Abstract
The role of humic substances in the transport of radioelements in natural aquifers is widely recognized. Complexation with humic materials is of particular interest when assessing the speciation of actinides in natural waters for the safety evaluation of nuclear waste storage policies.
The interaction between Am(III), a trivalent actinide, and humic/fulvic acids of aquatic origin (granitic groundwater) was investigated by two different techniques: spectrophotometry and size exclusion chromatography. Stability constants were calculated assuming the formation of complexes of 1:1 stoichiometry. The unit systems of these constants are discussed. Results when using these two techniques on Am(III) and Eu(III) are compared.
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References
Thurman, E.M. Organic Geochemistry of Natural Waters (Dordrecht: Nijhoff and Junk Publishers, 1985).
Aiken, G.R., D.M. McKnight, R.L. Wershaw and P. MacCarthy. Humic Substances in Soil, Sediment and Water (New York: J. Wiley, 1985).
Christman, R.F. and E.T. Gjessing. Aquatic and Terrestrial Humic Materials (Ann Arbor: Ann Arbor Sci., 1983).
Choppin, G.R. Radiochim. Acta 44/45:23 (1988).
Choppin, G.R. and B. Allard. In: A.J. Freeman and C. Keller, Eds, Handbook on the Physics and Chemistry of the Actinides, pp. 407–429 (Amsterdam: Elsevier, 1985).
Kim, J.I. In: A.J. Freeman and C. Keller, Eds, Handbook on the Physics and Chemistry of the Actinides, pp. 413–455 (Amsterdam: Elsevier, 1986).
Ramsay, J.D.F. Radiochim. Acta 44/45:165 (1988).
Moulin, V., P. Robouch, P. Vitorge and B. Allard. Radiochim. Acta 44/45:33 (1988).
Choppin, G.R. J. Inorg. Nucl. Chem. 40:655 (1978).
Lesourd-Moulin, V. Humic Acids and their Interactions with Cations Cu, Eu, Th, U, Report CEA-R-5354 (Saclay: Service of Documentation, 1986).
Carlsen, L., P. Bo and G. Larsen. In: G.S. Barney, J.D. Navratil and W.W. Schultz, Eds, Geochemical Behaviour of Disposed Radioactive Waste, Chapter 10 (Washington, DC: ACS-Symp. Series 246, American Chem. Soc. 1984).
Caceci, M. Radiochim. Acta 39:51 (1985).
Torres, R.A. and G.R. Choppin. Radiochim. Acta 35:143 (1984).
Moulin, V., P. Robouch, P. Vitorge and B. Allard. Inorg. Chim. Acta 140:303 (1987).
Robert, A., C. Sella and R. Heindl. Nucl. Instr. Methods in Physics Res. 225:179 (1984).
Moulin, V. In: J.I. Kim and E. Warnecke, Eds, Vortrage des 66-PTB Seminars PTB-SE-14 (Braunschweig: ISSN, 1986).
Moulin, V., A. Billon, C. Poitrenaud and M. Porthault. To be submitted.
Dellis, T. and V. Moulin. In: D.L. Miles Ed., Proceedings of WRI-6, pp. 197–201 (Rotterdam: Balkema, 1989).
Yamamoto, M. and M. Sakanoue. J. Radiat. Res. 23:261 (1982).
Marinsky, J.A. Report KBS AR84-21 (Stockholm: Swedish Nuclear Fuel and Waste Management Co, 1982).
Maes, A., J. De Brabandere and A. Cremers. Radiochim. Acta 44/45:51 (1988).
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© 1991 Springer-Verlag
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Moulin, V.M., Caceci, M.S., Theyssier, M.J. (1991). Complexation behaviour of humic substances from granitic groundwater towards Am(III). In: Allard, B., Borén, H., Grimvall, A. (eds) Humic Substances in the Aquatic and Terrestrial Environment. Lecture Notes in Earth Sciences, vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0010482
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DOI: https://doi.org/10.1007/BFb0010482
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