Abstract
The incorporation of nitrogen-containing substrates into syn gas/methanol reactions increases considerably the number of interesting products that are potentially available from these systems. We have already mentioned in Chapter 6 that methanol and ammonia manufacture are usually integrated in one plant. Much of the hydrogen necessary for ammonia manufacture in the Haber process is produced by the Water Gas Shift reaction. Some of the carbon dioxide coproduct from this reaction is used for the production of urea for fertilizer. The reactions involved are summarized below for an intregrated plant based on syn gas derived from methane steam reforming.
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Additional Reading
A. Mullen, `Ring Closure Reactions with Carbon Monoxide’ in New Syntheses with Carbon Monoxide,(J. Falbe, Ed.), Springer-Verlag, Berlin, 1980, p. 414.
A. F. M. Iqbal, `Deoxygenate Organic Compounds with Carbon Monoxide’, Chem. Tech., 4, 566 (1974)
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Sheldon, R.A. (1983). Nitrogen-Containing Systems. In: Chemicals from Synthesis Gas. Catalysis by Metal Complexes, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-1019-0_8
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DOI: https://doi.org/10.1007/978-94-017-1019-0_8
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