Summary
Sensitivities of a solid surface to dispersive and nondispersive (polar) interactions can be readily estimated by a multiple regression analysis of inverse gas chromatographic retention data of a set of probe solutes. This analysis is based on linear free energy relationships (LFERs). The sensitivity to the latter type of interactions can be used as a measure of the surface polarity of the solid. This has been shown in the case of a graphitized carbon fiber and the method is also applicable to other solids.
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Park, J.H., Lee, Y.K. & Donnet, J.B. A study of solid surface polarity using inverse gas chromatographic retention data. Chromatographia 33, 154–158 (1992). https://doi.org/10.1007/BF02275897
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DOI: https://doi.org/10.1007/BF02275897