Abstract
Fourier transform IR spectroscopy of CO and N2, adsorbed at liquid nitrogen temperature, was used to characterize an MFI-type H-FeZSM-5 ferrisilicate which was synthesized with a Si/Fe ratio of 50. Thermal treatment of this material at 773 and 973 K was performed in order to follow formation of extraframework species. On samples fired at 773 K Brønsted acid sites were present which gave an O-H stretching band at 3630 cm−1. These hydroxyl groups formed adducts with both probe molecules, which were monitored by the corresponding bathochromic shift, Δν. Corresponding values for adsorbed CO and N2 were Δν = −270 and Δν = − 100, respectively. Increasing the firing temperature up to 973 K led to complete removal of iron from the zeolite framework, and consequent disappearance of Brønsted acidity. In this process, extraframework iron oxide species were formed which were also characterized by IR spectroscopy of the adsorbed probe molecules. Both CO and N2 gave Lewis-type adducts with coordinatively unsaturated Fe3+ ions present in the extraframework material. A comparison is made with results of a previous study on the H-GaZSM-5 isomorph.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
W. Hölderich, M. Hesse and F. Näumann, Angew. Chem. Int. Ed. Engl. 27 (1988) 226.
P.B. Venuto, Microporous Mater. 2 (1994) 297.
R. Szostak and T.L. Thomas, J. Chem. Soc. Chem. Commun. (1986) 113.
P. Ratnasamy, A.N. Kothastane, V.P. Shiralkar, A. Thangaraj and S. Ganapathy, in:Zeolite Synthesis, ACS Monograph No. 398, eds. M.L. Occelli and H.E. Robson (Am. Chem. Soc. Washington, 1989) p. 405.
C.V.A. Duke, K. Latham and C.D. Williams, Zeolites 15 (1995) 213.
A.J. Chandwadkar, R.N. Bhat and P. Ratnasamy, Zeolites 11 (1991) 42.
L. Marosi, J. Stabenow and M. Schwarzmann, German Patent Appl. 2831611 (1980).
R. Szostak and T.L. Thomas, J. Catal. 100 (1986) 555.
R. Szostak, V. Nair and T.L. Thomas, J. Chem. Soc. Faraday Trans. I 83 (1987) 487.
G. Doppler, R. Lehnert, L. Marosi and A.X. Trautwein, Stud. Surf. Sci. Catal. 37 (1988) 215.
A. Meagher, V. Nair and R. Szostak, Zeolites 8 (1988) 3.
G.P. Handreck and T.D. Smith, J. Chem. Soc. Faraday Trans. I 85 (1989) 3195.
J.G. Ulan, R. Gronsky and R. Szostak, Zeolites 11 (1991) 466.
R. Szostak,Molecular Sieves (Van Nostrand Reinhold, New York, 1989).
P. Ratnasamy and R. Kumar, Catal. Today 9 (1991) 328.
P. Ratnasamy and R. Kumar, Catal. Lett. 22 (1993) 227.
A. Bruckner, R. Lück, W. Wieker, B. Fahlke and H. Mehner, Zeolites 12 (1992) 380.
J. Patarin, H. Kessler and J.L. Guth, Zeolites 10 (1990) 674.
D.M. Bibby and M.P. Dale, Nature 317 (1985) 157.
Q. Huo, S. Feng and R. Xu, J. Chem. Soc. Chem. Commun. (1988) 1486.
A. Hagen, F. Roessner, I. Weingart and B. Spliethoff, Zeolites 15 (1995) 270.
D.H. Lin, G. Coudurier and J.C. Vedrine, Stud. Surf. Sci. Catal. 49 (1989) 1431.
G. Vorbeck, M. Richter, R. Fricke, B. Parlitz, E. Screier, K. Szulmewsky and B. Zibrowius, Stud. Surf. Sci. Catal. 65 (1991) 631.
J. Cejka, B. Wichterlova, J. Krtil, M. Krivanek and R. Fricke, Stud. Surf. Sci. Catal. 69 (1991) 347.
G.I. Panov, O.A. Sheveleva, A.S. Kharitonov, V.N. Romannikov and L.A. Vostrikova, Appl. Catal. A 82 (1992) 31.
J. Ho Kim, S. Namba and T. Yashima, Appl. Catal. A 83 (1993) 51.
V.I. Sobolev, G.I. Panov, A.S. Kharitonov, V.N. Romannikov, A.M. Volodin and K.G. Ione, J. Catal. 139 (1993) 435.
V.I. Sobolev, A.S. Kharitonov, O.V. Panna and G.I. Panov, Stud. Surf. Sci. Catal. 98 (1995) 159.
R. Szostak, V. Nair, D.K. Simmons, T.L. Thomas, R. Kuvadia, B. Dunson and D.C. Shieh, Stud. Surf. Sci. Catal. 37 (1988) 403.
K. Yogo, S. Tanaka, T. Ono, T. Mikami and E. Kikuchi, Microporous Mater. 3 (1994) 39.
E. Kikuchi, K. Yogo, S. Tanaka and M. Abe, Chem. Lett. (1991) 1063.
I. Inui, S. Iwamoto, S. Kojo and T. Yoshida, Catal. Lett. 13 (1992) 87.
C. Otero Areán, G. Turnes Palomino, F. Geobaldo and A. Zecchina, J. Phys. Chem. 100 (1996) 6678.
A. Zecchina and C. Otero Areán, Chem. Soc. Rev., in press.
F. Geobaldo, C. Lamberti, G. Ricchiardi, S. Bordiga, A. Zecchina, G. Turnes Palomino and C. Otero Areán, J. Phys. Chem. 99 (1995) 11167.
S. Bordiga, F. Geobaldo, C. Lamberti, A. Zecchina, F. Boscherini, F. Genoni, G. Leofanti, G. Petrini, M. Padovan, S. Geremia and G. Vlaic, Nucl. Instr. Meth. Phys. Res. B 97 (1995) 23.
S. Bordiga, R. Buzzoni, F. Geobaldo, C. Lamberti, E. Giamello, A. Zecchina, G. Leofanti, G. Petrini, G. Tozzola and G. Vlaic, J. Catal. 158 (1996) 486.
M. Tamarasso, B. Perego and B. Notari, US Patent 4410501 (1983).
W.M. Meier and D.H. Olson,Atlas of Zeolite Structure Types (Butterworths, London, 1987).
A. Zecchina, S. Bordiga, G. Spoto, L. Marchese, G. Petrini, G. Leofanti and M. Padovan, J. Phys. Chem. 96 (1992) 4991.
A. Zecchina, S. Bordiga, G. Spoto, D. Scarano, G. Petrini, G. Leofanti, M. Padovan and C. Otero Areán, J. Chem. Soc. Faraday Trans. 88 (1992) 2959.
P.A. Jacobs and R. von Ballmoos, J. Phys. Chem. 86 (1982) 3050.
M.B. Sayed, R.A. Kydd and R.P. Cooney, J. Catal. 88 (1984) 137.
G. Qin, L. Zheng, Y. Xie and C. Wu, J. Catal. 95 (1985) 609.
L.M. Kustov, V.B. Kazansky, S. Beran, L. Kubelková and P. Jiru, J. Phys. Chem. 91 (1987) 5247.
J. Datka, M. Bozcar and P. Rymarowicz, J. Catal. 114 (1988) 368.
J. Dwyer, Stud. Surf. Sci. Catal. 37 (1988) 333.
R. Borade, A. Sayari, A. Adnot and S. Kaliaguine, J. Phys. Chem. 94 (1990) 5989.
C.T.W. Chu and C.D. Chang, J. Phys. Chem. 89 (1985) 1569.
J. Datka and T. Abramowicz, J. Chem. Soc. Faraday Trans. 90 (1994) 2417.
I. Mirsojew, S. Ernst, J. Weitkamp and H. Knözinger, Catal. Lett. 24 (1994) 235.
A.Yu. Khodakov, L.M. Kustov, T.N. Bondarenko, A.A. Dergachev, V.B. Kazansky, Kh.M. Minachev, G. Borbély and H.K. Beyer, Zeolites 10 (1990) 603.
D.J. Parrillo, C. Lee, R.J. Gorte, D. White and W.E. Farneth, J. Phys. Chem. 99 (1995) 8745.
G.C. Pimentel and A.L. McClellan,The Hydrogen Bond (Freeman, San Francisco, 1960) ch. 3.
F. Wakabayashi, J.N. Kondo, K. Domen and C. Hirose, J. Phys. Chem. 99 (1995) 10573; J. Phys. Chem. 100 (1996) 4154.
K.M. Neyman, P. Strodel, S.Ph. Ruzankin, N. Schiensog, H. Knözingerand N. Rösch, Catal. Lett. 31 (1995) 273.
M.A. Makarova, K.M. Al-Ghefaili and J. Dwyer, J. Chem. Soc. Faraday Trans. 90 (1994) 383.
H. Berndt, A. Martin, H. Kosslick and B. Lücke, Microporous Mater. 2 (1994) 197.
M.S. Stave and J.B. Nicholas, J. Phys. Chem. 99 (1995) 15046.
S. Bordiga, D. Scarano, G. Spoto, A. Zecchina, C. Lamberti and C. Otero Areán, Vib. Spectrosc. 5 (1993) 69.
S. Bordiga, C. Lamberti, F. Geobaldo, A. Zecchina, G. Turnes Palomino and C. Otero Areán, Langmuir 11 (1995) 527.
A. Zecchina, D. Scarano and A. Relier, J. Chem. Soc. Faraday Trans. I 84 (1988) 2327.
A. Raj and S. Sivasanker, J. Catal. 147 (1994) 207.
E. Guglielminotti, J. Phys. Chem. 98 (1994) 4884.
S. Bordiga, E. Escalona Platero, C. Otero Areán, C. Lamberti and A. Zecchina, J. Catal. 137 (1992) 179.
G. Ghiotti, E. Garrone, C. Morterra and F. Boccuzzi, J. Phys. Chem. 83 (1979) 2863.
H. Böse and H. Förster, J. Mol. Struct. 218 (1990) 393.
L. Koubi, M. Blain, E. Cohen de Lara and J.M. Leclerq, Chem. Phys. Lett. 217 (1994) 544.
D.M. Bishop and S.M. Cybulski, Chem. Phys. Lett. 230 (1994) 177.
D.W. Lewis, C.R.A. Catlow, G. Sankar and S.W. Carr, J. Phys. Chem. 99 (1995) 2377.
D.W. Lewis, G. Sankar, C.R.A. Catlow, S.W. Carr and J.M. Thomas, Nucl. Instr. Meth. Phys. Res. B 97 (1995) 44.
R.G. Bell, D.W. Lewis and C.R.A. Catlow, Stud. Surf. Sci. Catal. 98 (1994) 234.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zecchina, A., Geobaldo, F., Lamberti, C. et al. Infrared studies of the interaction of carbon monoxide and dinitrogen with ferrisilicate MFI-type zeolites. Catal Lett 42, 25–33 (1996). https://doi.org/10.1007/BF00814463
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00814463