Abstract
The synthesis and bulk and solution properties of block copolymers having nonlinear architectures are reviewed. These materials include star-block copolymers, graft copolymers, miktoarm star copolymers, and complex architectures such as umbrella polymers and certain dendritic macromolecules. Emphasis is placed on the synthesis of well-defined, well-characterized materials. Such polymers serve as model materials for understanding the effects of architecture on block copolymer self-assembly, in bulk and in solution.
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Pitsikalis, M., Pispas, S., Mays, J.W., Hadjichristidis, N. (1998). Nonlinear Block Copolymer Architectures. In: Bellon-Maurel, V., et al. Blockcopolymers - Polyelectrolytes - Biodegradation. Advances in Polymer Science, vol 135. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-69191-X_1
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