Abstract
This is a preliminary report about new osmotic pressure measurements in electrostatically stabilized highly swollen lamellar phases. We identify the stabilizing forces for different regimes: the equilibrium between dispersion and electrostatic forces explains the two coexisting lamellar phases while the lamellar to asymmetric disordered lamellar phase transition is entropically driven.
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© 1992 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Zemb, T., Belloni, L., Dubois, M., Marcelja, S. (1992). Osmotic pressure of highly charged swollen bilayers. In: Helm, C., Lösche, M., Möhwald, H. (eds) Trends in Colloid and Interface Science VI. Progress in Colloid & Polymer Science, vol 89. Steinkopff. https://doi.org/10.1007/BFb0116272
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DOI: https://doi.org/10.1007/BFb0116272
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Print ISBN: 978-3-7985-0913-9
Online ISBN: 978-3-7985-1680-9
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