Abstract
The separation of monomeric acrylates was performed with High Performance Liquid Chromatography (HPLC) and Supercritical Fluid Chromatography (SFC). A direct on-line structural assignment of all compounds by continuous-flow 1HNMR spectroscopy is possible with both separation techniques. The direct SFC-NMR coupling offers the advantage that the recorded continuous-flow 1HNMR spectrum is not obscured by solvent signals.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Klosterboer JG (1988) Adv polymer science, Vol 84. Springer, Berlin, Heidelberg, New York
Bayer E, Albert K, Nieder M, Grom E, Keller T (1979) J Chromatogr 186:497–507
Bayer E, Albert K, Nieder M, Grom E, Zhu An (1980) Fresenius Z Anal Chem 304:111–116
Bayer E, Albert K, Nieder M, Grom E, Wolff G, Rindlisbacher M (1982) Anal Chem 54:1747–1750
Dorn HC (1984) Anal Chem 56:747A-758A
Laude DA Jr, Wilkins CL (1986) Trends Anal Chem 15:230–235
Albert K, Bayer E (1988) Trends Anal Chem 7:288–293
Albert K (1988) Habilitationsschrift. Tübingen University
Albert K, Kunst M, Bayer E, Spraul M, Bermal W (1989) J Chromatogr 463:355–363
Albert K, Kunst M, Bayer E, de Jong HJ, Genissel P, Spraul M, Bermel W (1989) Anal Chem 61:772–775
Albert K, Bayer E (1992) In: Patonay G. (ed.) HPLC detections newer methods. VCH Publishers, New York, pp. 197–229
Spraul M, Hoffmann M, Dvortsak P, Nicholson JK, Wilson ID (1993) Anal Chem 65:327–330
Hofmann M, Spraul M, Streck R, Wilson ID, Rapp A (1993) Labor Praxis 10:36–41
Albert K, Braumann U, Tseng LH, Nicholson G, Bayer E, Spraul M, Hofmann M, Dowle C, Chippendale M (1994) Anal Chem 66:3042–3046
Albert K, Braumann U (1994) Frontiers Anal Spectrosc (in press)
Streck R, Personal communication
Author information
Authors and Affiliations
Additional information
Dedicated to Professor Dr. H. Kriegsmann on the occasion of his 70th birthday
Rights and permissions
About this article
Cite this article
Albert, K., Braumann, U., Streck, R. et al. Application of direct on-line coupling of HPLC and SFC with 1HNMR spectroscopy for the investigation of monomeric acrylates. Fresenius J Anal Chem 352, 521–528 (1995). https://doi.org/10.1007/BF00323378
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00323378