Abstract
Although, as Ovshinsky [1] has often noted, the history of civilization is intimately connected with advances in materials research (e.g., the Stone, Bronze, Iron, and Steel Ages), a quantitative theory of materials did not evolve until after the development of quantum mechanics in 1925. When Bloch [2] developed the quantum theory of solids in 1930, physicists were unduly influenced by the discovery less than 20 years previous that many solids were periodic arrays of atoms. By making use of the mathematical simplifications resulting from periodicity, Bloch was able to derive some general properties of the electronic states in crystals, from which Wilson [3] developed the band theory of electronic transport. There is no question that this theory has been very successful in providing a detailed understanding of the properties of crystalline solids, including the electrical and optical properties of a wide array of commercially important semiconductors and metals. However, it has long been known that many solids are not crystalline but are amorphous, and do not exhibit any long-range periodicity.
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References
S.R. Ovshinsky, J. de Phys. 42, C4–1095(1981).
F. Bloch, Z. Physik 52, 555(1928).
A.H. Wilson, Theory of Metals, Cambridge University Press, N.Y., 1936.
S.R. Ovshinsky, Phys. Rev. Lett. 21, 1450 (1968).
S.C. Moss and J.F. Graczyk, in Proceedings of the Tenth International Conference on the Physics of Semiconductors, edited by S.P. Keller, J.C. Hensel, and F. Stern, U.S. Atomic Energy Commission, Washington, D.C., 1970, p. 658.
W.H. Zachariasen, J. Am. Chem. Soc.54, 3841 (1932).
D.E. Polk, J. Noncryst. Solids 5, 365 (1971).
See, e.g., H. Koizumi and T. Ninomiya, J. Phys. Soc. Japan 44, 898 (1978).
G. Etherington, A.C. Wright, J.T. Wenzel, J.C. Dore, J.H. Clarke, and R.N. Sinclair, J. Noncryst. Solids 48, 265 (1982).
See, e.g., D. Beeman and B.L. Bobbs, Phys. Rev. B 12, 1399 (1975).
T. Takahashi, K. Ohno, and Y. Harada, Phys. Rev. B 21, 3399 (1980).
D. Adler, in Handbook on Semiconductors, edited by T.S. Moss, North-Holland, N.Y., 1982, volume 1, p. 805.
M.H. Brodsky and M. Cardona, J. Noncryst. Solids 31, 81(1978).
E.J. Yoffa and D. Adler, Phys. Rev. B 12, 2260 (1975).
See, e.g., O. Madelung, Introduction to Solid-State Theory, Springer-Verlag, Berlin, 1978.
B. Kramer, Phys. Stat. Sol .47b, 501 (1971).
L. van Hove, Phys. Rev.89, 1189 (1953).
D. Adler, Amorphous Semiconductors, CRC Press, Cleveland, 1971.
J.R. Reitz, Solid State Phys. 1, 1 (1955).
V. Heine, Solid State Phys. 35, 1 (1980).
J.C. Slater and K.H. Johnson, Phys. Rev. B 5, 844 (1972).
K.H. Johnson, H.J. Kolair, J.P. deNeufville and D.L. Morel, Phys. Rev. B 21, 643 (1980).
L. Ley, S. Kowalczyk, R. Poliak and D.A. Shirley, Phys. Rev. Lett 19, 1088 (1972).
D. Adler, Solar Energy Mats. 8, 53 (1982).
T.P. Eggarter and M.H. Cohen, Phys. Rev. Lett.25, 807 (1970).
C. M. Soukoulis and M.H. Cohen, J. Noncryst. Solids 66, 279(1984).
F.R. Shapiro and D. Adler, J. Noncryst. Solids 66, 303 (1984).
N.F. Mott, Adv. Phys.16, 49 (1976).
M.H. Cohen, H. Fritzsche and S.R. Ovshinsky, Phys. Rev. Lett.22, 1065 (1969).
T. Holstein, Ann. Phys. (N.Y.) 8, 343 (1959).
M.H. Cohen, E.N. Economou and C. M. Soukoulis, Phys. Rev. Lett.51, 1202 (1983).
N.F. Mott, Phil. Mag.19, 835 (1969).
V. Ambegaokar, B.I. Halperin and J.S. Langer, Phys. Rev. B 4, 2612 (1971).
G.E. Pike and C.H. Seager, in Amorphous and Liquid Semiconductors, edited by J. Stuke and W. Brenig, Taylor and Francis, London, 1974, p. 147.
M. Poliak, J. Noncryst. Solids 11, 1 (1972).
E.M. Hamilton, Phil. Mag.26, 1043 (1972).
V. Nguyen, B. Shklovskii and A. Efros, Sov. Phys. Semi- conductors 13, 11 (1979).
D. Adler, L.P. Flora and S.D. Senturia, Solid State Commun. 12, 9 (1973).
D. Emin, Phys. Rev. Lett.32, 303 (1974).
E.N. Economou, S. Kirkpatrick, M.H. Cohen and T.P. Eggarter, Phys. Rev. Lett. 25, 520 (1970).
E.N. Economou and M.H. Cohen, Phys. Rev. Lett. 25 1445 (1970).
T.D. Moustakas, Solid State Commun. 35, 745 (1980).
W.B. Jackson, N.M. Amer, A.C. Boccara and D. Fournier, Appl. Opt.20, 1333 (1981).
C.F. Fuleihan and D. Adler, Bull. Am. Phys. Soc.27, 873 (1982).
J. Orenstein and M. Kastner, Phys. Rev. Lett.46, 1421 (1981).
T. Tiedje and A. Rose, Solid State Commun. 37, 49(1981).
A. Madan, Solar Cells 2, 277 (1980).
D.V. Lang, J.D. Cohen and J.P. Harbison, Phys. Rev. B25, 5285 (1982).
I. Balberg, Phys. Rev. B 22, 3853 (1980).
H. Okushi, Y. Tokumaru, S. Yamasaki, H. Oheda and K. Tanaka, Phys. Rev. B 25, 4313(1982).
I. Balberg, E. Gal and B. Pratt, J. Noncryst. Solids 59–60, 277 (1983).
N.M. Johnson, J. Noncryst. Solids 59–60, 265 (1983).
K.P. Chik, C. K. Yu, P.K. Lim, B.Y. Tong, S.K. Wong and P.K. John, J. Noncryst. Solids 59–60, 285 (1983).
M. L. Knotek, M. Poliak, T. M. Donovan and H. Kurtzman, Phys. Rev. Lett.30, 853 (1973).
P. Viscor and A.D. Yoffe, J. Noncryst. Solids 35–36, 409 (1980).
J.A. Sauvage, C.J. Mogab and D. Adler, Phil. Mag.25, 1305 (1972).
N.B. Goodman and H. Fritzsche, Phil. Mag. B 42, 149 (1980).
M.L. Theye, Mat. Res. Bull.6, 103 (1971).
M.H. Brodsky, R.S. Title, K. Weiserand G.D. Pettit, Phys. Rev. B 1, 2632 (1970).
P.A. Walley and A.K. Jonscher, Thin Solid Films 1, 367 (1967).
K.L. Chopra and S.K. Bahl, Phys. Rev. B 1, 2545 (1970).
M.L. Knotek, Solid State Commun. 17, 1431(1975).
M.H. Brodsky and R.S. Title, Phys. Rev. Lett. 23., 581 (1969).
R.C. Chittick, J.H. Alexanderand H.F. Sterling, J. Electrochem. Soc.116, 77 (1969).
W.E. Spear and P.G. LeComber, Adv. Phys.26, 811 (1977).
N.F. Mott and E. A. Davis, Electronic Processes in Non Crystalline Materials, Second Edition, Clarendon Press, Oxford, 1979.
S.R. Ovshinsky and D. Adler, Contemp. Phys.19, 109 (1978).
S.R. Ovshinsky, in Structure and Excitations of Amorphous Solids, edited by G. Lucovsky and F. Galeener, A.I.P., N.Y., 1976, p. 31.
J.C. Phillips, J. Noncryst. Solids 34, 153 (1979).
D. Adler, J. Noncryst. Solids 35–36, 819 (1980).
D. Adler, Phys. Rev. Lett.41, 1755 (1978).
G.D. Cody, C.R. Wronski, B. Abeles, R.B. Stephens and B. Brooks, Solar Cells 2, 227 (1980).
B. von Roedern, L. Ley, M. Cardona and F.W. Smith, Phil. Mag. B 40, 433 (1980).
M.E. Eberhart, K.H. Johnson and D. Adler, Phys. Rev. B 26; 3138 (1982).
W.E. Carlos and P.C. Taylor, Phys. Rev. B 25, 1435 (1982).
H. N. Lohneysen, H.J. Schink and W. Beyer, Phys. Rev. Lett.52, 549 (1984).
J.E. Graebner, B. Golding, L.C. Allen, D.K. Biegelsen and M. Stutzmann, Phys. Rev. Lett.52, 553 (1984).
H. Fritzsche, C.C. Tsai and P. Persans, Solid State Technol. 21, 55(1978).
R. Tsu, personal communication, 1983.
D. Adler, J. de Phys. 42, C4–3 (1981).
A. Madan, P.G. LeComber and W.E. Spear, J. Noncryst. Solids 20, 239(1976).
J.D. Cohen, D.V. Lang and J.P. Harbison, Phys. Rev. Lett.45, 197 (1980).
D. Adler, in Semiconductor and Semimetals, edited by R.K. Willardson and A.C. Beer, Academic Press, N.Y., 1984, Vol.21A, p. 291.
D.C. Alien and J.D. Joannopoulos, Phys. Rev. Lett.44, 43 (1980).
D. Adler, Solar Cells 9, 133 (1983).
M. Kastner, D. Adler and H. Fritzsche, Phys. Rev. Lett.37, 1504 (1976).
D. Adler and E.J. Yoffa, Canad. J. Chem.55, 1920 (1977).
A. Kasdan, D.P. Go shorn and W. A. Lanford, J. Noncryst. Solids, in press.
J.D. Joannopoulos and M.L. Cohen, Solid State Phys. 31, 71 (1976).
J. Tauc, in Optical Properties of Solids, edited by F. Abels, North-Holland, Amsterdam, 1974, p. 279.
V. Vorlicek, M. Zavetova, S.K. Pavlov and L. Pajasova, J. Noncryst. Solids 45, 289 (1981).
B. von Roedern, L. Ley and M. Cardona, Phys. Rev. Lett.39, 1576 (1977).
W.E. Pickett, Phys. Rev. B 23, 6603 (1981).
W.Y. Ching, D.J. Lam and C.C. Lin, Phys. Rev. Lett.42, 805 (1979).
L. Ley, inSemiconductor and Semimetals, edited by R.K. Willardson and A.C. Beer, Academic Press, N.Y., Vol 21 B, in press.
G.D. Cody in Semiconductors and Semimetals, edited by R.K. Willardson and A.C. Beer, Academic Press, N.Y., 1984, Vol. 21 B, in press.
J.P. Dow and D. Redfield, Phys. Rev. B 5, 594 (1972).
S. Abe and Y. Toyazawa, J. Phys. Soc. Japan 50, 2185 (1981).
T. Tiedle in Semiconductors and Semimetals, edited by R.K. Willardson and A.C. Beer, Academic Press, N.Y., 1984, Vol. 21 B, in press.
C. Y. Huang, S. Guha and S.J. Hudgens, Phys. Rev. B 27, 7460 (1983).
W.E. Spear, J. Noncryst. Solids 59–60, 1 (1983).
C. R. Wronski, B. Abeles, T. Tiedje and G.D. Cody, Solid State Commun. 44; 1423 (1982).
W.B. Jackson, N.M. Amer, A.C. Boccara and D. Fournier, Appl. Opt.20, 1333 (1981).
D. Adler, A.I.P. Conf. Proc, in press.
D.K. Biegelsen, R.A. Street, C.C. Tsai and J.C. Knights, Phys. Rev. B 20, 4839 (1979).
W.B. Jackson and N.M. Amer, Phys. Rev. B. 25, 5559 (1982).
C.-Y. Huang, S. Guha and S.J. Hudgens, Phys. Rev. B 27, 7460 (1983).
W. Beyer, H. Meli and H. Overhof, J. de Phys. 42, C4–103 (1981).
W. Meyer and H. Neldel, Z. Tech. Phys.18, 588 (1937).
F.R. Shapiro and D. Adler, J. Noncryst. Solids 66, 303 (1984).
P.G. LeComber, D.I. Jones and W.E. Spear, Phil. Mag.35, 1173 (1977).
M. Rollos, Phil. Mag. B 38, 477 (1978).
D. Emin, Phil. Mag.35, 1189 (1977).
E.J. Yoffa and D. Adler, Phys. Rev. B 15, 2311 (1977).
D.I. Jones, P.G. LeComber and W.E. Spear, Phil. Mag.36, 541 (1977).
L. Onsager, Phys. Rev. 54, 554 (1938).
A. Rose, Concepts in Photoconductivity and Allied Problems, Interscience, N.Y. 1963.
T. Tiedje, J.M. Cebulka, D.L. Morel and B. Abeles, Phys. Rev. Lett.46, 1425 (1981).
W.E. Spear, J. Noncryst. Solids 1, 197 (1969).
M. Silver, E. Snow, and D. Adler, Solid State Comm. 51, 581 (1984).
W.E. Spear and H. Steemers, Phil. Mag. B 47, L77 (1983).
M. Silver, E. Snow, M. Aiga, V. Cannella, R. Ross, Z. Yaniv, M. Shaw and D. Adler, J. Noncryst. Solids 59–60, 445 (1983).
D. Adler, M. Silver, A. Madan and W. Czubatyj, J. Appl. Phys.51, 6429 (1980).
J. Tauc, in Semiconductors and Semimetals, edited by R.K. Willardson and A. C. Beer, Academic Press, N.Y., 1984, Vol. 21 A, p. 299.
B. Abeles and T. Tiedje, Phys. Rev. Lett.51, 2003 (1983).
D.L. Staebler and C.R. Wronski, J. Appl. Phys.51, 3262 (1980).
M. Tanielian, Phil. Mag. B 45, 435 (1982).
H. Dersch, J. Stuke and J. Beichler, Phys. Stat. Sol. B 105, 265 (1981).
R.S. Crandall, J. de Phys. 42, C4–413 (1981).
D.E. Carlson, A. Moore and A. Catalano, J. Noncryst. Solids 66, 59 (1984).
S. Yamazaki, T. Shiraishi and D. Adler, J. Noncryst. Solids, in press.
C.C. Tsai, J.C. Knights and M.J. Thompson, J. Noncryst. Solids 66, 45 (1984).
D. Adler, M.E. Eberhart, K.H. Johnson and S.A. Zygmunt, J. Noncryst. Solids 66, 273 (1984).
S.R. Ovshinsky and A. Madan, Nature 276, 482 (1978).
A. Madan, S.R. Ovshinsky and E. Benn, Phil. Mag.40, 259 (1979).
D. Adler, Solar Cells 2, 199 (1980).
D. Adler and E.J. Yoffa, Phys. Rev. Lett. 3 6, 1197 (1976).
S.G. Bishop and N.P. Shevchik, Phys. Rev. B 12, 1567 (1975).
P. Nagels, R. Callaerts and M. Denayer, in Amorphous and Liquid Semiconductors, edited by J. Stuke and W. Brenig, Taylor and Francis, London, 1974, p. 867.
C.H. Seager, D. Emin and R.K. Quinn, Phys. Rev. B 8, 4746 (1973).
D. Emin, Adv. Phys.22, 57 (1973).
D. Adler, H.K. Henisch and N.F. Mott, Rev. Mod. Phys.50, 209 (1978).
S.R. Ovshinsky, in Amorphous and Liquid Semiconductors, edited by W.E. Spear, C.I.C.L., University of Edinburgh, Scotland, 1977, p. 519.
B.A. Khan and D. Adler, J. Noncryst. Solids 66, 35(1984).
A.A. Andreev, Z.v Borisova, E.A. Bishkov and Ym. G. Vlasov, J. Noncryst. Solids 35–36, 901 (1980).
R. Flasck, M. Izu, K. Sapru, T. Anderson, S.R. Ovshinsky and H. Fritzsche, in Amorphous and Liquid Semiconductors, edited by W.E. Spear, C.I.C.L., University of Edinburgh, Scotland, 1977, p. 524.
G. Pfister and H. Scher, Adv. Phys. 2 7, 74 (1978).
B.A. Khan, M. Kastner and D. Adler, Solid State Commun. 45, 187 (1983).
G.S. Higashi and M. Kastner, Phys. Rev. Lett.47, 124 (1981).
T. Thio, D. Monroe and M. Kastner, Phys. Rev. Lett.52, 667 (1984).
J.M. Marshall and A.E. Owen, Phil. Mag.33, 457 (1976).
J.E. Mahan and R.H. Bube, J. Nonciyst. Solids 24, 29 (1977).
N.A. Rajdy and M. Green, Phil. Mag.41, 497 (1980).
R.C. Frye and D. Adler, Phys. Rev. Lett.46, 1027 (1981).
B.A. Khan, P. Bai and D. Adler, J. Noncryst. Solids 66, 321(1984).
R.C. Frye and D. Adler, Phys. Rev. B 24, 5812 (1981).
R.C. Frye and D. Adler, Phys. Rev. B 24, 4855 (1981).
R.A. Street, Adv. Phys.25, 397 (1976).
F. Mollot, J. Cernogora and C. Benoit a la Guillaume, Phys. Stat. Sol. A 17, 521 (1974).
S.G. Bishop, U. Strom and P.C. Taylor, Phys. Rev. Lett.34, 1346 (1975).
D. Adler, in Amorphous and Liquid Semiconductors, edited by W.E. Spear, C.I.C.L., University of Edinburgh, Scotland, 1977, p. 695.
D. Adler, M.S. Shur, M. Silver and S.R. Ovshinsky, J. Appl. Phys.51, 3289.(1980).
J.P. deNeufville, R. Seguin, S.C. Moss and S.R. Ovshinsky, in Amorphous and Liquid Semiconductors, edited by J. Stuke and W. Brenig, Taylor and Francis, London, 1974, p. 737.
K. Tanaka, in Structure and Excitation of Amorphous Solids, edited by G. Lucovsky and F. Galeener, A.I.P. Conf. Proc. No. 31, A.I.P. , N.Y. 1976, p. 148.
D.K. Biegelsen and R.A. Street, Phys. Rev. Lett.44, 803 (1980).
D. Adler and S.C. Moss, J. Vac. Sci. Tech.9, 1182 (1972).
D. Adler and J. Feinleib, in Physics of Opto-Electronic Materials, edited by W.A. Albers, Jr., Plenum Press, N.Y., 1971, p. 233.
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Adler, D. (1985). Chemistry and Physics of Covalent Amorphous Semiconductors. In: Adler, D., Schwartz, B.B., Steele, M.C. (eds) Physical Properties of Amorphous Materials. Institute for Amorphous Studies Series. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2260-1_2
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