Abstract
Conductance data for lithium bis(trifluoromethanesulfone)imide, LiN(CF 3 SO 2 ) 2 , are reported for the solvents water, propylene carbonate, acetonitrile and methyl formate at 25°C. Limiting molar conductivitiesA 0, association constants K A , and triple ion formation constants K t are reported where applicable. These data are compared with literature data for the commonly studied lithium salts LiClO 4 and LiAsF 6 . Non-coulombic energy contributions to ion pair formation are evaluated and discussed in terms of ion-ion and ion-solvent interactions.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
K. M. Abraham and S. B. Brummer, inLithium Batteries, J. P. Gabano, ed., (Academic Press, New York, 1983) Chap. 14.
B. Scrosati,Second International Symposium on Polymer Electrolytes, Siena, 1989 (Elsevier, London, 1990).
G. H. Newman, R. W. Francis, L. H. Gaines, and B. M. L. Rao,J. Electrochem. Soc. 127, 2025 (1980).
V. R. Koch,J. Electrochem. Soc. 126, 181 (1979).
M. Armand, W. Gorecki, and R. Andréani, inSecond International Symposium on Polymer Electrolytes, Siena, 1989 (Elsevier, London, 1990), p. 91.
M. Alamgir, R. D. Moulton, and K. M. Abraham, inProc. Symp. Primary and Secondary Lithium Batteries, K. M. Abraham and M. Salomon, eds., (The Electrochemical Society, 1991) p. 131.
A. Weber,J. Electrochem. Soc. 138, 2586 (1991).
J. Barthel, H.-J. Gores, G. Schmeer, and R. Wachter,Topics in Current Chemistry, Vol. 111 (Springer-Verlag, Heidelberg, 1982) p. 33.
E. Plichta, M. Salomon, S. Slane, and M. Uchiyama,J. Solution Chem. 16, 225 (1987).
R. Fernandez-Prini and J.-C. Justice,Pure and Applied Chem. 56, 541 (1984).
R. M. Fuoss and K.-L. Hsia,Proc. Ntl. Acad. Sci. USA 57, 1550 (1967).
M. Salomon and M. Uchiyama,J. Solution Chem. 16, 21 (1987).
S. Boileau and P. Hemery,Electrochim. Acta 16, 701 (1971).
A. D'Aprano,J. Phys. Chem. 75, 3290 (1971).
J. Barthel, R. Wachter, and H.-J. Gores, inModern Aspects of Electrochemistry, Vol. 13, B. E. Conway and J. O'M. Bockris, eds., (Plenum, New York, 1979).
J. Barthel, L. Iberl, R. Rossmaier, H.-J. Gores, and B. Kaukal,J. Solution Chem. 19, 321 (1990).
G. Atkinson and C. J. Hallada,J. Phys. Chem. 64, 1487 (1960).
M. Salomon and E. Plichta,Electrochim. Acta 28, 1681 (1983).
H. P. Hopkins, D. V. Jahagirdar, and A. B. Norman,J. Solution Chem. 8, 147 (1979).
J. Barthel, R. Wachter, and H.-J. Gores,J. Chem. Soc. Faraday Disc. 64, 285 (1978).
Tables of Interatomic Distances, Special Publication No. 11 (The Chemical Society, London, 1958).
R. A. Robinson and R. H. Stokes,Electrolyte Solutions (Butterworths, London, 1955).
M. Salomon,J. Solution Chem. 19, 1225 (1990).
C. H. Springer, J. F. Coetzee, and R. L. Kay,J. Phys. Chem. 73, 471 (1969).
A. D'Aprano, M. Goffredi, and R. Triolo,J. Chem. Soc. Faraday Trans. I 71, 1188 (1975).
E. Plichta, S. Slane, M. Uchiyama, M. Salomon, D. Chua, W. B. Ebner, and H. W. Lin,J. Electrochem. Soc. 136, 1865 (1989).
M. S. Greenberg and A. I. Popov,J. Solution Chem. 5, 653 (1973).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Salomon, M. Conductance of solutions of lithium bis(trifluoromethanesulfone)imide in water, propylene carbonate, acetonitrile and methyl formate at 25°C. J Solution Chem 22, 715–725 (1993). https://doi.org/10.1007/BF00647411
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00647411