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Neutron Spin Echo Investigations on the Segmental Dynamics of Polymers in Melts, Networks and Solutions

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Neutron Spin Echo Spectroscopy Viscoelasticity Rheology

Part of the book series: Advances in Polymer Science ((POLYMER,volume 134))

Abstract

Neutron spin echo (NSE) spectroscopy, an advanced high-resolution quasi-elastic neutron scattering technique, provides the unique opportunity to investigate long-range relaxation processes of macromolecules simultaneously in space and time on nano-scales. In particular, information on the single-chain behavior is not restricted to dilute solutions, but may also be obtained from concentrated solutions and melts, if labelling by proton deuterium exchange is used. Thus, this method facilitates a direct microscopic study of molecular models developed to explain the macroscopic dynamic properties of polymers, e.g. transport and viscoelastic phenomena.

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  1. MPI für Polymerforschung, Postfach 3148, 55021, Mainz, Germany

    B. Ewen

  2. Institut für Festkörperforschung, Forschungszentrum Jülich, Postfach 1913, 52425, Jülich, Germany

    D. Richter

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Ewen, B., Richter, D. (1997). Neutron Spin Echo Investigations on the Segmental Dynamics of Polymers in Melts, Networks and Solutions. In: Neutron Spin Echo Spectroscopy Viscoelasticity Rheology. Advances in Polymer Science, vol 134. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-68449-2_1

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