Abstract
Before the chemical engineering design of a proposed process can be initiated, values (or good estimates) will be required for a number of physico-chemical properties both for the pure components (these are usually comparatively easy to find) and the relevant mixtures. Extraction processes involving near-critical solvents are no more and no less demanding than other, more conventional, processes in this respect. Figures 1.16, 1.17 and 1.18, for example, and also 9.2 and 9.3 show simplified layouts for possible processes for extracting beds of solids or liquid streams with a near-critical solvent. In these cases the disengagement of the solute from the solvent gas is achieved by a throttling expansion. When carrying out the chemical engineering design of simple processes of this type, phase equilibria will be required for mixtures of the near-critical solvent with the material in the extractors and also for the solvent/solute mixtures in the separator. Mass transfer rate data will be required for sizing the continuous extractors in Figure 1.18 and 9.2. They will also be required in evaluating the performance of the extractor units (V1, V2, V3 in Figure 10.2 or 5 in Figure 9.3) used in the batch extraction of beds of solids.
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References
Prasad, R., Gottesman, M. and Scarella, R.A. (1981) US Patent 4, 246, 291.
Zosel, K. (1982), US Patent 4, 348, 422.
McHugh, M.A. and Krukonis, V.J. (1986) Supercritical Fluid Extraction: Principles and Practice, Butterworths, Boston, p. 186.
King, M.B., Bott, T.R., Barr, M.J., Mahmud, R.S. and Sanders, N. (1987) Separation Science and Technology, 22, 1103.
Francis, A.W. (1954), J. Phys. Chem., 58, 1099.
Azevedo, E.J.S.G., Matos, H.A., Nunes da Ponte, M. and Simoes, P.C. (1988) Proc. Int. Symp. on Supercritical Fluids, Nice, Vol. 1, p. 135.
Reid, R.C., Prausnitz, J.M. and Poling, B.E. (1987) The Properties of Gases and Liquids, 4th Edn., McGraw Hill, p.343.
King, M.B., Kassim, K., Bott, T.R., Sheldon, J.R. and Mahmud, R.S. (1984) Ber. Bunsenges. Phys. Chem., 88, 812.
Zou, M, Lim, S.B., Rizvi, S.S.H. and Zollweg, J.A. (1986), Chapter 8 in Supercritical Fluid Science and Technology (eds K.P. Johnston and J.N.L. Penninger), ACS Symposium Series No. 406, American Chemical Society, Washington.
Foster, N.R., Yun, S.L.J. and Ting, S.S.T. (1991) J. Supercritic. Fluids, 4, 127.
Liong, K.K., Foster, N.R. and Ting, S.S.T. (1992) Ind. Eng. Chem. Res., 31, 400.
Klein, T. and Schulz, S. (1989), Ind. Eng. Chem. Res., 28, 1073.
Chrastil, J. (1982) J. Phys. Chem., 86, 3016.
Panagiotopoulos, A.Z. and Reid, R.C. (1986) Chapter 28 in Equations of State — Theories and Applications, (eds K.C. Chao and R.L. Robinson), ACS Symposium Series No. 300, American Chemical Society, Washington.
Angus, S., Armstrong, B. and de Reuck, K.M. (1973) Carbon Dioxide, IUPAC International Thermodynamic Tables of Fluid State-3, Pergamon Press.
Levelt Sengers, J.M.H., Chang, R.F. and Morrison, G. (1986) Chapter 5 in Equations of State — Theories and Applications, (Eds Cheo, K.C. and Robinson, R.C.), ACS Symposium Series 300, American Chemical Society.
Skjold-Jorgensen, S. (1984) Fluid Phase Equilibria, 16, 317.
Brignole, E.A., Skjold-Jorgensen, S. and Fredenslund, A.A. (1985) Supercritical Fluid Technology, (eds J.M.C. Penninger et al.), Elsevier, p. 87.
Inomata, H., Konde, A. and Saito, S. (1990) Journal of Chemical Engineering of Japan, 23, 199.
Kleintgens, L.A. and Koningsveld, R. (1980) J. Electrochem. Soc., 127, 2352.
Bamburger, T., Erickson, J.C., Cooney, C.L. and Kumar, S.K. (1988) J.Chem. Eng. Data, 33, 327.
Benedict, M., Webb, G.B. and Rubin, L.C. (1942) J. Chem. Phys., 10, 747.
Stotler, H.H. and Benedict, M. (1953) Chem. Eng. Prog. Symp. Series 49 (6), 25.
Bishnoi, P.R. and Robinson, D.B. (1972) Can. J. Chem. Eng., 50, 101, 506.
Chao, K.C. and Greenkom, R.A. (1975) Thermodynamics of Fluids, Dekker, New York.
Reid, R.C., Prausnitz, J.M. and Poling, B.E. (1987) The Properties of Gases and Liquids,4th Edn., McGraw-Hill.
Cox, K.W., Bono, J.L., Kwok, Y.C. and Starling, K.E. (1971) Ind. Eng. Chem. Fund., 10, 245.
Starling, K.E. (1971) Hydrocarbon Processing, 50 (3), 101.
Starling, K.E. and Han, M.S. (1972) Hydrocarbon Processing, 51 (5), 129.
Nishiumi, H. and Saito, S. (1975) J. Chem. Eng. Japan, 8, 356.
Bender, E. (1970) Proc. 5th Symp. Thermophysical Properties, A.S.M.E., New York.
Angus, S. Armstrong, B. and De Reuck, K.M. (1978) Methane, International Thermodynamic Tables of the Fluid State-5, Pergamon Press.
Angus, S., Armstrong, B. and de Reuck, K.M. (1978) Nitrogen, International Thermodynamic Tables of the Fluid State-6,Pergamon Press.
Stewart, R.B. and Jaconsen, R.T. (1973) Cryogenics, 13, 526.
Angus, S., Armstrong, B. and de Reuck, K.M. (1978) Propylene, International Thermodynamic Tables of Fluid State-7,Pergamon Press.
Klincewicz, K.M. and Reid, R.C. (1984) AIChEJ, 30, 1, 137.
Edmister, W.C. (1958) Petroleum Refiner, 37, 4, 173.
Lin, H.M. and Chao, K.C. (1984) AIChEJ, 30, 981.
Plocker, U., Knapp, H. and Prausnitz, J.M. (1978) Ind. Eng. Chem. Proc. Des. Dey., 17, 324.
Knapp, H., Doring, R., Oellrich, L., Plocker, U. and Prausnitz, J.M. (1982) Vapor Liquid Equilibria for Mixtures of Low Boiling Substances, Part 1, Binary Systems, DECHEMA Chemistry Data Series, DECHEMA, Frankfurt.
King, M.B. and Bott, T.R. (1982) Separation Science and Technology, 17, 119.
Haselow, LS., Han, S.J., Greenkorn, R.A. and Chao, K.C. (1986) Chapter 7 in Equations of State — Theories and Applications, (eds K.C. Chao, and R.L. Robinson) ACS Symposium Series 300, American Chemical Society, Washington.
van Konynenburg, P.H. and Scott, R.L. (1980) Phil. Trans. Roy. Soc. (London), A298, 495.
Redlich, O. and Kwong, N.J.S. (1949) Chem. Rev., 44, 233.
Joffe, J. Schroeder, M. and Zudkevitch, D., (1970) AICHEJ, 16, 496.
Zudkevitch, D. and Joffe, J. (1970) AIChEJ, 16, 112.
Yarborough, L. (1979) in Equations of State in Engineering and Research, (eds K.C. Chao, and R.L. Robinson), ACS Advances in Chemistry Series No. 182, 385, American Chemical Society, Washington.
Morris, R.W. and Turek, E.A. (1986) Chapter 19 in Equations of State — Theories and Applications, (eds K.C. Chao and R.L. Robinson), ACS Symposium Series No. 300, American Chemical Society, Washington.
Soave, G. (1972) Chem. Eng. Sci., 27, 1197.
Graboski, M.S. and Daubed, T.E. (1978) Ind. Eng. Chem. Proc. Des. Dey., 17, 443.
Hederer, H., Peter, S. and Wenzel, H. (1976) Chem. Eng. J., 11, 183.
Brunner, G. (1978) Ph.D. Dissertation, University of Erlangen.
Brunner, G. and Hederer, H. (1979) High Pressure Science and Technology, Sixth AIRAPT Conference (eds K.D. Timmerhaus and M.S. Barber), Plenum Press, Vol. 1, p. 527.
Kwak, T.Y. and Mansoori, G.A. (1986) Chem. Eng. Sci., 41, 1303.
Panagiotopoulos, A.Z. and Reid, R.C. (1987) ACS Symposium Series No. 329, 115, American Chemical Society, Washington.
Nagahama, K., Suzuki, J. and Suzuki, T. (1988) Proceedings of International Symposium on Supercritical Fluids, Nice, France, Institut National Polytechnique de Lorraine, 107.
Peng, D.Y. and Robinson, D.B., (1976) Ind. Eng. Chem. Fundam., 15, 59.
Schmidt, G. and Wenzel, H. (1980) Chem. Eng. Science, 35, 1503.
Harmens, A. and Knapp, H. (1979) Ind. Eng. Chem. Fund., 19, 291.
Teja, A.S. and Patel, N.C. (1982) Chem. Eng. Sci., 37, 463.
Adachi, Y., Lu, B.C.Y. and Sugie, H. (1983) Fluid Phase Equilibria, 13, 133.
Palenchar, R.M., Erickson, D.D. and Leland, T.W. (1986) Chapter 6 in Equations of State — Theories and Applications, (eds K.C. Chao and R.L. Robinson), ACS Symposium Series 300, American Chemical Society, Washington.
Zudkevitch, D., Joffe, J. and Schroeder, G.M. (1969) Distillation 1969, Institution of Chemical Engineers, Rugby, p. 126.
King, M.B., Alderson, D.A., Fallaha, F.H., Kassim, D.M., Kassim, K.M., Sheldon, J.R. and Mahmud, R.S. (1983) Chapter 2 in Chemical Engineering at Supercritical Conditions, (eds M.E. Paulaitis, J.M.C. Penninger, R.D. Gray and P. Davidson ), Ann Arbor Science.
Tsekhanskaya, Y.V., Iomtev, M.B. and Mushkina, E.K. (1964) Russ. J. Phys. Chem., 38, 1173.
Mahmud, R.S. (1980) Ph.D. Thesis, University of Birmingham, U.K.
McHugh, M. and Krukonis, V. (1986) Supercritical Fluid Extraction — Principles and Practice, Butterworths, Boston, p. 18.
Schmitt, W.J. and Reid, R.C. (1986) J.Chem. Eng. Data, 31, 204.
Won, K.W. (1983) Chapter 14 in Chemical Engineering at Supercritical Fluid Conditions, (eds M.E. Paulitis, J.M.C. Penninger, R.D. Gray and D. Davidson ), Ann Arbor Science.
Wenzel, H. and Peter, S. (1971) Chem. Ing. Tech., 43, 856.
Panagiotopoulos, A.Z. and Kumar, S.K. (1985) Fluid Phase Equil., 22, 77.
del Valle, J.M. and Aguilera, J.M. (1988) Ind. Eng. Chem. Res., 27, 1551.
Gurdial, G., Wells, P.P., Foster, N.R. and Chaplin, R.C. (1989) J. Supercrit. Fluids, 2, 85.
Stahl, E., Schilz, W., Schutz, E. and Welling, E. (1978) Angew. Chem. Int. Edn., 17, 731.
Ziger, D.H. and Eckert, C.A. (1983) Int. Eng. Chem. Process Des. Dey., 22, 582.
McHugh, M.A., Seckner, A.J. and Yogan, T.J. (1984) Ind. Eng. Chem. Fund, 23, 493.
Goto, M., Smith, J.M., and McCoy, B.J.V., (1990) Ind. Eng. Chem. Res., 29, 282.
Favati, F., King, J.W. and Mazzanti, M. (1991) Supercritical Fluids II, Proc. Int. Symp., Boston, U.S.A., p. 2.
Bernardo-Gil, M.G., King, M.B. and Bott, T.R. (1988) Supercritical Fluids, Proc. Int. Symp., Nice, France, p. 651.
King, M.B., Bott, T.R. and Chami, S.H. (1987) in Separations for Biotechnology (eds M.S. Verral and M.J. Hudson ), Ellis Horwood.
Brady, B.O., Kao, C.P.C., Doolay, K.M., Knopf, F.C. and Gambrell, R.P., (1987) Ind. Eng. Chem. Res., 26, 261.
Dooley, K.M., Kno, C-P.C., Cambrell, R.P. and Knopf, F.C., (1987) Ind. Eng. Chem. Res., 26, 2058.
Gangadhara-Rao, V.S. and Mukhopadhyay, M. (1988) in Supercritical Fluids, Proc. Int. Symp. Nice, France, p. 643.
Sankar, K.U. and Manohar, B. (1988) in Supercritical Fluids, Proc. Int. Symp., Nice, France, p. 807.
Knez, Z., Posel, F., Hunek, J. and Golob, J. (1991) in Supercritical Fluids II, Proc. Int. Symp., Boston, U.S.A., p. 101.
Schaeffer, S.T., Zalkow, L.H. and Teja, A.S. (1989) in Supercritical Fluid Science and Technology (eds K.P. Johnston and J.M.L. Penninger ), A.C.S. Symp. Series, 426, p. 416.
Li, L. and Kitan, E. (1989) in Supercritical Fluid Science and Technology (eds K.P. Johnston and J.M.L. Penninger), ACS Symp. Ser., 406, American Chemical Society, Washington, p. 317.
Gotto, M., Smith, J.M. and McCoy, B.J. (1990) Ind. Eng. Chem. Res., 29, 282.
Stahl, E., Quirin, K-W. and Gerard, D. (1988) Dense Gases for Extraction and Refining, Springer-Verlag, Berlin.
Brunner, G. (1984) Ber. Bunsenges. Phys. Chem., 88, 887.
Eggers, R. (1985) Journal of American Oil Chemists Society, 62, 1222.
Eggers, R. and Wilp, C. (1990) High Pressure Chemical Engineering II, Proc. Int. Symp. Erlangen, Germany, p. 565.
O’Toole, C., Richmond, P. and Reynolds, J. (1986) The Chemical Engineer,June 73.
Catchpole, O.J., King, M.B. and Bott, T.R., (1992) Separations with Supercritical Fluids, AIChE Annual Meeting, Miami, U.S.A.
Tan, C.S., Liang, S.K., and Liou, D.C. (1988) Chem. Eng. Journal, 38, 17.
Lim, G.B., Holder, G.D. and Shah, Y.T. (1989) in Supercritical Fluid Science and Technology, (eds K.P. Johnston and J.C.L. Penninger), ACS Symposium 406, American Chemical Society, Washington, p. 379.
Knaff, G. and Schlunder, E.U. (1987) Chem. Eng. Process, 21, 151.
Debendetti, P.G. and Reid, R.C. (1986) A.I.Ch.E.J., 32, 2034.
Stephen, K. and Lucas, K. (1979) Viscosity of Dense Fluids, Plenum Press, New York and London.
Wakao, N. and Kaguei, S. (1982) Heat and Mass Transfer in Packed Beds,Gordon and Breach, New York, pp. 153 and 139.
King, M.B. and Chami, J.H. (1993) to be published.
Udayasankar, K., Manohar, B. and Chokkalingan (1986) J. Food. Sci. Tech., 23, 326.
Kandiah, M. and Spiro, M. (1990) Int. J. Food Sci. Tech., 25, 328.
Bartle, K.D., Boddington, T., Clifford, A.A. and Hawthorne, S.B. (1991) Supercritical Fluids 11, Proc. Int. Symp., Boston, U.S.A., p. 382.
So, G.G. and MacDonald, D.G. (1986) Can. J. Chem. Eng., 64, 80.
Catchpole, O.J. and King, M.B., to be published.
Hall, K.R., Eagleton, L.C., Acrivos A, and Vermeulen T, (1966) Ind. Eng. Chem. Fund., 5, 212.
del Valle, J.M., and Aguilera, J.M. (1988) Ind. Eng. Chem. Res., 27, 1551.
Iomtev, M.B., Tsekhanskaya, Y.V., (1964) Russ. J. Phys. Chem., 38 4, 485.
Tsekhanskaya, Y.V., (1971) Russ. J. Phys. Chem., 45, 744.
Knaff, G. and Schlunder, E.V. (1987) Chem. Eng. Process, 21, 101.
Taylor, G. (1953) Proc. R. Soc. (London), 219A, 186.
Taylor, G. (1954) Proc. R. Soc. (London), 223A, 446.
Taylor, G. (1953) Proc. R. Soc. (London), 225A, 473.
Aris, R. (1956) Proc. R. Soc. (London), 235A, 67.
Lee, H. and Thodos, G. (1983) Ind. Eng. Chem. Fund, 22, 17.
Fuller, E.N., Schettler, P.D. and Giddings, J.C. (1966) Ind. Eng. Chem., 58, 18.
Sun, C.K.J. and Chen, S.H. (1987) Ind. Eng. Chem. Res., 26, 815.
Sassiat, P.R., Mourier, P., Caude, M.H. and Rosset, R.H. (1987) Anal. Chem., 59, 1164.
Furazukuri, T., Hachisu, S. and Wakao, N. (1991) Ind. Eng. Chem. Res., 30, 1323.
Chami, J.H. and King, M.B., to be published.
Liong, K.K., Wells, P.A. and Foster, N.R. (1991) Ind. Eng. Chem. Res., 30, 1329.
Sun, C.K.J. and Chen, S.H. (1985) Chem. Eng. Sci., 40, 2217.
Sun, C.K.J. and Chen, S.H. (1985) A.I.Ch.E.J., 31, 1510.
Funazukuri, T. and Wakao, N. (1991) Supercritical Fluids: 2nd International Symposium, Boston, USA, p. 25.
Lee, H. and Thodos, G. (1983) Ind. Eng. Chem. Fund, 22, 17.
Mathur, G.P. and Thodos, G. (1963) A.I.Ch.E.J., 9, 596.
Murad, S. (1981) Chem. Eng. Sci., 36, 1867.
Wakao, N. and Smith, J.M. (1962) Chem. Eng. Sci., 17, 825.
Lorentz, K.A. (1881) Ann. Physik, 12, 127, 660.
Matos, H.A., De Azevedo, E.G. Simoes, P.C., Carrondo, M.T. and Nunes Da Ponte, M. (1989) Fluid Phase Equilibria, 52, 357.
Schneider, G. and Alwani, Z. (1967) Chem. Ing. Tech., 39, 649.
Morozov, V.S. and Vinkler, E.G. (1975) Russ. J. Phys. Chem., 49, 1404.
Vinkler, E.G. and Morozov, V.S. (1975) Russ. J. Phys. Chem., 49, 1405.
Debenedetti, P.G. and Reid, R.C. (1986) AJ.Ch.E.J., 32, (12), 2034.
Takahashi, S.J. and Hongo, M.J. (1982) Chem. Eng. Jap., 15, 1.
Lamb, D.M., Adamy, S.T., Woo, K.W. and Jonas, J. (1989) J. Phys. Chem., 93, 5002.
Sassiat, P.R., Mourier, P., Caude, M.H. and Rosset, R.H. (1987) Anal. Chem., 59, 1164.
Funazukuri, T., Hachisu, S. and Wakao, N. (1989) Anal. Chem., 61, 118.
Funazukuri, T., Hachisu, S. and Wakao, N. (1991) Ind. Eng. Chem. Res., 30, 1323.
Swaid, I. and Schneider, G.M. (1979) Ber. Bunsenges Phys. Chem., 83, 969.
Sun, C.K.J. and Chen, S.H. (1985) A. I. Ch. E. J., 31, 1904.
Dahmen, H., Kordikowski, A. and Schneider, G.M. (1990) J. Chrom., 505, 169.
Kopner, A., Hamm, A., Ellert, J., Feist, R. and Schneider, G.M. (1987) Chem. Eng. Sci., 42, 2213.
Feist, R. and Schneider, G.M. (1982) 17, (1), 261.
Dahmen, N., Dulberg, A. and Schneider, G.M. (1990) Ber. Bunsenges Phys. Chem.,94, 384 and 710.
Lauer, H.H., McManigill, D and Board, R.D., (1983) Anal. Chem., 55, 1370.
Hamann, H. and Richtering, H. (1970) Ber. Bunsenges Phys. Chem., 74, 995.
Harris, K.R. (1978) Physica, 93A, 593.
Tison, J.K. and Hunt, E.R. (1971) J. Chem. Phys., 54, 1526.
Sun, C.K.J. and Chen, S.H. (1986) A.I.Ch.E.J., 32, 1367.
Danckwerts, P.V. (1953) Chem. Eng. Sci., 2, 1.
Catchpole, O.J., King, M.B., Grey, J.B. and O’Malley, P.J.R. (1992) Chemeca 92 20th Australasian Chemical Engineering Proceedings, Canberra 2, 317.
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King, M.B., Catchpole, O. (1993). Physico-chemical data required for the design of near-critical fluid extraction process. In: King, M.B., Bott, T.R. (eds) Extraction of Natural Products Using Near-Critical Solvents. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2138-5_7
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