Abstract
It has been suggested that several hypothetical hydrocarbons with conjugate π-electron systems will show ferromagnetic spin alinement due to the topological nature of the MO's. Some qualitative discussions have been given for the mechanism of the realization of this “ferromagnetic state”.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Heisenberg, W.: Z. Physik 38, 411 (1926); 49, 619 (1928).
Bloch, F.: Z. Physik 57, 545 (1929).
Murray, R. W., A. M. Trozzolo, E. Wasserman, and W. A. Yager: J. Amer. chem. Soc. 84, 3213 (1962).
Brandon, R. W., G. L. Cless, and C. A. Hutchison, Jr.: J. chem. Physics 37, 1878 (1962).
Wasserman, E., A. M. Trozzolo, W. A. Yager, and R. W. Murray: J. chem. Physics 40, 2408 (1964).
—, L. C. Snyder, and W. A. Yager: J. chem. Physics 41, 1763 (1964).
Brandon, R. W., G. L. Closs, C. E. Davoust, C. A. Hutchison, Jr., B. E. Kohler, and R. Silbey: J. chem. Physics 43, 2006 (1965).
Moritani, I., S. Murahashi, M. Nishino, Y. Yamamoto, K. Itoh, and N. Mataga: J. Amer. chem. Soc. 89, 1259 (1967).
Itoh, K.: Chem. Physics Letters 1, 235 (1967).
Wasserman, E., R. W. Murray, W. A. Yager, A. M. Trozzolo, and G. Smolisky: J. Amer. chem. Soc. 89, 5076 (1967).
Gibbons, W. A., and A. M. Trozzolo: J. Amer. chem. Soc. 88, 172 (1966).
Closs, G. L., C. A. Hutchison, Jr., and B. Kohler: J. chem. Physics 44, 413 (1966).
Moritani, I., S. Murahashi, N. Nishino, K. Kimura, and H. Tsubomura: Tetrahedron Letters 1966, 373.
Itoh, K., H. Konishi, and N. Mataga: Optical absorption and luminescence spectra of a ground state quintet hydrocarbon molecule, to be published in J. chem. Physics.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mataga, N. Possible “ferromagnetic states” of some hypothetical hydrocarbons. Theoret. Chim. Acta 10, 372–376 (1968). https://doi.org/10.1007/BF00526505
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00526505