Conclusions
-
1.
The basic principles governing the cyclocodimerization of norbornene with allyl compounds have been elucidated for their reaction in the presence of a three-component catalyst system, Ni(acac)2-P(OR)3-AlR′3 (or MgR″2); a highly selective method has also been developed for the introduction of a methylenecyclobutane fragment to a norbornene hydrocarbon derivative.
-
2.
A new Ni complex has been prepared; it appears to be the catalyst which is active for the cyclocodimerization of norbornene with allylic compounds.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
Literature cited
M. Catellani, G. P. Chiusoli, E. Dradi, and G. Salerno, J. Organometal. Chem.,177, 29 (1979).
U. M. Dzhemilev, R. I. Khusnutdinov, D. K. Galeev, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim., 910 (1979).
C. A. Tolman, W. C. Seidel, and L. W. Gosser, J. Am. Chem. Soc.,96, 53 (1974).
C. J. Rix and J. G. Verkade, Coord. Chem. Revs.,16, (1–2), 129 (1975).
G. A. Tolstikov, N. R. Popod'ko, A. A. Pozdeeva, R. I. Khusnutdinov, S. I. Zhdanov, D. K. Galeev, and U. M. Dzhemilev, Izv. Akad. Nauk SSSR, Ser. Khim., 1293 (1984).
F. M. Dayrit and Z. Schwartz, J. Am. Chem. Soc.,103, 4466 (1981).
C. A. Tolman, J. Am. Chem. Soc.,96, 2780 (1974).
G. P. Chiusoli, E. Dradi, G. Salerno, and G. Campari, Bull. Soc. Chim. Belg.,89 (10), 869 (1980).
J. Kiji, S. Yoshijawa, E. Sasakawa, S. Nishimura, and J. Furukawa, J. Organometal. Chem.,80, 267 (1974).
J. A. Jensen, B. Nygaard, G. Elisson, and P. U. Nielsen, Acata Chem. Scand.,19(3), 768 (1965).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 138–148, January, 1987.
Rights and permissions
About this article
Cite this article
Dzhemilev, U.M., Khusnutdinov, R.I., Galeev, D.K. et al. Nickel complex-catalyzed codimerization of allyl esters with compounds in the norbornene series. Russ Chem Bull 36, 122–131 (1987). https://doi.org/10.1007/BF00953861
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00953861