Skip to main content

Part of the book series: NATO Science Series ((NAII,volume 52))

Abstract

Calorimetric techniques constitute a powerful tool to investigate materials. The methods used for the characterization of thermodynamic properties for molten salts include temperature, enthalpy and heat capacity measurements as mixing enthalpy and phase diagram determinations for their mixtures.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. A. Tian, J. Chim. Phys. 20, 132 (1923)

    CAS  Google Scholar 

  2. E. Calvet and H. Prat, Microcalorimetrie, Masson, Paris (1955); E. Calvet and H. Prat, Recents progrès en microcalorimetrie, Dunod, Paris (1958)

    Google Scholar 

  3. M. Gaune-Escard and J. P. Bros, Thermochim. Acta 31, 323 (1979)

    Article  CAS  Google Scholar 

  4. O. Kubaschewski and E. L. L. Evans, La thermochimie en métallurgie, Gauthier-Villard, Paris (1964)

    Google Scholar 

  5. H. Eslami, Thesis, Universite de Provence, Marseille (1976)

    Google Scholar 

  6. R. Fehrmann, M. Gaune-Escard, and N. J. Bjerrum, Inorg. Chem. 25, 1132 (1986)

    Article  CAS  Google Scholar 

  7. M. Gaune-Escard, Thesis, Universite de Provence, Marseille (1972)

    Google Scholar 

  8. O. J. Kleppa, J. Phys. Chem. 64, 1937 (1960)

    Article  CAS  Google Scholar 

  9. M. Gaune-Escard, L. Rycerz, A. Bogacz. Enthalpies of mixing in the DyCl3-NaCl, DyCl3-KCl and DyCl3-PrCl3 liquid systems. J. Alloys and Compounds, 204. 185–188, (1994).

    Article  CAS  Google Scholar 

  10. R. Takagi, L. Rycerz, M. Gaune-Escard. Mixing enthalpy and structure of the molten NaCl-DyCl3 system. Denki Kagaku, 62, 3, 240, (1994).

    CAS  Google Scholar 

  11. M. Gaune-Escard, L. Rycerz, W. Szczepaniak, A. Bogacz. Enthalpies of mixing in the PrCl3-CaCl2 and NdCl3-CaCl2 liquid systems, Thermochimica Acta, 236, 51–58, (1994).

    Article  CAS  Google Scholar 

  12. M. Gaune-Escard, L. Rycerz, W. Szczepaniak, A. Bogacz, Calorimetric investigation of the NdCl3-MCl (M = Na, K, Rb, Cs). Thermochimica Acta, 236, 67–80, (1994).

    Article  CAS  Google Scholar 

  13. M. Gaune-Escard, L. Rycerz, W. Szczepaniak, A. Bogacz, Calorimetric investigation of the PrCl3-NaCl and PrCl3-KCl liquid mixtures. Thermochimica Acta, 236, 59–66, (1994).

    Article  CAS  Google Scholar 

  14. M. Gaune-Escard, A. Bogacz, L. Rycerz, W. Szczepaniak. Formation enthalpies of the MBr-LaBr3 liquid mixtures (M = Li, Na, K, Rb, Cs). Thermochimica Acta, 279, 1–10, (1996).

    Article  CAS  Google Scholar 

  15. M. Gaune-Escard, L. Rycerz. Mixing enthalpy of TbCl3-MCl liquid mixtures. M = Li, Na, K, Rb, Cs. High Temp. Material Processes, 2, n°4, 483–496 (1998).

    Google Scholar 

  16. M. Gaune-Escard, L. Rycerz. Calorimetric investigation of the NdI3-MI systems ((M = Li, Na, K, Cs). Molten Salt Forum, 5-6, 217 (1998)

    CAS  Google Scholar 

  17. F. da Silva, L. Rycerz, M. Gaune-Escard, Z. Naturforsch 2001 (under press)

    Google Scholar 

  18. H. Aghai-Khafri, J.P. Bros, M. Gaune-Escard, Chem. Thermodynamics, 8, 331–338, (1976)

    Article  CAS  Google Scholar 

  19. W. Lukas, M. Gaune-Escard, and J. P. Bros, J. Chem. Thermodyn. 19, 717 (1987)

    Article  CAS  Google Scholar 

  20. J. W. Johnson, W. J. Silva, and D. J. Cubicciotti, J. Chem. Phys. 69, 3916 (1965)

    Article  CAS  Google Scholar 

  21. D. Chiotti, G. Gartner, E. Stevens, and Y. Saito, J. Chem. Eng. Data 11, 571 (1966)

    Article  CAS  Google Scholar 

  22. Z. Benkhaldoun, Thesis, Universite de Provence, Marseille (1985)

    Google Scholar 

  23. G. Hatem, M. Gaune-Escard, J. P. Bros, and T. Ostvold, Ber. Bunsenses Phys Chem 92, 751 (1988).

    CAS  Google Scholar 

  24. Y. Fouque, M. Gaune-Escard, W. Szczepaniak, and A. Bogacz, J. Chim. Phys. 75, 360 (1978)

    CAS  Google Scholar 

  25. G. N. Papatheodorou and O. J. Kleppa, Z. Anorg. Allg. Chem. 401, 132 (1973)

    Article  CAS  Google Scholar 

  26. J. L. Holm and O. J. Kleppa, Inorg. Chem. 6, 645 (1967)

    Article  CAS  Google Scholar 

  27. T. Ostvold and O. J. Kleppa, Inorg. Chem. 8, 78 (1969)

    Article  Google Scholar 

  28. B. K. Andersen and O. J. Kleppa, Acta Chem. Scand. Ser. A 30, 751 (1976)

    Article  Google Scholar 

  29. M. Gaune-Escard and J. P. Bros, Can. Met. Q. 13(2), 335 (1974)

    Article  Google Scholar 

  30. G. Hatem, P. Gaune, J. P. Bros, F. Gehringer, and E. Hayer, Rev. Sci. Instrum. 52, 585 (1981)

    Article  CAS  Google Scholar 

  31. G. Hatem and M. Gaune-Escard, J. Chem. Thermodyn. 11, 927 (1979)

    Article  CAS  Google Scholar 

  32. J. P. Bros, H. Eslami, and P. Gaune, Ber. Bunsenges. Phys. Chem. 85, 333 (1981)

    Article  CAS  Google Scholar 

  33. G. Hatem and M. Gaune Escard, 9th Experimental Thermodynamic Conference, London April 16-18, 1980

    Google Scholar 

  34. E. Hayer, K. L. Komarek, J. P. Bros, and M. Gaune-Escard, Z. Metallkde. 72, 109 (1981)

    CAS  Google Scholar 

  35. J. M. Miane, M. Gaune-Escard, and J. P. Bros, High Temp.-High Pressures 9, 465 (1977)

    CAS  Google Scholar 

  36. G. Hatem, M. Gaune-Escard, and A. Pelton, J. Phys. Chem. 86, 3039 (1982)

    Article  CAS  Google Scholar 

  37. G. Hatem and M. Gaune-Escard, J. Chem. Thermodyn. 16, 897 (1984)

    Article  CAS  Google Scholar 

  38. G. Hatem, F. Tabaries, and M. Gaune-Escard, Thermochim. Acta 149, 15, (1989)

    Article  CAS  Google Scholar 

  39. K. Mahmoud, Thesis, Universite de Provence, Marseille (1989)

    Google Scholar 

  40. P. Peretz, G. Hatem, M. Gaune-Escard, M. Hoch, Thermochimica Acta 262, 45–54 (1995)

    Article  CAS  Google Scholar 

  41. G. Hatem, M. Gaune-Escard, J. Chem. Thermodynamics, 25, 219–228 (1993).

    Article  CAS  Google Scholar 

  42. E. Hayer, K. Komarek, J. P. Bros, and M. Gaune-Escard, 4th International Conference on Liquid and Amorphous Metals, Grenoble, July 7-11, 1980

    Google Scholar 

  43. D. El Allam, Thesis, Universite de Provence, Marseille (1989)

    Google Scholar 

  44. M. J. O’Neil, Anal. Chem. 38, 1331 (1966)

    Article  Google Scholar 

  45. A. Bogacz, W. Wisniowski, Y. Fouque, J. P. Bros, and M. Gaune-Escard, J. Cat. Anal. Therm XIV, 339 (1983)

    Google Scholar 

  46. A. Bogacz, J. P. Bros, Y. Fouque, M. Gaune-Escard, and W. Szczepaniak, J. Chem. Soc., Faraday Trans1. 80, 2935 (1984)

    Article  CAS  Google Scholar 

  47. Y. Fouque, J. P. Bros, M. Gaune-Escard, M. Wisniowski, and A. Bogacz, Ber. Bunsenges Phys. Chem. 89, 777 (1985)

    Article  CAS  Google Scholar 

  48. J. P. Bros, M. Gaune-Escard, W. Szczepaniak, A. Bogacz, and A. W. Hewat, Acta Crystallogr. Sect. B, 43, 113(1987)

    Google Scholar 

  49. M. Gaune-Escard, L. Rycerz, W. Szczepaniak, A. Bogacz, Entropies of phase transitions in the the M3LnCl6 compounds (M = K, Rb, Cs; Ln = La, Ce, Pr, Nd) and K2LaCl5, J. Alloys and compounds, 204, 189–192, (1994).

    Article  CAS  Google Scholar 

  50. M. Gaune-Escard, L. Rycerz, W. Szczepaniak, A. Bogacz. Enthalpies of phase transition of the lanthanide chlorides LaCl3, CeCl3, PrCl3, NdCl3, GdCl3, DyCl3, ErCl3 and TmCl3. J. Alloys and Compounds, 204, 193–196, (1994).

    Article  CAS  Google Scholar 

  51. L. Rycerz, M. Gaune-Escard. Enthalpy of phase transition and heat capacity of stoichiometric compounds in LaBr3-MBr systems (M = K, Rb, Cs). J. Thermal Analysis and Calorimetry, 56, 355–363 (1999).

    Article  CAS  Google Scholar 

  52. L. Rycerz, M. Gaune-Escard. Enthalpies of phase transitions and heat capacity of SmCl3, EuCl3, TbCl3, ErCl3 and TmCl3 Z. Naturforsch 2001 (sous presse)

    Google Scholar 

  53. J. L. Holm, B. J. Holm, B. Rinnan, and F. GrOnvold, J. Chem. Thermodyn. 5, 97 (1973)

    Article  CAS  Google Scholar 

  54. M. Gaune-Escard, A. Bogacz, L. Rycerz, W. Szczepaniak, Heat capacity of LaCl3, CeCl3, PrCl3, NdCl3,GdCl3,DyCl3. J. Alloys Compounds, 235, 176–181, (1996).

    Article  CAS  Google Scholar 

  55. M. Gaune-Escard, A. Bogacz, L. Rycerz, W. Szczepaniak Heat capacity of LaC13, CeC13, PrC13, NdC13,GdC13,DyC13 J. Alloys Compounds, 235, 176–181, (1996).

    Article  CAS  Google Scholar 

  56. K. M. Gaune-Escard, L. Rycerz Heat capacity of the K3LnC16 compounds — Ln = La, Ce, Pr, Nd. Z. Naturforsch.54 a, 229–235, (1999).

    CAS  Google Scholar 

  57. I. M. Gaune-Escard, L. Rycerz Heat capacity of the Rb3LnC16 compounds — Ln = La, Ce, Pr, Nd. Z. Naturforsch. 54 a, 397–403, (1999).

    Google Scholar 

  58. H.J. Seifert, J. Sandrock and J. Uebach, Z. anorg. Allg. Chem. 555, 143 (1987)

    Article  CAS  Google Scholar 

  59. G. Tamman, Z. Anorg. Chem. 37, 303 (1903); Z. Anorg. Chem. 45, 24 (1905); Z. Anorg. Chem. 47, 289 (1905); see also J. E. Ricci, The Phase Rule and Heterogeneous Equilibrium, Dover, New York (1966)

    Article  Google Scholar 

  60. O. J. Kleppa, J. Phys. Chem. 61, 1120 (1957)

    Article  CAS  Google Scholar 

  61. O. J. Kleppa, J. Phys. Chem. 65, 843 (1961)

    Article  CAS  Google Scholar 

  62. J. P. Bros, Thesis, Universite de Provence, Marseille (1968)

    Google Scholar 

  63. G. Hatem, Thesis, Universite de Provence, Marseille, (1980)

    Google Scholar 

  64. F. da Silva, M; Gaune-Escard, Z. Naturforsch 2001 (under press)

    Google Scholar 

  65. Y. Koyama, R. Takagi, Y. Iwadate and K. Fukushima, J. Alloys Comp. 260, 75 (1997)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2002 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Gaune-Escard, M. (2002). Calorimetric Methods. In: Gaune-Escard, M. (eds) Molten Salts: From Fundamentals to Applications. NATO Science Series, vol 52. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0458-9_16

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0458-9_16

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0459-9

  • Online ISBN: 978-94-010-0458-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics