Conclusions
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1.
The initial heat of krypton adsorption on zeolite NaX is 15.3 kJ/mole.
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2.
The partial molar enthalpy of the adsorbate under isosteric conditions increases with increase in the temperature.
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3.
The partial molar isosteric heat capacity of the adsorbate is independent of the temperature at small adsorption values, and increases with temperature at high adsorption values.
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Literature cited
L I. Seliverstova, A. A. Fomkin, and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, No. 1.
A. A. Fomkin and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2108.
B. P. Bering, V. V. Serpinskii, and A. A. Fomkin, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2111.
V. A. Rabinovich, A. A. Vasserman, V. I. Nedostup, and L. S. Veksler, Heat Physical Properties of Neon, Argon, Krypton, and Xenon [in Russian], Izd. Standartov, Moscow (1976), p. 474.
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Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2816–2819, December, 1977.
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Bering, B.P., Seliverstova, I.I., Serpinskii, V.V. et al. Thermodynamic ratios in adsorption system: Krypton-zeolite NaX. Russ Chem Bull 26, 2606–2609 (1977). https://doi.org/10.1007/BF00924583
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DOI: https://doi.org/10.1007/BF00924583