Abstract
The selectivity dependence of multiphoton dissociation of CF3I on the conditions of excitation (pulse duration, concentration of the isotope under excitation and gas pressure) has been studied. It has been shown that the main mechanism of selectivity loss isV-V exchange during a laser pulse. The elaborated model is in good agreement with the experiment.
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Bagratashvili, V.N., Doljikov, V.S., Letokhov, V.S. et al. Isotopic selectivity of IR laser photodissociation of CF3I molecules. Appl. Phys. 20, 231–235 (1979). https://doi.org/10.1007/BF00886023
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DOI: https://doi.org/10.1007/BF00886023