Abstract
The problem of relating interaction coefficients applicable to conditions of constant chemical potential of one of the solute elements in a solution to the usual interaction coefficients at infinite dilution is treated. The formal relationships are applied to data on the Fe-Cr-C(sat) system at 1600°C and to results presented earlier on the Fe-P-C(sat) system at 1600°C. An alternative treatment for obtaining interaction coefficients for relatively concentrated solutions by a statistical technique is also presented and applied to data on the Fe-Cr-P system. When applicable, the former is considered to be more reliable.
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T. Fuwa and J. Chipman:Trans. TMS-AIME, 1959, vol. 215, pp. 708–16.
F. Neumann, H. Schenck, and W. Patterson:Giesserei Tech., Wiss. Beih., 1959, pp. 1217–56.
C. Wagner:Thermodynamics of Alloys, p. 51, Cambridge, Mass., 1952.
C. H. P. Lupis and J. F. Elliott:Acta Met., 1966, vol. 14, pp. 529–38.
C. H. P. Lupir:Acta Met., 1968, vol. 16, pp. 1365–75.
M. G. Frohberg, J. F. Elliott, and H. G. Hadrys:Arch. Eisenhuettenw., 1968, vol. 39, pp. 587–93.
A. Rist and J. Chipman:The Physical Chemistry of Steelmaking, J. F. Elliott, Ed., p. 3, John Wiley & Sons, New York, 1958.
B. C. Allen:Trans. TMS-AIME, 1967, vol. 239, p. 1026.
M. Hansen and K. Anderko:Constitution of Binary Alloys, McGraw Hill Book Co., New York, 1958.
R. Hultgren, R. L. Orr, P. D. Anderson, and K. K. Kelley:Selected Values of Thermodynamic Properties of Metals and Alloys, John Wiley & Sons, New York, 1963.
R. B. Reese, R. A. Rapp, and G. R. St. Pierre:Trans. TMS-AIME, 1968, vol. 242, pp. 1719–26.
H. Wada, Y. Kawai, and T. Saito:Sci Rep. Res. Inst. Tohoku Univ., 1961, vol. A13, pp. 96–104.
M. Onillon and M. Olette:Comptes Rend., 1967, vol. 264–C, p. 46.
A. P. Lyubinov and A. A. Granovskaya:Zhur. Fiz. Khim., 1953, vol. 27, p. 1443.
R. J. Fruehan:Trans. TMS-AIME, 1969, vol. 245, pp. 1215–18.
N. R. Griffing, W. D. Forgeng and G. W. Healy:Trans. TMS-AIME, 1962, vol. 224, pp. 148–59.
M. Ohtani:Sci. Rep. Res. Inst. Tohoku Univ., 1956, vol. A8, pp. 337–51.
K. Sanbongi, M. Ohtani, and K. Toita:Sci. Rep. Res. Inst. Tohoku Univ., 1957, vol. A9, pp. 147–58.
H. Schenck and U. Feldman: thesis, 1956, Technische Hochchule, Aachen.
K. Goto, S. Ban-ya, and S. Matoba:Tetsu-to-Hagané, Overseas, 1963, vol. 3, pp. 184–89.
F. D. Richardson and W. E. Dennis:J. Iron Steel Inst., 1953, vol. 175, pp. 257–66.
C. H. P. Lupis and J. F. Elliott:Acta Met., 1966, vol. 14, pp. 1019–32.
R. Karasev: unpublished, M.I.T., 1959.
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Formerly Graduate Student, Technical University of Berlin, Germany and M.I.T., Cambridge, Mass.
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Hadrys, H.G., Frohberg, M.G., Elliott, J.F. et al. Activities in the liquid Fe-Cr-C(sat), Fe-P-C(sat), and Fe-Cr-P systems at 1600°c. Metall Trans 1, 1867–1874 (1970). https://doi.org/10.1007/BF02642785
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DOI: https://doi.org/10.1007/BF02642785