Abstract
The counterion binding behaviour of micelles of sodium dodecyl sulphate (SDS) and several bile salts in the pure state have been studied, as well as in mutually mixed states, and in a mixed state with polyoxyethylene sorbitan monolaurate (PSML) as a nonionic surfactant. Electrochemical measurements have shown no counterion binding by the pure bile salt micelles and their mixtures with PSML; they can bind counterions when mixed with SDS, whereas the surfactant anions of SDS micelles bind counterions in the pure state and/or in mixed states with PSML. In the SDS-PSML and SDS-bile salts combinations, the counterion association is decreased by the increased proportions of the second component. The extent of counterion binding by the different systems is presented.
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References
Yamauchi A, Kunisaki T, Minematsu T, Tomokiyo Y, Yamaguchi T, Kimizuka H (1978) Bull Chem Soc Jpn 51:2791
Kale KM, Cussler EL, Evans DF (1980) J Phys Chem 84:593
Kale KM, Cussler EL, Evans DF (1983) J Solution Chem 11:581
Rajagopalan N, Vadnere M, Lindenbaum S (1981) J Solution Chem 10:785
Ryu K, Lowery JM, Evans DF, Cussler EL (1983) J Phys Chem 87:5015
Cutler SG, Meares P, Hall DG (1978) J Chem Soc Faraday Trans 174:1758
Hall DG, Price TJ (1984) J Chem Soc Faraday Trans 180:1193
Shedlovsky L, Jacob CW, Epstein MB (1963) J Phys Chem 67:2075
Satake I, Tahara T, Matuura R (1969) Bull Chem Soc Jpn 42:319
Sasaki T, Hattori M, Sasaki J, Nukina K (1975) Bull Chem Soc Jpn 48:1397
Nishikido N (1983) J Colloid Interface Sci 92:588
Ogino K, Tsubaki N, Abe M (1984) J Colloid Interface Sci 98:78
Abe M, Tsubaki N, Ogino K (1984) Colloid Polym Sci 262:584
Bandyopadhyay A, Moulik SP (1987) Ind J Bichem Biophys, in press
Moulik SP, Ray S, Das AR (1977) J Phys Chem 81:1766
Botré C, Crescenzi VL, Mele K (1959) J Phys Chem 63:650
Mandal AB, Moulik SP (1982) In: Mittal KL, Fendler EJ (eds) Solution behaviour of surfactants: Theoretical and applied aspects, Vol 1, Plenum Press, New York, p 521
Small DM (1971) In: Nair PP, Kritchevsky D (eds) The Bile Acids: Chemistry, Vol 1, Plenum Press, New York, Ch 8
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Bandyopadhyay, A., Moulik, S.P. Counterion binding behaviour of micelles of sodium dodecyl sulphate and bile salts in the pure state, in mutually mixed states and mixed with a nonionic surfactant. Colloid & Polymer Sci 266, 455–461 (1988). https://doi.org/10.1007/BF01457263
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DOI: https://doi.org/10.1007/BF01457263