Abstract
Models that consider temperature alone or a combination of temperature and heating duration have been defined for the thermal maturation of sedimentary organic matter (OM). Both types of models appear to give adequate maximum paleotemperature estimates, but these estimates are imprecise due to problems in measuring thermal maturity (rank), heating duration, and maximum temperature (T max). Must temperature and functional heating duration (t) be considered or is T max alone sufficient to characterize thermal maturation to the precision level now possible in sedimentary environments? This question is addressed by developing a temperature-heating duration model for OM thermal maturation based on a broad geological data base and comparing it to other empirical models that consider T max alone or T max and t.
If a first-order reaction can be assumed for OM thermal maturation, then its reaction rate constant, k, is equal to -ln(f)·(1/t), where t is the functional heating duration and f is the fraction of reactable OM. The fraction of reactable OM (f) is the complement of transformation ratio (r) estimated from Tissot and Espitalié’s 1975 model of vitrinite reflectance (R m ) evolution. The functional heating duration for burial diagenesis is calculated by determining the elapsed time as temperature increases within 15°C of T max without exceeding the time necessary for the controlling reactions to approach completion. Geologic field data and OM thermal maturation experiments extrapolated to a geologic time and temperature range suggest OM thermal maturation reactions approach completion in about 106 to 107 years during burial diagenesis. The elapsed time near T max is used as the reaction time in geothermal systems and contact metamorphism by intrusive sheets.
The calculated reaction rate when plotted on an Arrhenius diagram [ln k versus absolute temperature (1/T)] falls along three subparallel straight-line segments. These segments correspond to OM thermal maturation in three different environments: burial diagenesis, geothermal systems, and contact metamor-phism by intrusive sheets. These environments were individually analyzed by linear regression of ln(k) and 1/T data which for a single reaction mechanism conform to a straight line, ln(k) = (−E a /R)1/T + ln A, where E a is the activation energy for the reaction, R is the gas constant, and A is the Arrhenius factor. OM thermal maturation in burial diagenesis shows a strong linear relationship (correlation coefficient, r = −0.84) with an E a of 9 kcal/mol (38 kJ/mol) and an A of 7 × 10−11/s. OM thermal maturation in geothermal systems shows a moderate linear relationship (r = −0.74), an E a of 11 kcal/mol (46 kJ/mol), and an A of 2.5 × 10−7/s. OM thermal maturation from contact metamorphism by intrusive sheets is modeled by a linear relationship (r = −0.64), with an E a of 12 kcal/mol (50 kJ/mol), and an A of 1.5 × 10−3/s. In summary, these data conform to lines with a uniform and similar slope, indicating that OM thermal maturation consists of a pseudoreaction that has a similar E a in each environment.
OM thermal maturation differs in burial diagenesis, geothermal systems, and contact metamorphism by intrusive sheets primarily in the reaction rate at a given temperature. This may be due to differences in pressure between these environments. The different reaction rate in each environment is also expressed in the time required for OM thermal maturation to stabilize. The regression line calculated for geothermal systems overlies a T max-R m model that is based on geologic evidence that indicates t was not important after 104 years. The regression line from contact metamorphism by igneous sheets is in fair agreement with data from laboratory experiments that indicate stabilization after 10−1 to 10° years.
Comparison of these calculated regression curves to published models of OM thermal maturation indicates that precision is not increased by considering heating duration. The data can be adequately modeled by considering T max alone.
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References
Abelson, P.H. 1963. Organic geochemistry and the formation of petroleum. In: Proceedings of the Sixth World Petroleum Congress, Geophysics and Geology, section 1, Hamburg, Verien Zur Forderung, pp. 397–407.
Abelson, P.H. 1967. Conversion of biochemicals to kerogen and n-paraffins. In: Abelson, P.H. (ed.): Researches in Geochemistry: Vol. 2. New York, Wiley, pp. 63–86.
Almon, W.R. 1974. Petroleum-forming reactions: Clay catalyzed fatty acid decarboxylation. Ph.D. dissertation, University of Missouri, Columbia, 117 pp.
Ammosov, I.I., Babashkin, B.G., and Sharkova, L.S. 1975. Bituminit nizhnekembriyskikh otlozheniy Irkuts-kay neftegazonosnoy oblasti (Bituminite of Lower Cambrian deposits in the Irkutsk oil and gas region). In: Yeremin, I.V. (ed.): Paleotemperatury zon Nefteobrazovaniya. Moscow, Nauka Press, pp. 25–29.
Ammosov, I.I., Gorshkov, V.I., Greshnikov, N.P., and Kalmykov, G.S. 1977. Paleogeotermicheskiye Kriteriyi Razmeshcheniya Neftyanykh Zalezhen (Paleogeothermal Criteria of the Location of Petroleum Deposits). Leningrad, Nedra Press.
Asakawa, T., and Fujita, Y. 1979. Organic metamorphism and hydrocarbon generation in sedimentary basins of Japan. In: Generation and Maturation of Hydrocarbons in Sedimentary Basins. United National Economic and Social Commission for Asia and the Pacific, Technical Publication Series 6, pp. 142–162.
Baker, E.W., Huang, W.Y., Rankin, J.G., Castano, J.G., Guinn, J.R., and Fuex, A.N. 1977. Electron paramagnetic resonance study of thermal alteration of kerogen in deep-sea sediments by basaltic sill intrusion. In: Lancelot, Y., et al. (eds.): Initial Reports of Deep Sea Drilling Project: Vol. 41. Washington, DC, U.S. Government Printing Office, pp. 839–847.
Barber, P.M. 1982. Palaeotectonic evolution and hydrocarbon genesis of the central Exmouth Plateau. Australian Petroleum Exploration Association Journal 22:131–144.
Barker, C.E. 1983. The influence of time on metamorphism of sedimentary organic matter in selected geothermal systems, western North America. Geology 11:384–388.
Barker, C.E., and Elders, W.A. 1981. Vitrinite reflectance geothermometry and apparent heating duration in the Cerro Prieto geothermal field. Geothermics 10:207–223.
Barker, C.E., and Pawlewicz, M.J. 1985. The correlation of vitrinite reflectance with maximum temperature in humic organic matter. Abstracts, Society of Economic Paleontologists and Mineralogists Annual Midyear Meeting, Golden, Colorado, p. 8.
Barker, C.E., and Pawlewicz, M.J. 1986. The correlation of vitrinite reflectance with maximum temperature in humic organic matter. In: Buntebarth, G., and Stegena, L. (eds.): Paleogeothermics. New York, Springer-Verlag, pp. 79–93.
Barker, C.G. 1979. Organic geochemistry in petroleum exploration. American Association of Petroleum Geologists Continuing Education Course Note Series 10, 159 pp.
Bartenstein, H., and Teichmüller, R. 1974. Inkohlungsuntersuchugen, ein Schlussel zur Prospektierrung von palaozoischen Kohlenwasserstoff-Lagerstatten. Fortschritte in der Geologie von Rheinland und Westfalen 24:129–160.
Benson, S.W. 1965. Bond energies. Journal of Chemical Education 42:502–518.
Berkowitz, N. 1967. The coal-carbon transformation: Basic mechanisms. In: Symposium on the Science and Technology of Coal. Ottawa, Canada, Mines Branch, Department of Energy, Mines, and Resources, pp. 148–156.
Blumer, M. 1965. Organic pigments: Their long term fate. Science 149:722–726.
Bostick, N.H. 1971. Thermal alteration of clastic organic particles as an indicator of contact and burial metamorphism in sedimentary rocks. Geoscience and Man 3:83–92.
Bostick, N.H. 1979a. Microscopic measurement of the level of catagenesis of solid organic matter in sedimentary rocks to aid exploration for petroleum and to determine former burial temperatures: A review. In: Scholle, P.A., and Schluger, P.R. (eds.): Aspects of Diagenesis. Society of Economic Paleontologists and Mineralogists Special Publication 26, pp. 17–44.
Bostick, N.H. 1979b. Organic petrography of nineteen rocks, a split of each analyzed in thirty different laboratories. Abstracts of Papers, Ninth International Congress of Carboniferous Stratigraphy and Geology, Urbana, Illinois, p. 24.
Briggs, N.D., Naeser, C.W., and McCulloh, T.H. 1981. Thermal history by fission-track dating, Tejon oil field area, California (abst.). American Association of Petroleum Geologists Bulletin 65:906.
Brooks, J.D. 1970. The use of coals as indicators of the occurrence of oil and gas. Australian Petroleum Exploration Association Journal 10:35–40.
Bullard, E.C. 1947. The time necessary for a borehole to attain temperature equilibrium. Monthly Notices, Royal Astronomical Society 5:127–130.
Cardoso, J.N., et al. 1978. Preliminary organic geochemical analyses. Site 391, leg 44 of the deep sea drilling project. In: Benson, W.E., and Sheridan, R.E. (eds.): Initial Reports of the Deep Sea Drilling Project: Vol. 44. Washington, DC, U.S. Government Printing Office, pp. 617–624.
Cassou, A.-M., Connan, J., and Porthault, B. 1977. Relations between maturation of organic matter and geothermal effect, as exemplified in Canadian east coast offshore wells. Canadian Petroleum Geologists Bulletin 25:174–194.
Castano, J.R., and Sparks, D.M. 1974. Interpretation of vitrinite reflectance measurements in sedimentary rocks and determination of burial history using vitrinite reflectance and authigenic minerals. In: Dutcher, R.R., Hacquebard, P.A., Schopf, J.M., and Simon, J.A. (eds.): Carbonaceous Materials as Indicators of Metamorphism. Geological Society of America Special Paper 153, pp. 31–52.
Cecil, C.B., Stanton, R.W., Allshouse, S.D., and Cohen, A.D. 1979. Effects of pressure on coalification. Abstracts of Papers, Ninth International Congress Carboniferous Stratigraphy and Geology, Urbana, Illinois, p. 32.
Chandra, D, and Bond, R.L. 1956. The reflectance of carbonized coals. In: Proceedings of the International Committee for Coal Petrology: Vol. 2. pp. 47–51.
Chatterjee, N.N., Chandra, D., and Ghosh, T.K. 1964. Reflectance of Poniati seam affected by a mica-peridotite dyke. Journal of Mines, Metals, and Fuels (India) 12:346–348.
Clegg, K.E. 1955. Metamorphism of coal by peridotite dikes in southern Illinois. Illinois Geological Survey Report of Investigations 178:18 pp.
Connan, J. 1974. Time-temperature relation in oil genesis. American Association of Petroleum Geologists Bulletin 58:2516–2521.
Connan, J., and Cassou, A.M. 1980. Properties of gases and petroleum liquids derived from terrestrial kerogen at various maturation levels. Geochimica et Cosmochimica Acta 44:1–23.
Cornelius, C.D. 1975. Geothermal aspects of hydrocarbon exploration in the North Sea areas. Norges Geologiske Undersokelse 316:25–66.
Cornford, C., Rullkotter, J., and Welte, D.H. 1979. Organic geochemistry of DSDP leg 47A, site 397, eastern North Atlantic: Organic petrography and extractable hydrocarbons. In: Rad, von U., et al. (eds.): Initial Reports of the Deep Sea Drilling Project: Vol. 47, Part 1. Washington, DC, U.S. Government Printing Office, pp. 511–522.
Corrigan, G.M. 1982. Cooling rate studies of rocks from two basic dykes. Mineralogical Magazine 46:387–394.
Creaney, S. 1980. Petrographic texture and vitrinite reflectance variation on the Alston block, north-east England. Yorkshire Geological Society Proceedings 42:553–580.
Crelling, J.C., and Dutcher, R.R. 1968. A petrologic study of a thermally altered coal from the Purgatoire River Valley of Colorado. Geological Society of America Bulletin 79:1375–1386.
Davis, A., and Spademan, W. 1964. The role of the cellulosic and lignitic components of wood in artificial coalification. Fuel 43:215–224.
Demaison, G.J. 1975. Relationships of coal rank to paleotemperatures in sedimentary rocks. In: Alpern, B. (ed.): Petrographie de la Matiere Organique des Sediments, Relations avec la Paleotemperature et le Potentiel Petrolier. Paris, Centre National de la Recherche Scientifique, pp. 217–224.
Diessel, C.F.K., Brothers, R.N., and Black, P.M. 1978. Coalification and graphitization in high-pressure schists in New Caledonia. Contributions to Mineralogy and Petrology 68:63–78.
Dow, W.G. 1978. Petroleum source beds on continental slopes and rises. American Association of Petroleum Geologists Bulletin 62:1584–1606.
Drury, M.J. 1984. On a possible source of error in extracting equilibrium formation temperatures from borehole BHT data. Geothermics 13:175–180.
Drury, M.J., Jessop, A.M., and Lewis, T.J. 1984. The detection of groundwater flow by precise temperature measurements in boreholes. Geothermics 13:163–174.
Eby, J.B. 1925. Contact metamorphism of some Colorado coals by intrusives. American Institute of Mining and Metallurgical Engineers Transactions 71:246.
Ghosh, T.K. 1967. A study of temperature conditions at igneous contacts with certain Permian coals of India. Economic Geology 62:109–117.
Goldstein, T.P. 1983. Geocatalytic reactions in formation and maturation of petroleum. American Association of Petroleum Geologists Bulletin 67:152–159.
Goodarzi, F., and Murchinson, D.G. 1977. Effect of prolonged heating on the optical properties of vitrinite. Fuel 56:89–96.
Gorohkov, S.S., Petrova, N.I., and Kovalenko, V.S. 1973. Experimental study of the alteration of biogenic carbon at high temperature and pressure. Doklady Akademii Nauk SSSR 209:194–196.
Gretener, P.E., and Curtis, C.D. 1982. Role of temperature and time on organic metamorphism. American Association of Petroleum Geologists Bulletin 66:1124–1129.
Hacquebard, P.A. 1975. Pre- and postdeformational coalification and its significance for oil and gas exploration. In: Alpern, B. (ed.): Petrographie de la Matiere Organique des Sediments, Relations avec la Paleotemperature et le Potentiel Petrolier. Paris, Centre National de la Recherche Scientifique, pp. 225–241.
Harwood, R.J. 1977. Oil and gas generation by laboratory pyrolysis of kerogen. American Association of Petroleum Geologists Bulletin 61:2082–2102.
Hoering, T.C., and Abelson, P.H. 1963. Hydrocarbons from kerogen. Carnegie Institution of Washington Yearbook 62:229–234.
Hood, A., and Castano, J.R. 1974. Organic metamorphism: Its relationship to petroleum generation and application to studies of authigenic minerals. United Nations Economic Commission for Asia and the Far East Technical Bulletin 8:85–118.
Hood, A., Gutjahr, C.C.C., and Heacock, R.L. 1975. Organic metamorphism and the generation of petroleum. American Association of Petroleum Geologists Bulletin 59:986–996.
Huc, A.Y., and Hunt, J.M. 1980. Generation and migration of hydrocarbons in offshore south Texas Gulf Coast sediments. Geochimica et Cosmochimica Acta 44:1081–1089.
Huck, Von G., and Patteisky, K. 1964. Inkohlungsreaktionen unter Druck. Fortschritte in der Geologie von Reinland und Westfalen 12:551–558.
Hunt, J.M. 1979. Petroleum Geochemistry and Geology. San Francisco, Freeman, 617 pp.
Ishiwatari, R., Ishiwatari, M., Rohrback, B.G., and Kaplan, I.R. 1977. Thermal alteration experiments on organic matter from recent marine sediments in relation to petroleum genesis. Geochimica et Cosmochimica Acta 41:814–828.
Jaeger, J.C. 1959. Temperatures outside a cooling intrusive sheet. American Journal of Science 257:44–54.
Jaeger, J.C. 1964. Thermal effects of intrusions. Reviews of Geophysics 2:443–466.
Johns, W.D. 1979. Clay mineral catalysis and petroleum generation. Annual Reviews of Earth and Planetary Science 7:183–198.
Johnson, V.H. 1952. Thermal metamorphism and ground-water alteration of coking coal near Paonia, Colorado. Mining Engineering 4:391–395.
Jones, J.M., and Creaney, S. 1977. Optical character of thermally metamorphosed coals of northern England. Journal of Microscopy 109:105–118.
Juntgen, H., and Klein, J. 1975. Origin of natural gas from coaly sediments. Erdol und Kohle 28:65–73.
Kantsler, A.J., and Cook, A.C. 1979. Maturation patterns in the Perth Basin. Australian Petroleum Exploration Association Journal 19:94–107.
Kantsler, A.J., Smith, G.C., and Cook, A.C. 1978. Lateral and vertical rank variation: Implications for hydrocarbon exploration. Australian Petroleum Exploration Association Journal 18:143–156.
Karweil, J. 1956. Die Metamorphose der Kohlen von Stand punkt der physikalischen Chemie. Deutsche Geologische Gesellschaft Zeitschrift 107:132–139.
Karweil, J. 1975. The determination of paleotemperatures from the optical reflectance of coaly particles in sediments. In: Alpern, B. (ed.): Petrographie de la Matiere Organique des Sediments, Relations avec la Paleotemperature et le Potentiel Petrolier. Paris, Centre National de la Recherche Scientifique, pp. 195–203.
Katz, B.J., Liro, L.M., Lacey, J.E., and White, H.E. 1982. Time and temperature in petroleum formation: Application of Lopatin’s method to petroleum exploration: Discussion. American Association of Petroleum Geologists Bulletin 66:1150–1151.
Kharaka, Y.K., Carothers, W.W., and Rosenbauer, R.J. 1983. Thermal decarboxylation of acetic acid: Implications for the origin of natural gas. Geochimica et Cosmochimica Acta 47:397–402.
King, J.D., and Claypool, G.E. 1982. Biological marker compounds and implications for generation and migration of petroleum in rocks of the Point Conception deep-stratigraphic test well, OCS-CAL 78–164 no. 1, offshore California. In: Issacs, C.M., and Garrison, R.E. (eds.): Petroleum Generation and Occurrence in the Miocene Monterey Formation, California. Los Angeles, Pacific Section, Society of Economic Paleontologists and Mineralogists, pp. 191–200.
Kisch, H.J. 1966. Carbonization of semi-anthracitic vitrinite by an analcime basanite sill. Economic Geology 61:1043–1063.
Laplante, R.E. 1974. Hydrocarbon generation in Gulf Coast Tertiary sediments. American Association of Petroleum Geologists Bulletin 58:1281–1289.
Law, B.E., Spencer, C.W., and Bostick, N.H. 1980. Evaluation of organic matter, subsurface temperature and pressure with regard to gas generation in lowpermeability Upper Cretaceous and Lower Tertiary sandstones in Pacific Creek area, Sublette and Sweetwater Counties, Wyoming. Mountain Geologist 17:23–35.
Leith, M.J., and Rowsell, D.M. 1979. Burial history and temperature-depth conditions for hydrocarbon generation and migration on the Agulas Bank, South Africa. In: Anderson, A.M., and van Biljon, W.J. (eds.): Some Sedimentary Basins and Associated Ore Deposits of South Africa. Geological Society of South Africa Special Publication 6, pp. 205–217.
Lopatin, N.V. 1971. Temperature and geological time as factors of carbonification. Akademiya Nauk SSSR Series Geologicheskaya Izvestiya 3:95–106.
Lopatin, N.V., and Bostick, N.H. 1973. Geologicheskiye faktory katagneza ugley. In: Priroda Organischeskogo Veshchestva Sovremennykh i Isokopaemykh Osadkov. Moskow, Nauka Press, pp. 79–90.
Mackenzie, A.S., and McKenzie, D. 1983. Isomerization and aromatization of hydrocarbons in sedimentary basins formed by extension. Geological Magazine 120:417–528.
Magoon, L.B., and Claypool, G.E. 1982. NPRA Inigok no. 1: Use of Lopatin’s method to reconstruct thermal maturity. Pacific Section, American Association of Petroleum Geologists Newsletter, January 1982, pp. 4–6.
Marshall, C.E. 1952. The thermal metamorphism of coal seams. Sir Douglas Mawson Anniversary Volume, Adelaide, Scotland, Adelaide University, pp. 109–142.
McCartney, J.T., and Teichmüller, M. 1972. Classification of coals according to degree of coalification by reflectance of the vitrinite component. Fuel 51:64–68.
McNab, J.G., Smith, P.V., and Betts, R.L. 1952. The evolution of petroleum. Industrial and Engineering Chemistry 44:2556–2563.
McTavish, R.A. 1978. Pressure retardation of vitrinite reflectance, offshore northwest Europe. Nature 271:648–650.
Myhr, D.W., and Gunther, P.R. 1974. Lithostratigraphy and coal reflectance of a Lower Cretaceous deltaic succession in the Gulf-Mobil Parsons F-09 borehole, N.W.T. Geological Survey of Canada Paper 74-1b, pp. 24–28.
Nagornyi, V.N., and Nagornyi, Y.N. 1974. The question of the quantitative evaluation of the role of the time in processes of the regional metamorphism of coals. Solid Fuel Chemistry 8:30–36.
Neruchev, S.G., and Parparova, G.M. 1972. The role of geologic time in processes of metamorphism of coal and dispersed organic matter in rocks (in Russian). Otdeleniye Geologiya i Geofizika (Akademiya Nauk SSSR Sibirsk) 10:3–10.
Pauling, L. 1965. College Chemistry (3rd ed.). San Francisco, Freeman, 832 pp.
Pearson, D.B. 1981. Experimental simulation of thermal maturation in sedimentary organic matter. Ph.D. dissertation, Rice University, Houston, TX, 563 pp.
Peters, K.E., Ishiwatari, R., and Kaplan, I.R. 1977. Color of kerogen as index of organic maturity. American Association of Petroleum Geologists Bulletin 61:504–510.
Peters, K.E., Simoneit, B.R.T., Brenner, S., and Kaplan, I.R. 1978. Vitrinite reflectance-temperature determination for intruded Cretaceous black shale in the eastern Atlantic. In: Oltz, D.F. (ed.): Low Temperature Metamorphism of Kerogen and Clay Minerals. Los Angeles, Pacific Section, Society of Economic Paleontologists and Mineralogists, pp. 65–96.
Philippi, G.T. 1965. On the depth, time, and mechanism of petroleum generation. Geochimica et Cosmochimica Acta 29:1021–1049.
Povoledo, D., and Vallentyne, J.R. 1964. Thermal reaction kinetics of the glutamic acid-pyroglutamic acid system in water. Geochimica et Cosmochimica Acta 28:731–734.
Price, L.C. 1982. Organic geochemistry of core sample from an ultra deep hot well (300°C, 7 km). Chemical Geology 37:215–228.
Price, L.C. 1983. Geologic time as a parameter in organic metamorphism and vitrinite reflectance as an absolute paleogeothermometer. Journal of Petroleum Geology 6:5–38.
Price, L.C., and Barker, C.E. 1985. Suppression of vitrinite in amorphous-rich kerogen: A major unrecognized problem. Journal of Petroleum Geology 8:59–84.
Price, L.C., Clayton, J.L., and Rumen, L.L. 1981. Organic geochemistry of the 9.6 km Bertha Rogers no. 1 well, Oklahoma. Organic Geochemistry 3:59–77.
Rashid, M.A., Purcell, L.P., and Hardy, I.A. 1980. Source rock potential for oil and gas of the east Newfoundland and Labrador Shelf areas. In: Miall, A.D. (ed.): Facts and Principles of World Petroleum Occurrence. Canadian Society of Petroleum Geologists Memoir 6, pp. 589–608.
Rohrback, B.G. 1979. Analysis of low molecular weight products generated by thermal decomposition of organic matter in recent sedimentary environments. Ph.D. dissertation, University of California, Los Angeles, 195 pp.
Sajgo, C. 1980. Hydrocarbon generation in a super-thick Neogene sequence in south-east Hungary: A study of the extractable organic matter. In: Douglas, A.G., and Maxwell, J.R. (eds.): Advances in Organic Geochemistry 1979. New York, Pergamon Press, pp. 103–113.
Saxby, J.D. 1982. A reassessment of the range of kerogen maturities in which hydrocarbons are generated. Journal of Petroleum Geology 5:117–128.
Schapiro, N., and Gray, R.J. 1966. Physical variations in highly metamorphosed Antarctic coals. In: Gould, F.E. (ed.): Coal Science. American Chemical Society Advances in Chemistry Series, vol. 55, pp. 196–217.
Scholle, P.A. 1977. Geological studies on the COST no. B-2 well, U.S. mid-Atlantic outer continental shelf area. U.S. Geological Survey Circular 750, 71 pp.
Seyer, W.F. 1933. The conversion of fatty and waxy substances into petroleum hydrocarbons. Institute of Petroleum Technologists Journal 19:773–783.
Shibaoka, M., and Bennett, A.J.R. 1977. Patterns of diagenesis in some Australian sedimentary basins. Australian Petroleum Exploration Association Journal 17:58–63.
Shibaoka, M., Saxby, J.D., and Taylor, G.H. 1978. Hydrocarbon generation in Gippsland basin, Australia: Comparison with Cooper basin, Australia. American Association of Petroleum Geologists Bulletin 62:1151–1158.
Shimoyama, A., and Johns, W.D. 1971. Catalytic conversion of fatty acids to petroleum-like paraffins. Nature Physical Science 232:140–144.
Smyth, M., and Saxby, J.D. 1981. Organic petrology and geochemistry of source rocks in the Pedirka-Simpson Basins, central Australia. Australian Petroleum Exploration Association Journal 21:187–199.
Snowdon, L.R. 1979. Errors in the extrapolation of experimental kinetic parameters to organic geochemical systems. American Association of Petroleum Geologists Bulletin 63:1128–1138.
Stach, E., Mackowsky, M.-T., Teichmüller, M., Taylor, G.H., Chandra, D., and Teichmüller, R. 1982. Stach’s Textbook of Coal Petrology (3rd ed.). Berlin, Gebruder Borntraeger, 535 pp.
Suggate, R.P. 1982. Low-rank sequences and scales of organic metamorphism. Journal of Petroleum Geology 4:377–392.
Tan, L.-P. 1965. The metamorphism of Taiwan Miocene coals. Bulletin of the Geological Survey of Taiwan 16:44 pp.
Teichmüller, M., and Teichmüller, R. 1979. Zur Geothermischen Geschichte des Oberrhein-Grabens Zusammenfassung und Auswertung eines Symposiums. Fortschritte in der Geologie von Rheinland und Westfalen 27:109–120.
Teichmüller, M., and Teichmüller, R. 1981. The significance of coalification studies to geology: A review. Bulletin Centres Recherches Exploration-Production Elf-Aquitaine 5:491–534.
Thomas, B.M. 1979. Geochemical analysis of hydrocarbon occurrences in northern Perth Basin, Australia. American Association of Petroleum Geologists Bulletin 63:1092–1107.
Ting, F.T.C. 1975. Reflectivity of disseminated vitrinite in the Gulf Coast region. In: Alpern, B. (ed.): Petrographie de la Matiere Organique des Sediments Relations avec la Paleotemperature et le Potentiel Petrolier. Paris, Centre National de la Recherche Scientifique.
Ting, F.T.C. 1978. Petrographic techniques in coal analysis. In: Karr, C., Jr. (ed.): Analytical Methods for Coal and Coal Products. New York, Academic Press, pp. 3–26.
Tissot, B.P., Bard, J.F., and Espitalié, J. 1980. Principal factors controlling the timing of petroleum generation. In: Miall, A.D. (ed.): Facts and Principles of World Petroleum Occurrence. Canadian Society of Petroleum Geologists Memoir 6, pp. 143–152.
Tissot, B.P., Debyser-Califet, Y., Deroo, G., and Oudin, J.L. 1971. Origin and evolution of hydrocarbons in early Toarcian shales, Paris Basin, France. American Association of Petroleum Geologists Bulletin 55:2177–2193.
Tissot, B.P., Deroo, G., and Hood, A. 1978. Geochemical study of the Uinta basin: Formation of petroleum from the Green River Formation. Geochimica et Cosmochimica Acta 42:1469–1485.
Tissot, B.P., and Espitalié, J. 1975. The thermal evolution of organic matter in sediments: Applications of mathematical simulation. Revue de la Institut Francais du Petrole 30:743–777.
Tissot, B.P., and Welte, D.H. 1984. Petroleum Formation and Occurrence (2nd ed.). New York, Springer-Verlag, 699 pp.
Vallentyne, J.R. 1957. Thermal degradation of amino acid. In: Annual Report of the Director of the Geophysical Laboratory, 1956–1957. Carnegie Institution of Washington, Geophysical Laboratory Paper 1277, pp. 185–186.
Vallentyne, J.R. 1964. Biogeochemistry of organic matter: II. Geochimica et Cosmochimica Acta 28:157–188.
Veto, I. 1980. An examination of the timing of catagenesis of organic matter using three published models. In: Douglas, A.G., and Maxwell, J.R. (eds.): Advances in Organic Geochemistry 1979. New York, Pergamon Press, pp. 163–167.
Walker, A.L., McCulloh, T.H., Petersen, N.F., and Stewart, R.J. 1983. Discrepancies between anomalously low reflectance of vitrinite and other maturation indicators from an Upper Miocene oil source rock, Los Angeles Basin, California (abst.): American Association of Petroleum Geologists Bulletin 67:565.
Waples, D.W. 1980. Time and temperature in petroleum exploration: Application of Lopatin’s method to petroleum exploration. American Association of Petroleum Geologists Bulletin 64:916–926.
Waples, D.W. 1982. Time and temperature in petroleum formation: Application of Lopatin’s method to petroleum exploration: Reply. American Association of Petroleum Geologists Bulletin 66:1152.
Waples, D.W. 1984. Thermal models for oil generation. In: Brooks, J., and Welte, D.H. (eds.): Advances in Petroleum Geochemistry: Vol. 1. London, Academic Press, pp. 8–67.
Wright, N.J.R. 1980. Time, temperature, and organic maturation: The evolution of rank within a sedimentary pile. Journal of Petroleum Geology 2:411–425.
Ziegler, P.A. 1980. Northwest European Basin: Geology and hydrocarbon provinces. In: Miall, A.D. (ed.): Facts and Principles of World Petroleum Occurrence. Canadian Society of Petroleum Geologists Memoir 6, pp. 653–706.
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Barker, C.E. (1989). Temperature and Time in the Thermal Maturation of Sedimentary Organic Matter. In: Naeser, N.D., McCulloh, T.H. (eds) Thermal History of Sedimentary Basins. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-3492-0_5
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DOI: https://doi.org/10.1007/978-1-4612-3492-0_5
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