Abstract
The interaction of NO2 with sublimed films ofmeso-tetraphenylporphyrinatozinc was studied by IR and UV-VIS spectroscopy. The π-radical cation (ZnTPP)•+NO2 − containing an unpaired electron on HOMO of the A2u symmetry is formed at the first stage of the reaction. The second NO2 molecule attacks themeso-carbon atom to form zinc isoporphyrin with the covalently bound nitro group. The IR data indicate that the NO2 − anion is axially coordinated to the central metal atom, and the NO2 group is covalently bonded through the N atom.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
M. P. Byrn, C. J. Curtis, Y. Hsiou, S. I. Khan, P. A. Sawin, S. K. Tendick, A. Terzis, and C. E. Strouse,J. Am. Chem. Soc., 1993,115, 9480.
M. P. Byrn and C. E. Strouse,J. Am. Chem. Soc., 1991,113, 2501.
T. S. Kurtikyan, A. V. Gasparyan, G. G. Martirosyan, and G. A. Zhamkochyan,Zh. Prikl. Spektrosk., 1993,59, 453 [Russ. J. Appl. Spectr., 1993,59 (Engl. Transl.)].
T. S. Kurtikyan, A. V. Gasparyan, G. G. Martirosyan, and G. A. Zhamkochyan,Khim. Zh. Armenii [Armenian Chem. J.], 1995,48, 123 (in Russian).
T. S. Kurtikyan, A. V. Gasparyan, G. G. Martirosyan, and G. A. Zhamkochyan,Zh. Prikl. Spektrosk., 1995,62, 62 [Russ. J. Appl. Spectr., 1995,62 (Engl. Transl.)].
O. A. Golubchikov, O. N. Koifman, and G. V. Ponomarev inPorfiriny: Spektroskopiya, elektrokhimiya, primenenie [Porphyrins: Spectroscopy, Electrochemistry, and Application], Nauka, Moscow, 1987, 214 (in Russian).
T. S. Kurtikyan, G. G. Arutyunyan, R. K. Kazaryan, V. N. Madakyan, and M. B. Ordyan,Khim. Fiz., 1988,7, 933 [Sov. Chem. Phys., 1988,7 (in Russian)].
Y. Sadaoka, Y. Sakai, T. A. Jones, and W. Copel,J. Mater. Sci., 1990,25, 3024.
J. Schoch, T. A. Temofonte, K. R. Sadhir, J. Greggi, and Z. N. Sanjama,Synthetic Metals, 1989,29, F89.
T. S. Kurtikyan, A. V. Gasparyan, G. G. Martirosyan, and G. A. Zhamkochyan,Zh. Prikl. Spektrosk., 1990,52, 106 [Russ. J. Appl. Spectr., 1990,52 (Engl. Transl.)].
A. Adler, F. Kampas, and J. Kim.J. Inorg. Nucl. Chem., 1970,32, 3443.
W. L. Jolly,The Synthesis and Characterization of Inorganic Compounds, Prentice-Hall, New York, 1970, 545.
E. T. Shimomura, M. A. Philippi, H. M. Goff, W. F. Scholz, and G. A. Reed,J. Am. Chem. Soc., 1981,103, 6778.
A. S. Hinman, B. J. Pavelich, and K. McGarty,Can. J. Chem., 1988,66, 1589.
A. Wolberg and J. Manassen,J. Am. Chem. Soc., 1970,92, 3982.
H. J. Shine, A. G. Padilla, and S. M. Nu,J. Org. Chem., 1979,44, 4069.
B. Evans and K. M. Smith,Tetrahedron Lett., 1976, 4863.
D. Dolphin, R. H. Felton, D. C. Borg, and J. Fajer,J. Am. Chem. Soc., 1970,92, 743.
B. D. Berezin and O. N. Koifman,Usp. Khim., 1980,49, 2389 [Russ. Chem. Rev., 1980,49 (Engl. Transl.)].
L. D. Spandling, P. G. Eller, J. A. Bertrend, and R. H. Felton,J. Am. Chem. Soc., 1974,96, 982.
S. G. Clarhson and F. Basolo,Inorg. Chem., 1973,12, 1528.
K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, J. Wiley and Sons, New York, 1986.
S. Hu and T. G. Spiro,J. Am. Chem. Soc., 1993,115, 12029.
E. C. Johnson and D. Dolphin,Tetrahedron Lett., 1976, 2197.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 665–668, April, 1998.
Rights and permissions
About this article
Cite this article
Kurtikyan, T.S., Stepanyan, T.G., Gasparyan, A.V. et al. Interaction of nitrogen dioxide with sublimed films ofmeso-tetraphenylporphyrinatozinc. Russ Chem Bull 47, 644–647 (1998). https://doi.org/10.1007/BF02495969
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02495969