Abstract
X-ray structural results have been reviewed for the related Mz+ L −z -B15C5 complexes where Mz+=Li+ to Cs+ and Mg2+ to Ba2+, L−=2,4,6-trinitrophenolate (Picrate or Pic) and 3,5-dinitrobenzoate (Dnb), and B15C5=benzo-15-crown-5. These results combined with those for come MXz-B15C5 (X=NCS−, I−, NO −3 , ClO −4 , BPh −4 ) complexes have revealed that B15C5 is a useful macrocycle with regard to the ‘within-the-group’ and ‘between-the-groups’ discriminations of Mz+ in the solid state.
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References
C. J.Pedersen:J. Am. Chem. Soc. 89, 7017 (1967).
D. Bright and M. R. Truter:Nature (London) 225, 176 (1970);J. Chem. Soc. B,1544 (1970).
M. A. Bush and M. R. Truter: J. Chem. Soc. B, 1440 (1971).
M. A. Bush and M. R. Truter:J. Chem. Soc., Perkin Trans. 2, 341 (1972).
P. R. Mallinson and M. R. Truter:J. Chem. Soc., Perkin Trans. 2, 1818 (1972).
M. A. Bush and M. R. Truter:J. Chem. Soc., Perkin Trans. 2, 345 (1972).
N. S. Poonia and A. V. Bajaj:Chem. Rev. 79, 389 (1979).
N. S. Poonia and M. R. Truter:J. Chem. Soc. Dalton Trans., 2062 (1973).
N. S. Poonia:J. Am. Chem. Soc. 96, 1012 (1974).
N. S. Poonia:J. Inorg. Nucl. Chem. 37, 1855 (19750.
D. E. Fenton, M. Mercer, and M. R. Truter:Biochem. Biophys. Res. Commun. 48, 10 (1972).
M. Mercer and M. R. Truter:J. Chem. Soc., Dalton Trans. 2215 (1973).
D. E. Fenton, M. Mercer, N. S. Poonia and M. R. Truter:J. Chem. Soc. Chem. Commun., 66 (1972).
M. N. Hughes:The Inorganic Chemistry of Biological Processes, Chap. 9. Wiley, New York, 2nd edn. (1981).
P. J. Quinn:The Molecular Biology of Cell Membrane, Chap. 4 Macmillan, London (1976).
N. S. Poonia: inProgress in Macrocyclic Chemistry, Vol. 1, Chap. 3 (eds. R. M. Izatt and J. J. Christensen), Wiley-Interscience, New York (1979).
V. W. Bhagwat, H. Manohar, and N. S. Poonia:Inorg. Nucl. Chem. Lett. 16, 373 (1980).
D. L. Ward, A. I. Popov, and N. S. Poonia:Acta Crystallogr. C40, 238 (1984).
V. W. Bhagwat, H. Manohar, and N. S. Poonia:Inorg. Nucl. Chem. Lett. 17, 207 (1981).
K. Venkatasubramanian, N. S. Poonia, and W. H. Watson: Work in progress.
N. S. Poonia, A. V. Bajaj, K. Venkatasubramanian, W. Montfort, S. R. Ernst, and M. L. Hackert: Communicated.
C. J. Pedersen and H. K. Frensdorff:Angew. Chem., Int. Ed. Engl. 11, 16 (1972).
J. A. Kanters, K. Venkatasubramanian, and N. S. Poonia: Communicated.
D. G. Parsons, M. R. Truter, and J. N. Wingfield:Inorg. Chim. Acta 14, 45 (1975).
D. G. Parsons and J. N. Wingfield:Inorg. Chim. Acta 17, L25 (1976).
M. Van Meerssche: 1983, Personal communication.
P. R. Mallinson:J. Chem. Soc., Perkin Trans. 2, 261 (1975).
N. S. Poonia:J. Sci. Ind. Res. 36, 268 (1977).
N. S. Poonia, A. V. Bajaj, A. K. Arora, K. Joshi, and A. Banthia:Indian J. Chem.,A 19, 37 (1980).
V. W. Bhagwat, H. Manohar, and N. S. Poonia:Inorg. Nucl. Chem. Lett. 16, 289 (1980).
K. Venkatasubramanian, N. S. Poonia, K. Clinger, S. R. Ernst, and M. L. Hackert:J. Incl. Phenom. 1, 319 (1984).
J. Feneau-Dupont, E. Arte, J. P. Declercq, G. Germain, and M. Van Meerssche:Acta Crystallogr.,B 35, 1217. (1979).
P. Groth:Acta Chem. Scand., Ser. A 35, 721 (1981).
C. Cambillau, G. Bram, J. Corset, and C. Riche:Can. J. Chem. 60, 2554 (1982).
J. D. Owen:J. Chem. Soc., Dalton Trans., 1066 (1980).
D. C. Moody and R. R. Ryan:Cryst. Struct. Commun. 8, 933 (1979).
K. Joshi: Ph. D. Thesis, University of Indore (1981).
J. Hasek, K. Huml, and D. Hlavata:Acta Crystallogr. B 35, 330 (1979).
J. D. Owen:J. Chem. Soc., Dalton Trans., 1418 (1978).
D. G. Parsons and J. N. Wingfield:Inorg. Chim. Acta 18, 263 (1976).
C. J. Pedersen:J. Am. Chem. Soc. 92, 386 (1970).
K. Venkatasubramanian, N. S. Poonia, and S. Chaudhuri: to be published.
W. X. Xu, K. Clinger, M. L. Hackert and N. S. Poonia:J. Incl. Phenom. 3, 163 (1985).
P. D. Cradwick and N. S. Poonia:Acta Crystallogr. B 33, 197 (1977).
D. L. Ward, A. I. Popov, and N. S. Poonia:Acta Crystalogr. C 40, 1183 (1984).
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Poonia, N.S., Bagdi, P. & Sidhu, K.S. Structural aspects of crown complexes with alkali and alkaline earth cations. Benzo-15-crown-5 as a discriminating macrocycle. Journal of Inclusion Phenomena 4, 43–54 (1986). https://doi.org/10.1007/BF00662080
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DOI: https://doi.org/10.1007/BF00662080