Summary
Hot drawing of high molecular weight polyethylene (\(\left( {\bar M_w = 1.5 \times 10^6 } \right)\)) was studied. It was found that solutioncast films exhibited a drastically increased drawability in comparison with melt-crystallized material. This phenomenon, which enabled the production of polyethylene structures with a Young's modulus of 108 GPa and a strength of 3.0 GPa, is discussed in terms of a reduced number of entanglements in solution-crystallized material related to melt-crystallized films.
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References
Capaccio, G., T. A. Crompton, I. M. Ward, Polymer17, 644 (1976).
Warner, S. B., J. Polym. Sci. Phys. Ed.16, 2139 (1978).
Zachariades, A. E., M. P. C. Watts, T. Kanamoto, R. S. Porter, J. Polym. Sci. Letters. Ed.17, 485 (1979).
Smith, P., P. J. Lemstra, B. Kalb, A. Pennings, J. Polym. Bull.1, 733 (1979).
Smith, P., P. J. Lemstra, J. Mater. Sci.15, 505 (1980).
Smith, P., P. J. Lemstra, Makromol. Chem.180, 2983 (1979).
Capaccio, G., I. M. Ward, Polymer16, 239 (1975).
Vincent, P. I., in: Encyclopedia of Polymer Science and Technology vol. 7, 352, John Wiley, Inc., (New York 1967).
Treloar, L. R. G., The Physics of Rubber Elasticity, 3rd ed., Clarendon Press (Oxford 1975).
Barham, P. J., A. Keller, J. Mater. Sci.11, 27 (1976).
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Smith, P., Lemstra, P.J. Ultra-drawing of high molecular weight polyethylene cast from solution. Colloid & Polymer Sci 258, 891–894 (1980). https://doi.org/10.1007/BF01566246
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DOI: https://doi.org/10.1007/BF01566246