Abstract
Synthesis conditions, structures and physical properties of superhard and ultrahard forms of carbon obtained from C60 fullerene by static high-pressure-high-temeperature treatment are presented. The unit-cell parameters and intermolecular bonds have been found using molecular mechanics calculations and X-ray diffraction profile analysis. A weighted pattern factor R wP of 5–10% has been achieved when besides (2+2) intermolecular bonds a ‘common 4-memeber ring’ and (3+3) type links are considered. The sound velocities have been measured and a full set of elastic moduli calculated. The highest value of longitudinal sound wave velocity 26 ± 2 km s−1 has been found which is a record value for known solids. The bulk elastic modulus and the hardness of ultrahard fullerites are higher than the values for diamond. The correct diamond hardness at room temperature has been measured using the ultrahard fullerite indentors.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
S. R. Ruoff and A. L. Ruoff, Nature 350 (1991) 663.
Y. Wang, D. Tomanek and G. F. Bertsch, Phys. Rev. B 44 (1991) 6562.
M. Nunez-Regueiro, P. Monceau and J.-L. Hodeau, Nature 355 (1992) 237.
T. Sekine. Proc. Jpn. Acad, Ser. B 68 (1992) 95.
C. S. Yoo and W. J. Nellis,Science 252 (1991) 1489.
C. S. Yoo and W. J. Nellis, Chem. Phys. Lett. 198 (1992) 379.
H. Hirai, K. Kondo, N. Yoshizawa and M. Shiraishi, Appl. Phys. Lett 64 (1994) 1797.
V. D. Blank, S. G. Buga, M. Yu. Popov, et al, Phys. Lett. A 188 (1994) 281.
M. E. Kozlov, M. Hirabayashi, K. Nozaki, M. Tokumoto and H. Ihara, Appl. Phys. Lett 66 (1995) 1199.
V. D. Blank, B. A. Kulnitskiy and Ye. V. Tatyanin. Phys. Lett. A 204 (1995) 151.
V. D. Blank, S. G. Buga, N. R. Serebryanaya, et al, ibid. 205 (1995) 208.
V. D. Blank, S. G. Buga, N. R. Serebryanaya, et al, ibid. 220 (1996) 149.
V. D. Blank, S. G. Buga, G. A. Dubitsky, N. R. Serebryanaya, M. Yu. Popov and B. Sundqvist, Carbon 36 (1998) 319.
V. D. Blank, N. R. Serebryanaya, G. A. Dubitsky et al, Phys. Lett. A 248 (1998) 415.
S. G. Buga, V. D. Blank, B. A. Kulnitskiy, N. R. Serebryanaya, M. Klaeser, G. Liu and S. Lebedkin, Synth. Met. 121 (2001) 1093.
V. Blank, M. Popov, G. Pivovarov, N. Lvova, K. Goolinsky and V. Reshetov, Diam. Relat. Mater. 7 (1998) 427.
V. Blank, M. Popov, G. Pivovarov, N. Lvova and S. Terentev, ibid. 8 (1999) 1531.
N. R. Serebryanaya and L. A. Chernozatonskii. Solid State Commun. 114 (2000) 537.
L. A. Chernozatonskii, N. R. Serebryanaya and B. Mavrin. Chem. Phys. Lett. 316 (2000) 199.
S. Osawa, E. Osawa and Y. Hirose, Fullerene Sci. Technol. 3 (1995) 565.
L. Marques, M. Mezouar, J.-L. Hodeau, M. Nuez-Regueiro, N. R. Serebryanaya, V. A. Ivdenko, V. D. Blank and G. A. Dubitskyl, Science 283 (1999) 1720.
S. Buga, V. Blank, R. Bagramov, G. Dubitsky, A. Fransson, N. Serebryanaya and B. Sundqvist. Proceedings of the International Conference on Engineering and Technological Sciences 2000, Beijing, China, Oct. 11–13, Session 3 `Advanced Materials“, edited by J. Song and R. Yin (New World Press, China) 1 pp. 505–511.
S. Buga, V. Blank, A. Fransson, N. Serebryanaya and B. Sundqvist, J. Phys. Chem. Solids 63 (2002) 331.
V. D. Blank, Ye. V. Tatyanin and B. A. Kulnitskiy, Phys. Lett. A 225 (1997) 121.
S. Buga, V. Blank, G. Dubitsky, L. Ledman, X.-M. Zhu, E. B. Nyanchi and B. Sundqvist. J. Phys. Chem. Solids 61 (2000) 1009.
S. A. Kasarian, V. D. Blank, S. G. Buga, G. A. Dubitsky, V. M. Prokhorov, A. N. Oraevsky and N. F. Starodubtsev. J. Russian Laser Research 19 (No. 3) (1998) 237.
V. D. Blank, V. M. Levin, V. M. Prokhorov, S. G. Buga, G. A. Dubitsky and N. R. Serebryanaya, J. Experim. Theor. Phys. 87 (1998) 741.
V. M. Levin, V. D. Blank, V. M. Prokhorov, J. M. Soifer and N. P. Kobelev, J. Phys. Chem. Solids 61 (2000) 1017.
N. R. Serebryanaya, V. D. Blank, V. A. Ivdenko and L. A. Chernozatonskii, Solid State Commun. 118 (2001) 183.
V. Blank, M. Popov, N. Lvova, K. Goolinsky and V. Reshetov, J. Mater. Res. 12 (1997) 3109.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Kluwer Academic Publishers
About this chapter
Cite this chapter
Blank, V., Buga, S., Dubitsky, G., Serebryanaya, N., Popov, M., Prokhorov, V. (2002). Properties and Applications of Superhard and Ultrahard Fullerites. In: Ōsawa, E. (eds) Perspectives of Fullerene Nanotechnology. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-9598-3_19
Download citation
DOI: https://doi.org/10.1007/978-94-010-9598-3_19
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-9600-3
Online ISBN: 978-94-010-9598-3
eBook Packages: Springer Book Archive