Abstract
Because of the importance of the absorption cross-sections of ozone in the atmosphere, we give a new set of data at ambient temperature for the whole spectral region within the 195–345 nm range. Two new methods have been investigated for the experiments to measure the ozone pressures. Our results are compared with all of the previous data. The agreement between the more recent works is relatively good and can be improved by making some corrections in the WMO set. The new reference value at 254 nm proposed by Mauersberger et al. is confirmed and we suggest taking it as a new standard.
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Bass A. M. and Paur R. J., 1984, The ultraviolet cross-sections of Ozone: I. Measurements in C. Zeferos and A. Ghazi (eds.), Proc. Quadrennial Ozone Symp., Halkidiki, Greece, D. Reidel, Dordrecht, pp. 606–616.
Cacciani M., Di Sarra A., Fiocco G., and Amoruso A. 1989, Absolute determination of the cross-sections of ozone in the wavelength region 339–355 nm at temperature 220–293K J. Geophys. Res. 94, 8485–8490.
DeMore W.B., and Patapoff M., 1976, Comparison of ozone determination by ultraviolet photometry and gas-phase titration, Environ. Sci. Technol. 10, 897.
Griggs M., 1968, Absorption coefficients of ozone in the ultraviolet and visible regions, J. Chem. Phys. 49, 857–859.
Hearn A. G., 1961, The absorption of ozone in the ultraviolet and visible regions of the spectrum, Proc. Phys. Soc. London 78, 932–940.
Inn E. C. Y., and Tanaka Y., 1953, Absorption coefficients of ozone in the ultraviolet and visible regions, J. Opt. Soc. Amer. 43, 870–873.
Malicet J., Brion J., and Daumont D., 1984, New values of ozone absolute cross-sections in the ultraviolet spectral range at 298 and 228 K, by a method based upon pressure measurements at constant volume, in C. Zerefos and A. Ghazi (eds.), Proc. Quadrennial Ozone Symp., Halkidiki, Greece, D. Reidel, Dordrecht, pp. 617–621.
Malicet J., Brion J., and Daumont D., 1989. Temperature dependence of the absorption cross-section of ozone at 254 nm, Chem. Phys. Lett. 158, 293.
Mauersberger K., Hanson D., and Morton J., 1985, A new ozone standard: the vapor pressure of ozone at liquid argon temperatures, Geophys. Res. Lett. 12, 89–92.
Mauersberger K., Hanson D., Barnes J., and Morton J., 1987, Ozone vapor pressure and absorption cross-section measurements: Introduction of an ozone standard, J. Geophys. Res. 92, 8480.
Molina L. T. and Molina M. J., 1986, Absolute absorption cross-sections of ozone in the 185–350 nm wavelength range. J. Geophys. Res. 91, 14501.
Nicolet M., Bucchia M., and Megie G., 1985, Atmospheric transmittance and photodissociation rates in the 185–240 nm spectral range: sensitivity of O2 absorption cross-sections in the Herzberg continuum and Schumann-Runge bands, Ann. Geophys. 3, 429.
Poulter K. F., Rodgers M. J., Nash P. J., Thomson T. J., and Perkin M. P., 1983, Thermal transpiration correction in capacitance manometers, Vacuum 33, 311.
Vigroux E., 1953, Contribution à l'étude expérimentale de l'absorption de l'ozone, Ann. Physique 8, 709.
Vigroux E., 1967, Determination des coefficients moyens d'absorption de l'ozone en vue des observations concernant l'ozone atmosphérique à l'aide due spectromètre Dobson, Ann. Phys. 2, 209.
Yoshino K., Freeman D. E., Esmond J. R., and Parkinson W. H., 1988, Absolute absorption cross-section measurements of ozone in the wavelength region 238–335 nm and the temperature dependence, Planet. Space Sci. 36, 395–398.
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Daumont, D., Brion, J., Charbonnier, J. et al. Ozone UV spectroscopy I: Absorption cross-sections at room temperature. J Atmos Chem 15, 145–155 (1992). https://doi.org/10.1007/BF00053756
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DOI: https://doi.org/10.1007/BF00053756