Abstract
Forest soil organic horizons from old and young plantations in the Alltcailleach Forest, N.E. Scotland were first sampled in 1949/50 and resampled in 1987. Copper, Pb and Zn in the soils were determined simultaneously on the original (stored) and the resampled soils. Overall mean Cu and Pb concentrations increased from 12.7 to 15.3 and 49.5 to 60.8 mg kg−1 between 1949/50 and 1987. Zinc concentrations decreased from 76.4 to 60.7 mg kg−1. Amounts of all 3 heavy metals increased because of increases in the thickness of organic horizons. Mean accumulation rates for Cu, Pb and Zn were 39.1, 186 and 114 g ha−1 yr−1, respectively. The rate of accumulation of Pb was significantly related to the rate of accumulation of organic matter. Copper and Zn concentrations were directly correlated with pH and inversely correlated with C/N ratio, whereas Pb was inversely correlated with pH and directly correlated with % C and C/N ratio. The more acidic soil organic horizons therefore contained higher concentrations of Pb and lower concentrations of Cu and Zn.
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References
Andersson, A. and Nilsson, K. O.: 1974, Ambio 3, 198.
Andresen, A. M., Johnson, A. H., and Siccama. T. G.: 1980, J. Environ. Qual. 9, 292.
Bartlett, R. and James, B.: 1980, Soil Sci. Soc. Am. J. 44, 721.
Bergkvist, B.: 1986, Water, Air, and Soil Pollut. 31, 901.
Bergkvist, B.: 1987a, Forest Ecol. and Manage. 22, 29.
Bergkvist, B.: 1987b, ‘Leaching of Metals in the Upper C Horizons of Spruce and Beech Forest Soils’, in S. E. Lindberg and T. C. Hutchinson (eds.), International Conference, Heavy Metals in the Environment. New Orleans, September 1987, CEP Consultants Ltd., Edinburgh, Vol. 2, pp. 479–481.
Bergkvist, B.: 1987c, Water, Air, and Soil Pollut. 33, 131.
Bergkvist, B. Folkeson, L., and Berggren, D.: 1989, Water, Air, and Soil Pollut. 47, 217.
Billett, M. F., FitzPatrick, E. A. F., and Cresser, M. S.: 1988, Soil Use and Manage. 4, 102.
Billett, M. F., Parker-Jerris, F., FitzPatrick, E. A. F., and Cresser, M. S.: 1990a, J. Soil Sci. 41, 133.
Billett, M. F., FitzPatrick, E. A. F., and Cresser, M. S.: 1990b, Environ. Pollut. 66, 67.
Cawse, P. A.: 1980, ‘Deposition of trace elements from the atmosphere in the UK’. in Inorganic Pollution and Agriculture. Her Majesty's Stationary Office, London, pp. 22–46.
Coughtrey, P. J., Jones, C. H., Martin, M. H., and Shales, S. W.: 1979, Oecologia 39, 51.
Cresser, M. S. and Parsons, J. W.: 1979, Anal. Chim. Acta 109, 431.
Flower, C. A.: 1987, ‘Atmospheric Inputs of Nutrients and Pollutants to Uplands in North-East Scotland’, Unpublished Ph.D. Thesis, University of Aberdeen.
Friedland, A. J., Johnson, A. H., and Siccama, T. G.: 1984, Water, Air, and Soil Pollut. 21, 161.
Gosz, J. R., Likens, G. E., and Bormann, F. H.: 1973, Ecol. Monogr. 43, 173.
Groet, S. S.: 1976, Oikos 27, 445.
Heinrichs, H. and Mayer, R.: 1980, J. Environ. Qual. 9, 111.
Johnson, A. H., Siccama, T. G., and Friedland, A. J.: 1982, J. Environ. Qual. 11, 577.
Jones, K. C., Watts, S. A., Hanson, A. F., and Dighton, V.: 1988, Environ. Pollut. 51, 31.
Martin, M. H., Duncan, E. M., and Coughtrey, P. J.: 1982, Environ. Pollut. B3, 147.
Meteorological Office.: 1952, ‘Climatological Atlas of Britain’, Her Majesty's Stationary Office, London.
Page, R. A., Cawse, P. A., and Baker, S. T.: 1988, Sci. Total Environ. 68, 71.
Ruhling, A. and Tyler, G.: 1973, Oikos 24, 402.
Ruhling, A. and Tyler, G.: 1984, Water, Air, and Soil Pollut. 22, 173.
Shuman, L. M.: 1980, Soil Sci. 130, 336.
Siccama, T. G., Smith, W. H., and Mader, D. L.: 1980, Environ. Sci. Technol. 14, 54.
Smith, W. H. and Siccama, T. G.: 1981, J. Environ. Qual. 10, 323.
Steinnes, E., Solberg, W., Petersen, H. M., and Wren, C. D.: 1989, Water, Air, and Soil Pollut. 45, 207.
Tinsley, J.: 1950, Transactions of the 4th International Meeting of the Society of Soil Science 1, 161.
Tyler, G.: 1975, Nature 255, 701.
Zoltai, S. C.: 1988, Water, Air, and Soil Pollut. 37, 217.
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Billett, M.F., Fitzpatrick, E.A. & Cresser, M.S. Long-term changes in the Cu, Pb, and Zn content of forest soil organic horizons from North-East Scotland. Water Air Soil Pollut 59, 179–191 (1991). https://doi.org/10.1007/BF00283180
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DOI: https://doi.org/10.1007/BF00283180