization,” Fiz. Tverd. Tela,2, No. 3, 757–765 (1982).
V. I. Trefilov, Yu. V. Mil’man, I. F. Kazo, and I. V. Gridneva, “Effect of annealing on the structure of deformed Si and Ge,” Metallofizika,2, No. 2, 68–75 (1980).
O. A. Kaibyshev, N. G. Zaripov, L. V. Petrova, and O. Yu. Efimov, “Superplasticity of oxide and oxygen-free ceramics”, Inzh.-Fiz. Zh.,65, No. 5, 617–622 (1993).
B. Pratt, S. Kulkarni, D. P. Pope, et al., “Deformation and recrystallization textures in compressed polycrystalline silicon,” Met. Trans.,A8, No. 11, 1799–1804 (1977).
O. A. Kaibyshev, R. M. Imaev, and M. F. Imaev, “Superplasticity of ceramic compound YBa2Cu3O7−x,” Dokl. Akad. Nauk SSSR,305, No. 5, 1120–1123 (1989).
L. R. Fleischer and J. M. Tobin, “Growth of transition metal carbide single crystals by recrystallization,” J. of Crystal Growth,8, No. 3, 243–246 (1971).
R. D. Baeta and K. H. G. Ashbee, “Transition electron microscopy studies of plastically deformed quartz,” Phys. Stat. Sol. (a),18, No. 1, 155–170 (1973).
D. Laister and G. M. Jenkins, “Deformation of single crystals of gallium arsenide,” J. Mater. Sci.,8, No. 9, 1218–1232 (1973).
P. C. Panda, R. Raj, and P. E. D. Morgan, “Superplastic deformation in fine-grained MgO·2Al2O3 spine,” J. Amer. Ceram. Soc.,68, No. 10, 522–529 (1985).
J. S. Haggerty and D. W. Lee, “Plastic deformation of ZrB2 single crystals,” J. Amer. Ceram. Soc.,54, No. 11, 572–576 (1971).
H.-E. Kim and A. J. Moorhead, “Optical and mechanical properties of hot-pressed cesium iodide,” J. Amer. Ceram Soc.,73, No. 3, 496–501 (1990).
J. D. Daw and P. S. Nicholson, “Primary recrystallization during the hot pressing of MgAl2O4,” J. Amer. Ceram. Soc.,58, Nos. 3–4, 109–112 (1975).
R. B. Day and R. J. Stokes, “Mechanical behavior of magnesium oxide at high temperatures” J. Amer. Ceram. Soc.,47, No. 10, 493–503 (1964).
R. W. Rice and J. G. Hunt, “Hot extrusion of MgO,” Amer. Ceram. Soc. Bull.,43, No. 4, 279 (1964).
A. N. Evans and T. L. Langdon, Structural Ceramics [Russian translation], Metallurgiya, Moscow (1980).
M. F. Imaev, R. M. Imaev, O. A. Kaibyshev, et al., “Microstructural changes with hot extrusion of polycrystalline ceramic YBa2Cu3O7−x,” Sverkhprovodimost’: Fiz. Khim. Tekh.,4, No. 11, 2213–2221 (1991).
A. M. Glaoser, R. M. Cannon, and H. K. Bowen, “Hot forging of CaF2,” Amer. Ceram. Soc. Bill.,56, No. 3, 290 (1977).
A. H. Heuer, D. J. Sellers, and W. H. Rhodes, “Hot working of aluminum oxide. I. Primary recrystallization and texture,” J. Amer. Ceram. Soc.,52, No. 9, 468–474 (1969).
M. J. Klein, F. A. Rough, and C. C. Simons, “Structure and annealing behavior of explosively shocked magnesia single crystals,” J. Amer. Ceram. Soc.,46, No. 7, 356–358 (1963).
S. Sawai and K. Kondo, “Characterization of the grain boundary of shock-compacted diamond,” J. Amer. Ceram. Soc.,71, No. 4, 185–188 (1988).
S. A. Bozhko, “Study of the recrystallization of refractory carbides in the homogeneity region,” Diss. Cand. Tech. Sci., Kiev (1970).
G. S. Oleinik, V. V. Yarosh, O. A. Shevchenko, and D. Z. Yurchenko, “Microstructure of polycrystalline aluminum nitride formed in shock waves,” Poroshk. Metall., No. 10, 65–69 (1992).
G. I. Savrakin, T. V. Dubovik, and G. S. Oleinik, “Structural study of material based on graphite-like boron nitride subject to detonation treatment,” Poroshk. Metall., Nos 9–10, 12–17 (1995).
N. E. Sergeeva, N. I. Eremin, and M. V. Pechnikova, “Thermal recrystallization of sulfides,” Vestn. Moskov Univ., No. 4, 41–54 (1975).
S. U. White, “The effect of strain and microstructure fabrics and deformation mechanisms in quartzite,” Philos. Trans. Roy. Soc. London A,283, 69–86 (1976).
I. G. Kushtalova, “Study of recrystallization processes for refractory compounds,” Diss. Cand. Tech. Sci., Kiev (1967).
P. J. Whalen, F. Reidinger, and R. F. Antrim, “Prevention of low-temperature surface transformation by surface recrystallization in yttria-doped tetragonal zirconia,” J. Amer. Ceram. Soc.,72, No. 2, 319–321 (1989).
T. A. Parthasarathy and P. G. Shewmon, “Diffusion induced recrystallization of NiO,” Acta Met.,32, No. 1, 29–33 (1984).
J.-J. Kim, B.-M. Song, and D.-Y. Kim, “Chemically induced grain boundary migration and recrystallization in PLZI ceramics,” Amer. Ceram. Soc. Bull.,65, No. 10, 1390–1392 (1986).
S. S. Gorelik, T. B. Sagalova, and Yu. S. Safonov, “Features of structure formation for polycrystalline semiconductor films,” Tsvet. Met., No. 3, 84–90 (1981).
A. N. Pilyankevich and G. S. Oleinik, “Structure formation of polycrystalline superhard materials at high pressures and temperatures,” in: Effect of High Pressures on a Substance, Vol. 1 [in Russian], Naukova Dumka, Kiev (1987).
V. I. Trefilov, S. A. Nachevkin, G. I. Sawaki, et al., “Formation of the microstructure during sintering of detonation synthesis diamond powders,” Dokl. Akad. Nauk SSSR,283, No. 6, 1379–1381 (1985).
S. A. Nochevkin and G. S. Oleinik, “Barodynamic polygonization and recrystallization of diamond”, in: Change in the Properties of Materials Under the Action of High Pressures [in Russian], Materials Science Institute, Ukrainian Academy of Sciences, Kiev (1986).
G. S. Oleinik, A. A. Bochechka, and N. V. Danilenko, “Features of the structural state of polycrystalline diamond obtained in the high temperature sintering region,” Sverkhtverd. Mater., No. 6, 32–41 (1977).
I. N. Frantsevich, V. A. Kravets, and K. V. Nazarenko, “Relaxation processes in α-SiC single crystals “, Fiz. Tekh. Vysokikh Davlenii, No. 10, 38–42 (1982).
A. N. Pilyankevich, V. F. Britun, and G. S. Oleinik, “Transformation in boron carbide at high pressures and temperatures,” in: Electron Microscopy and Strength of Materials [in Russian], Materials Science Institute, Ukrainian Academy of Sciences, Kiev (1989).
H. W. Green, “Quartz: extreme preferred orientation produced by annealing,” Science,157, No. 3795, 1444–1447 (1967).
G. S. Oleinik, Yu. Lezhnenko, V. F. Britun, and N. P. Semenenko, “Structural transformations in titanium diboride at high pressures and temperatures,” Sverkhtverd. Mater., No. 2, 28–31 (1992).
G. S. Oleinik and N. V. Danilenko, “Deformation mechanism for forming recrystallization centers of the sphaleritic phase forming from wurtzitic phase BN,” Sverkhtverd. Mater., No. 1, 12–17 (1995).
G. S. Oleinik and N. V. Danilenko, “Features of the wurtzite—sphalerite type transition in the initial stage of primary recrystallization of BN and SiC,” Sverkhtverd. Mater., No. 6, 78–82 (1996).
G. S. Oleinik, I. A. Petrusha, Yu. I. Lezhnenko, and N. V. Danilenko, “High-temperature recrystallization of sphaleritic boron nitride,” Sverktverd. Mater., No. 2, 4–34 (1995).
N. V. Danilenko, G. S. Oleinik, and N. P. Semenenko, “Structural transformations in polycrystalline β-Si3N4 at high pressures and temperatures,” Poroshk. Metall., No. 8, 5–10 (1992).
N. V. Danilenko, G. S. Oleinik, V. B. Shipilo, and Yu. I. Lezhnenko, “Structural changes in A1N with an increase in the duration temperature-and-pressure treatment,” Fiz. Tekh. Vysokikh, Davlenii, No. 2, 80–95 (1996).
G. S. Oleinik, N. V. Danilenko, A. A. Bochechka, and A. V. Kotko, “Recrystallization mechanisms for silicon carbide at high pressures and temperatures,” Fiz. Tekh. Vysokikh Davlenii, No. 4, 20–31 (1996).
V. F. Britun, G. S. Oleinik, and A. N. Pilyankevich, “Structural rebuilding mechanisms in hexagonal silicon carbide at high pressures and temperatures,” Ukr. Fiz. Zh.,33, No. 5, 791–794 (1988).
N. V. Ivchenko, R. I. Kuznetsov, and B. B. Beresnev, “Effect of hydrostatic pressure on the recrystallization of CsJ(Tl) crystals,” Fiz. Tekh. Vysokikh Davlenii, No. 21, 30–37 (1986).
A. N. Pilyankevich, G. S. Oleinik, and V. F. Britun, “Electron microscope study of the phase transition 2H→3C in boron nitride,” Sverkhtverd. Mater., No. 1, 18–24 (1988).
G. S. Oleinik and Yu. I. Lezhnenko, “Microstructural features of fault formation in SiC(6H) and BN(2H) crystals at high pressures,” Sverkhtverd. Mater., No. 1, 26–31 (1993).
V. A. Strel’tsov, V. I. Zaitsev, and T. A. Ryumshina, “Compression anisotropy effects and their role in studies of the plastic deformation of hydrostatically compressed crystal systems,” Fiz. Tekh. Vysokikh Davlenii, No. 3, 8–19 (1991).
V. Britun and G. S. Oleinik, “Features of the mechanical twinning of diamond and sphaleritic boron nitride at high pressures and temperatures,” in: Electron Microscopy and the Strength of Materials [in Russian], Materials Science Institute, Ukrainian Academy of Sciences, Kiev (1991).
A. R. Jones, “Annealing twinning and the nucleation of recrystallization at grain boundaries,” J. Mater. Sci.,16, No. 5, 1374–1380 (1981).
T. E. Konstantinova, V. B. Primisler, and A. A. Dobrikov, “Structural defects and modes of the mesoscopic level of plastic deformation,” Fiz. Tekh. Vysokikh Davlenii,2, No. 4, 5–10 (1992).
C. M. F. Rae, C. R. M. Grovenor, and K. M. Knowles, “Multiple twinning and recrystallization,” Z. Metallkunde.72, No. 11, 718–801 (1981).
J. A. Kohn, “Twinning in a structure of the diamond type,” in: Defects in Semiconductor Crystals [Russian translation], Mir, Moscow (1969), pp. 38–71.
J. A. Kohn and D. W. A. Eckart, “A twinning study of cubic (β) silicon carbide,” American Mineralogist,47, No. 9-10, 1000–1004 (1962).
V. A. Pavlov, N. I. Noskova, and R. I. Kuznetsov, “Effect of packing defects on the mechanical properties of metals,” Fiz. Met. Metalloved.,24, No. 5, 945–965 (1967).
V. A. Feigin, L. I. Yakovenkova, and L. E. Kar’kina, “Change in the Properties of Materials Under the Action of High Pressures [in Russian], Materials Science Institute, Ukrainian Academy of Sciences, Kiev (1986).
G. S. Oleinik and N. V. Danilenko, “Processes of plastic deformation in ceramics,” Preprint No. 10: Institute Materials Science Institute, Ukrainian Academy of Sciences, Kiev (1997).
G. Gottstein and U. F. Kocks, “Dynamic, recrystallization and dynamic recovery in <111> single crystals of nickel and copper,” Acta Met.,31, No. 1, 175–189 (1983).
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Materials Science Institute, Ukrainian Academy of Sciences, Kiev. Translated from Poroshkovaya Metallurgiya. Nos. 1-2, pp. 63–77, January–February, 1998.
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Oleinik, S.G., Danilenko, N.V. Primary recrystallization mechanisms in ceramic materials. Powder Metall Met Ceram 37, 55–66 (1998). https://doi.org/10.1007/BF02677231
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DOI: https://doi.org/10.1007/BF02677231