Abstract
An on-line isotope dilution technique has been developed for use with a high performance liquid chromatography system (HPLC) coupled to an inductively coupled plasma mass spectrometer (ICP-MS). With this method it is possible to characterize elemental species at low concentration levels and to quantify them accurately. The possibilities of this method are shown using the examples of the determination of the interactions of different molecular weight fractions of dissolved organic matter (DOM) with copper and molybdenum in a natural water sample.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Heumann KG (1986) Fresenius Z Anal Chem 324:601
Riviello JM, Siriaks A, Manabe RM, Roehl R, Alforque M (1991) LC · GC Intl 4:25
McLaren JW, Siu KWM, Lam JW, Willie SN, Maxwell PS, Palepu A, Koether M, Berman SS (1990) Fresenius J Anal Chem 337:721
Mason AZ, Storms SD, Jenkins KD (1990) Anal Biochem 186:187
Hansen SH, Larsen EH, Pritzl G, Cornett C (1992) J Anal At Spectrom 7:629
Klinkenberg H, van der Wal S, Frusch J, Terwint L, Beeren T (1990) At Spectrosc 11:198
Al-Rashdan A, Heitkemper D, Caruso JA (1991) J Chromatogr Sci 29:98
Beauchemin D, Bednas ME, Berman SS, McLaren JW, Siu KWM, Sturgeon RE (1988) Anal Chem 60:2209
Beauchemin D, Siu KWM, McLaren JW, Berman SS (1989) J Anal At Spectrom 4:285
Crews HM, Dean JR, Ebdon L, Massey RC (1989) Analyst 114:895
Dean JR, Munro S, Ebdon L, Crews HM, Massey RC (1987) J Anal At Spectrom 2:607
Elder RC, Tepperman K, Tarver ML, Matz S, Jones WB, Hess EV (1990) J Liquid Chrom 13:1191
Salov VV, Yoshinaga J, Shibata Y, Morita M (1992) Anal Chem 64:2425
Suyani H, Creed J, Davidson T, Caruso J (1989) J Chromatogr Sci 27:139
Gercken B, Barnes RM (1991) Anal Chem 63:283
Heumann KG (1992) Mass Spectrom Rev 11:41
Heumann KG (1992) Int J Mass Spectrom Ion Processes 118/119:575
Heumann KG (1988) In: Adams F, Gijbels R, van Grieken R (eds) Inorganic mass spectrometry. Wiley, New York, p 301
Buckley WT, Ihnat M (1993). Fresenius J Anal Chem 345:217
Toole J, McKay K, Baxter M (1991) Anal Chim Acta 245:83
Beauchemin D, McLaren JW, Mykytiuk AP, Berman SS (1987) Anal Chem 59:778
McLaren JW, Beauchemin D, Berman SS (1987) Anal Chem 59:610
Garbarino JR, Taylor HE (1987) Anal Chem 59:1568
Viczián M, Lásztity A, Wang X, Barnes RM (1990) J Anal At Spectrom 5:125
Abbt-Braun G, Frimmel FH, Schulten HR (1989) Water Res 23:1579
Warwick P, Hall T (1992) Analyst 117:151
Ohzeki K, Tatehana M, Nukatsuka I, Ishida R (1991) Analyst 116:199
Allain P, Janault L, Mauras Y, Mermet JJ, Delaporte T (1991) Anal Chem 63:1497
Savitzky A, Golay MJE (1964) Anal Chem 36:1627
Madden HH (1978) Anal Chem 50:1383
Oberste Baubehörde im Bayerischen Staatsministerium des Inneren (1991) Flüsse und Seen in Bayern, Wasserbeschaffenheit Gewässergüte, Heft 23 der Schriftenreihe Wasserwirtschaft in Bayern. Bartels & Wernitz, München
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rottmann, L., Heumann, K.G. Development of an on-line isotope dilution technique with HPLC/ICP-MS for the accurate determination of elemental species. Fresenius J Anal Chem 350, 221–227 (1994). https://doi.org/10.1007/BF00322473
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00322473