Abstract
The behavior of Hg in the soil is mainly controlled by adsorption and desorption processes depending on complexation, the most important ligands in solution being OH−, Cl−, and organic anions. Since the solubility of HgCl2 and Hg(OH)2 is rather high, the affinity of Hg to these ligands leads to an increased mobility. This is especially true for HgCl2, whereas the hydrolysis of Hg2+ may result in the specific adsorption of Hg on mineral colloids. The high affinity of Hg to S explains the strong binding of Hg to soil organic matter and also the stability of HgS. Further precipitation products than HgS are unlikely to occur, since the activity of Hg2+ remains too low to exceed the solubility product of any other defined Hg compound. It is mainly the physical fractioning of soil organic matter (dissolved vs adsorbed) that determines the behavior and distribution of Hg in soils.
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References
Andersson, A.: 1979, ‘Mercury in soils’, in O. Nriagu (ed.), The Biogeochemistry of Mercury in the Environment. Elsevier, North-Holland Biomedical Press, Amsterdam, The Netherlands, pp. 79–112.
Aomine, S. and Inoue, K.: 1967, Soil Sci. Plant Nutr. 13, 129.
Aomine, S., Kawasaki, H. and Inoue, K.: 1967, Soil Sci. Plant Nutr. 13, 186.
Behra, P.: 1986, ‘Migration or retention of mercury II salts when percolating through a porous medium constituted of a natural quarz sand?’, in Environmental Contamination, 2nd Int. Conf. Amsterdam, Sept. 1986, pp. 318–320.
Bourg, A.C.M.: 1988, ‘Metals in aquatic and terrestrial systems: sorption, speciation and mobilisation’, in W. Salomons and U. Förstner (eds.), Environmental impact and management of mine tailings and dredged materials, Springer Verlag, pp. 3–32.
Bourg, A.C.M. and Schindler, P.W.: 1985, ‘Control of trace metals in natural aquatic systems by the adsorptive properties of organic matter’ in T.D. Lekkas (ed.), Proc. 5th Int. Conf. Heavy Metals in the Environment, Athens (GR), Sept. 1985, pp. 97–99.
Brümmer, G.W.: 1986, ‘Heavy metal species, mobility and availability in soils’, in M. Berhard, F.E. Brinckman and P.J. Sadler (eds.), The Importance of Chemical “Speciation” in Environmental Processes, pp. 169–192.
Cappon, C.J.: 1987, Water, Air and Soil Pollut. 34, 353.
Cranston, R.E. and Buckley, D.E.: 1972, Environm. Science Technol. 6, 274.
Dudas, M.J. and Pawluk, S.: 1976, Can. J. Soil Sci. 56, 413.
Elliott, H.A., Huang, C.P.: 1979, Environ. Internat. 2, 145.
Fang, S.C.: 1978, Environ. Sci. Technol. 12, 285.
Farrah, H. and Pickering, W.F.: 1978, Water, Air, Soil Pollut. 9, 23.
Feick, G., Horne, R.A. and Yeaple, D.: 1972, Science 175, 1142.
Forbes, E.A., Posner, A.M. and Quirk, J.P.: 1974, J. Coll. Interf. Sci. 49, 403.
Frimmel, F.: 1976, Z. Wasser Abwasser Forsch. 6, 170.
Frimmel, F.H., Sattler, D. and Quentin, K.E.: 1980, Vom Wasser 55, 111.
Frimmel, F.H., Geywitz, J. and Velikov, B.L.: 1983, Vom Wasser 61, 17.
Gilmour, J.T.: 1971, Envir. Lett. 2, 143.
Gotoh, S. and Koga, H.: 1977, Plant and Soil 47, 49.
Gracey, H.I. and Stewart, J.W.B.: 1974, ‘The fate of applied mercury in soil’, in J. Tomlinson (ed.) Proc. Int. Conf. on Land for Waste Management, Oct. 1973. Agric. Inst. of Canada, Ottawa, Ontario, pp. 97–103.
Hahne, H.C.H. and Kroontje, W.: 1973a, J. Environ. Qual. 2, 444.
Hahne, H.C.H. and Kroontje, W.: 1973b, Proc. Soil Sci. Soc. Amer. 37, 838.
Harsh, J.B. and Doner, H.E.: 1981, J. Environ. Qual. 10, 333.
Hogg, T.J., Stewart, J.W. and Bettany, J.R.: 1978, J. Environ. Qual. 7, 440.
Inoue, K. and Aomine, S.: 1969, Soil Sci. Plant Nutr. 15, 86–91.
Käferstein, et al: 1979, Blei, Cadmium und Quecksilber in und auf Lebensmitteln, ZEBS-Berichte 1/1979, Schriftenreihe des des BGA, Reimer-Verlag, Berlin.
Kerndorff, H. and Schnitzer, M.: 1980, Geochim. Cosmochim. Acta 44, 1701.
Kinniburgh, D.G. and Jackson, M.L.: 1978, Soil Sci. Soc. Am. J. 42, 45.
Kloke, A.: 1985, Garten und Umwelt 37, 1.
Landa, E.R.: 1978, Geochim. Cosmochim. Acta 42, 1407.
Leckie, J.O.: 1986, ‘Adsorption and transformation of trace element species at sediment/water interfaces’ in M. Berhard, F.E. Brinckman and P.J. Sadler (eds.), The Importance of Chemical “Speciation” in Environmental Processes. Springer-Verlag, pp. 237–254.
Lindberg, S.E., Andren, A.W. and Harriss, R.C.: 1975, ‘Geochemistry of mercury in the estuarine environment’, in E.L. Cronin (ed), Estuarine Research. Chemistry, Biology and the Estuarine System, Vol. I, Academic Press, New York, pp. 64–107.
Lindberg, S.E., Jackson, D.R., Huckabee, J.W., Janzen, S.A., Levin, M.J. and Lund, J.R.: 1979, J. Environ. Qual. 8, 572.
Lockwood, R.A. and Chen, K.Y.: 1973, Environm. Sci. Technol. 7, 1028.
McKeague, J.A. and Kloosterman, B.: 1974, Can. J. Soil Sci. 54, 503.
MacNaughton, M.G. and James, R.O.: 1974, J. Colloid Int. Sci. 47, 431.
Moraghan, J.T.: 1971, N. Dakota Farm Res. 4, 53.
Newton, D.W., Ellis, R.JR. and Paulsen, G.M.: 1976, J. Env. Qual. 5, 251.
Obukhovskaya, T.D. and Zyrin, N.G.: 1987, Moscow Univ. of Soil Science Bull. 42, 39.
Poelstra, P., Frissel, R.J., Van der Klugt, N. and Tap, W.: 1974, ‘Behavior of mercury compounds in soils: accumulation and evaporation’ in Comparative Studies of Food and Environmental Contamination. Proc. Series IAEA-SM-175/46, Vienna, pp. 281–292.
Ramamoorthy, S. and Rust, B.R.: 1976, Env. Geology 2, 165.
Randle, K. and Hartmann, E.H.: 1987, Geoderma 40, 281.
Reimers, R.S. and Krenkel, P.A.: 1974, ‘Sediment sorption phenomena’ in Mercury: Environmental Considerations, Part II. CRC Press Inc. Cleveland, Ohio, pp. 265–295.
Schindler, P.W. and Stumm, W.: 1988, ‘The surface chemistry of oxides, hydroxides and oxide minerals’, in W. Stumm (ed.), Aquatic Surface Chemistry. John Wiley & Sons, New York, pp. 83–110.
Schnitzer, M., Kerndorff, H.: 1981, Water Air Soil Pollut. 15, 97.
Semu, E., Singh, B.R. and Selmer-Olsen, A.R.: 1987, Water, Air, Soil Pollut. 32, 1.
Sillen, L.G. and Martell, A.G.: 1971, Stability constants of metal-ion complexes. Special Publication No 25. The Chem. Soc. London.
Stumm, W. and Morgan, J.J.: 1981, Aquatic Chemistry. John Wiley and Sons, New York.
Trost, P.B. and Bisque, R.E.: 1970, ‘Distribution of mercury in residual soils’, in R. Hartung & B.D. Dinman (eds.), Environmental Mercury Contamination. Ann Arbor Science Publ., pp. 178–196.
Vuceta, J.: 1976, Adsorption of Pb(II) and Cu(II) on α-quartz from aqueous solutions: influence of pH, ionic strength, and complexing ligands. Ph.D. Thesis, California Inst. of Technology.
Wollast, R., Billen, G., Mackenzie, F.T.: 1975, ‘Behavior of mercury in natural systems and its global cycles’, in A.D. McIntyre and C.F. Mills (eds.), Ecological Toxicology Research: Effects of Heavy Metal and Organohalogen Compounds. Proceedings of a NATO Science Conference. London, N. Y. Plenum Press, pp. 145–166.
Zyrin, N.G. and Sadovnikova, L.K.: 1988, Moscow University Soil Science Bulletin 43, 25–30.
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Schuster, E. The behavior of mercury in the soil with special emphasis on complexation and adsorption processes - A review of the literature. Water, Air, and Soil Pollution 56, 667–680 (1991). https://doi.org/10.1007/BF00342308
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DOI: https://doi.org/10.1007/BF00342308