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It should be noted that coordination by N1 can occur only when deprotonation has occurred, as in benzimidazole complexes [M. G. B. Drew, D. H. Templeton and A. Zalkin,Inorg. Chem., 7, 2618 (1968)] and in the benzotriazolato anion, [L. D. Brown, J. A. Ibers and A. R. Siedle,Inorg. Chem., 17, 3026 (1978)].
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Reedijk, J. The donor site in indazole and other azoles. Transition Met Chem 4, 335 (1979). https://doi.org/10.1007/BF00618331
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DOI: https://doi.org/10.1007/BF00618331