Abstract
The application of the compound energy model to crystalline ionic phases is discussed and compared with the regular solution model. Its application to solutions with reciprocal reactions between cations on different sublattices is discussed with special reference to oxides. Examples are taken from various solutions between spinels, including cases with vacancies and interstitials. Problems connected with the choice of a state of reference for charged components in a multicomponent solution are addressed. This paper was presented at the International Phase Diagram Prediction Symposium sponsored by the ASM/MSD Thermodynamics and Phase Equilibria Committee at Materials Week, October21-23,1991, in Cincinnati, Ohio. The symposium was organized by John Morral, University of Connecticut, and Philip Nash, Illinois Institute of Technology.
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Barry, T.I., Dinsdale, A.T., Gisby, J.A. et al. The compound energy model for ionic solutions with applications to solid oxides. JPE 13, 459–475 (1992). https://doi.org/10.1007/BF02665760
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DOI: https://doi.org/10.1007/BF02665760