Abstract
Selected examples of dehydration, accompanied by violent disintegration or bloating of the decomposing solid substance are presented. This phenomenon has been explained as a specific case of internal decomposition of solids. A sealed box with compressed gaseous products is proposed as a model of the process. The practical applications of this phenomenon are discussed.
Zusammenfassung
Es werden ausgewählte Beispiele für die Dehydratation, begleitet von heftiger Zersetzung oder Aufblähen der zersetzten Feststoffe dargelegt. Diese Erscheinung wird als ein Spezialfall der internen Zersetzung von Feststoffen beschrieben. Als Modell für diesen Prozeß wird ein abgeschlossener Behälter mit unter Druck stehenden gasförmigen Produkten vorgeschlagen. Praktische Anwendungen dieser Erscheinung werden diskutiert.
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References
L. Stoch, J. Thermal Anal., 29 (1984) 919.
L. Stoch, Thermochim. Acta, 110 (1987) 359.
E. A. Prodan, Reactivity of Solids, 4 (1988) 363.
E. A. Prodan, Topokhimiya Kristallov (Topochemistry of Crystals), Nauka i Tekhnika, Minsk 1990.
E. Thilo and M. Wallis, Chem. Ber., 86 (1953) 1213.
H. Worzala and K. H. Jost, Advanced Solid State Chemistry, Proc. 2nd Int. Symposium on Solid State Chemistry, Pardubice 1989, Elsevier, Amsterdam (1989) p. 52.
I. Waclawska, L. Stoch, J. Paulik and F. Paulik, Thermochim. Acta, 126 (1988) 307.
L. Stoch and I. Waclawska, J. Thermal Anal., 20 (1981) 291.
J. Schomburg, 9th Conference on Clay Mineralogy and Petrology, Zvolen 1982, Univerzita Karova, Praha (1984) p. 159.
R. Sh. Mikhali, N. H. Guindy and S. Hanafi, J. Appl. Chem., 70 (1970) 346.
J. Paulik, F. Paulik and M. Arnold, J. Thermal Anal. 32 (1987) 301.
D. Bridson, T. W. Davies and D. P. Harrison, Clays and Clay Min., 33 (1985) 258.
T. W. Davies, S. Colak and R. M. Hooper, 18th Australian Chemical Engineering conf., Auckland, New Zealand 1990, V. 2, p. 1164.
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Dedicated to Professor Dr. H. J. Seifert on the occasion of his 60th birthday
The work was financially supported by the Ministry of National Education, grant No P/03/257/90-z. The authors wishes to express his thanks to all who contributed to this support.
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Stock, L. Explosive thermal dehydration of solids. Journal of Thermal Analysis 37, 1415–1429 (1991). https://doi.org/10.1007/BF01913478
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DOI: https://doi.org/10.1007/BF01913478